Vapor-Liquid-Liquid Equilibrium (VLLE) Data for the Systems Ethyl acetate + Water, Toluene + Water and Toluene + Ethyl acetate + Water at 101.3 kPa. Using Modified Equilibrium Still
DOI:
https://doi.org/10.31699/IJCPE.2011.3.1Abstract
Isobaric Vapor-Liquid-Liquid equilibrium data for the binary systems ethyl acetate + water, toluene + water and the ternary system toluene + ethyl acetate + water were determined by a modified equilibrium still, the still consisted of a boiling and a condensation sections supplied with mixers that helped to correct the composition of the recycled condensed liquid and the boiling temperature readings in the condensation and boiling sections respectively. The VLLE data where predicted and correlated using the Peng-Robinson Equation of State in the vapor phase and one of the activity coefficient models Wilson, NRTL, UNIQUAC and the UNIFAC in the liquid phase and also were correlated using the Peng-Robinson Equation of State in both the vapor and liquid phases.
References
Colburn, A. P.; Schoenborn, E.M. ; David Shiling. Equilibrium still for partially miscible liquids. Ind.Eng.Chem. 1943, 35, 1250-1254.
Ellis, S. R. M.; Garbett, R. D. A new equilibrium still for the study of partially miscible systems. Ind.Eng.Chem. 1960, 52, 385-388.
Prausnitz, J. M.; Lichtenthaler, R. N.; Azevedo, E. G. Molecular Thermodynamics Of Fluid-Phase Equilibria; Prentice Hall: PTR, 1999.
Peng, D. Y.; Robinson, D. B. Two and Three Phase Equilibrium Calculations for Systems Containing Water. Canadian J. Chem. Eng. 1976, 54, 595-599.
Carroll, J. J. ; Mather, A. E. Phase Equilibrium in The system WaterHydrogen Sulphide: Modelling the Phase Behavior with an Equation of State. Canadian J. Chem. Eng. 1989, 67, 999-1003.
Ohe, S. Vapor-Liquid equilibrium data; Kodansha, 1989.
Hala, E.; Pick, J;. Fried, V.; Vilim, O. VAPOR-LIQUID EQUILIBRIUM; Pergamon Press, 1958.
Universal Data Acquisition program (525 032); Leybold Didactic GmbH,1998.
Stockhardt, J. S.; Hull, C. M. VaporLiquid Equilibria and Boiling-Point Composition Relations for Systems nButanol-Water and Isobutannol-Water. Ind. Eng. Chem. 1931, 23, 1438-1440.
Chopade, S. P.; Dhale, A. D.; Clark, A. M.; Kiesling, C. W.; Myrant, L. K.; Jackson, J. E.; Miller, D. J. Vapor-LiquidLiquid Equilibrium (VLLE) and Vapor Pressure Data for the Systems 2-Methyl- 1,3-dioxolane (2MD) + Water and 2,4-Dimethyl-1,3-dioxolane (24DMD) + Water. J. Chem. Eng. Data 2003, 48, 44-47.
Prausnitz, J. M. Molecular Thermodynamics of Fluid-Phase Equilibria; Prentice Hall, 1969.
Mohammed, G. A. Investigation of Vapor-Liquid-Liquid Equilibria; Ph.D. thesis Al-Nahrain University: BaghdadIraq, 2005.
Assael, M. J.; Trusler, J.P.; Tsolakis, T. F. Thermophysical Properties Of Fluids An Introduction to their Prediction; Imperial College Press, 1996.
Smith, J. M.; Van Ness, H. C.; Abbott, M. M. Introduction to Chemical Engineering Thermodynamics; McGrawHill, 1996.
Edgar, T. F.; Himmelblau, D. M. Optimization Of Chemical Processes; McGraw-Hill, 1988.
Malesinski, W. Azeotropy and other Theoretical Problems of Vapor-Liquid Equilibrium; Interscience, PWN:New York, 1965.
Windholz, M.; Budavari, S.; Stroumtsos, L. Y.; Fertig, M. N. THE MERCK INDEX; MERCK & CO, 1976.
Gerald, C. F.; Wheatly, P. O. Applied Numerical Analysis;AddisonWesley, 1989.
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