Iraqi Journal of Chemical and Petroleum Engineering

Performance of Immobilized Chlorella Algae for Removing pb(II) Ions from Aqueous Solution

Hala N. Abdulkareem — 2019-09-30

This study aims to show the effectiveness of immobilization of Chlorella green algae biomass in the form of bead for the removal of lead ions from synthetic polluted water at various operational parameters such as pH (2–6), biosorbent dosage (0.5–20 g/L) and initial concentration (10–100 mg/L). More than 90 % removal efficiency was achieved. FTIR and SEM-EDX analysis of the biosorbent before and after sorption show differences in the functional groups on the adsorbent surface. Langmuir and Freundlich equilibrium isotherm, pseudo-first-order and pseudo-second-order kinetic models were applied to the experimental and results and show good conformity with Langmuir isotherm model and pseudo-second-order kinetic model with correlation coefficient (0.994) and (0.998) respectively.

A Comparative Study of the Influence of Different Types of Polymers on Viscosity Index and Pour Point of Iraqi Base Oils

Rusul F. Abdul-saheb — 2019-09-30

In this study, the effects of blending the un-branched acrylate polymer known as Poly (n-decyl acrylate), and the branched acrylate polymer known as Poly (iso-octyl acrylate), on the viscosity index (VI), and the pour point of the Iraqi base stocks 40, and 60 respectively, were investigated. Toluene was used as a carrier solvent for both polymer types. The improvement level of oils (VI, & pour point) gained by blending the oil with the acrylate derived polymers was compared with the values of (VI, and pour point) gained by blending the oil with a commercial viscosity index, and pour point improver. The commercial lubricant additive was purchased and used by Al-Daura Refineries. It consisted of an un-known olefin copolymer dissolved in an un-known carrier solvent. All polyacrylate derivatives and the commercial lubricant additive named HITEC5748 were blended with each type of oil in weight percentage of (2, 4, 6, 8, & 10) wt. %. The result of the study was that the improvement in the viscosity index and the pour point of both base stock types was higher when using the polyacrylate derivatives than when using the commercial olefin copolymer additive.

Evaluation Properties and PNA Analysis for Different Types of Lubricants Oils

Asaad Salim Bded — 2019-09-30

A study of characteristics of the lubricant oils and the physical properties is essential to know the quality of lubricant oils. The parameters that lead to classify oils have been studied in this research. Three types of multi-grades lubricant oils were applied under changing temperatures from 25 ^oC to 78^oC to estimate the physical properties and mixture compositions. Kinematic viscosity, viscosity gravity constant and paraffin (P), naphthenes (N) and aromatics (A) (PNA) analysis are used to predict the composition of lubricants oil. Kinematic viscosity gives good behaviors and the oxidation stability for each lubricant oils. PNA analysis predicted fractions of paraffin (X_P), naphthenes (X_N), and aromatics (X_A) for each one give us a good value for sample 3 (15W40) leads to suitable classification for this type multi-grade oils by kinematic viscosity

Adsorption of Methyl Orange from Wastewater by using Biochar

Mohammed Abdulrahman Hanoon — 2019-09-30

The biochar prepared from sawdust raw material was applied in this study for the treatment of wastewater polluted with methyl orange dye. The effect of pH (2-11), initial concertation (50-250 mg/L) and time were studied. The isotherm of Langmuir, Frendluch and temkin models studied. The Langmuir model was the best to explain the adsorption process, maximum uptake was 136.67 mg/g at 25C^o of methyl orange dye. Equilibrium reached after four hours of contact for most adsorbents.The values of thermodynamic parameters ∆G were negative at various temperatures, so the process spontaneous, while ∆H values were 16683 j/mol and ∆S values was 60.82 j/mol.k.

Removal of-Copper Ions-from Aqueous Solution Using Liquid-Surfactant-Membrane Technique

Huda M. Salman — 2019-09-30

Extraction of copper (Cu) from aqueous solution utilizing Liquid Membrane technology (LM) is more effective than precipitation method that forms sludge and must be disposed of in landfills. In this work, we have formulated a liquid surfactant membrane (LSM) that uses kerosene oil as the main diluent of LSM to remove copper ions from the aqueous waste solution through di- (2-ethylhexyl) phosphoric acid - D2EHPA- as a carrier. This technique displays several advantages including one-stage extraction and stripping process, simple operation, low energy requirement, and. In this study, the LSM process was used to transport Cu (II) ions from the feed phase to the stripping phase, which was prepared, using H₂SO₄. For LSM process, various parameters have been studied such as carrier concentration; treat ratio (TR), agitating speed and initial feed concentration. After finding the optimum parameters, it was possible to extract Cu up to 95% from the aqueous feed phase in a single stage extraction.

Certain Assessment of Using MWCNT Nps in Drilling Fluid to Mitigate Stick-Slip Problem during Drilling Operation System

Saifalden Y. Alssafar — 2019-09-30

Stick- slip is the continuous stopping& release of the Bit/BHA due to the irregular down-hole rotation prompted by the existing relationship between the friction torque and the torque applied from the surface to free the bit.

Friction coefficient between BHA and wellbore is the main player of stick slip amount, which can be mitigated by support a good lubricators as additives in drilling mud.

Mathematical (or empirical) solves should be done through adjusting all parameters which supposed to reduce stick- slip as low as possible using different models, one of the main parameters is drilling mud. As per Nanoparticles drilling fluid is a new technology that offers high performance it’s necessary to find out the relationship between the use of Nano fluid and the minimum stick- slip vibration. In this study (multiwall carbon Nano tube) will be used as a Nanoparticles in Fresh water bentonite mud and polymer mud by five tests per each one to find out the coefficient of friction and used it in a special torque and drag software as a part of drilling vertical well simulation to calculate expected bottom hole torque within five different Nano concentration per each mud type. In fresh water bentonite mud torque reduction was from 4000 ft-lb to 3500 ft-lb, while in polymer mud torque failed and didn’t reduce, so it raised from 2050.88 ft-lb to be around 2200 ft-lb.

Corrosion of Carbon Steel in Oxygen and NaCl Concentration Cells: the Influence of Solution Temperature and Aeration

Muayad F. Hamad — 2019-09-30

Corrosion rate tests were carried out on carbon steel under concentration cells conditions of oxygen and sodium chloride. The effect of aeration in one compartment on the corrosion rate of both coupled metals was determined. In addition, the effects of time and temperatures on the corrosion rate of both coupled metals and galvanic currents between them were investigated. Corrosion potentials for the whole range of operating conditions under concentration cell conditions were also studied. The results showed that under aeration condition, the formation of concentration cell caused a considerable corrosion rate of the Carbon steel specimens coupled in different concentrations of O₂ and NaCl due to the galvanic effect. Aerating one compartment caused a noticeable increase in the corrosion rate of the coupled specimen in the other compartment due to the galvanic effect. Increasing temperature caused unstable trends in the free and galvanic corrosion potentials. Increasing the temperature led to an increase in the corrosion rate for both metals.

Re-evaluation of Petro physical Properties in Yammama Formation at Nasiriya Field

Karrar Hayder Jassim — 2019-09-30

Nasiriya field is located about 38 Km to the north – west of Nasiriya city. Yammama, a giant lower cretaceous reservoir in Nasiriya field which is lithologically formed from limestone. Yammama mainly was divided into three main reservoir units YA, YB1, YB2 and YB3 and it is separated by impermeable layers of variable thickness. An accurate petro physical evolution of the reservoir is of great importance perform an excellent geological model so that four petro physical properties which are shale volume, porosity, water saturation and permeability was re-evaluated. The volume of shale was calculated using the density and neutron logs (VSH-DN) rather than using gamma ray log because of presence a uranium content in the formation that makes overestimation of shale volume. Cross plots of Density Neutron logs are used to determine porosity by using IP software, which is correcting automatically Density Neutron logs for the effect of shale. Indonesian equation was used to estimate water saturation for five wells rather than Archie equation in order to consider shale volume. Fuzzy logic was adopted to predict permeability instead of regression analysis (cross plot) because of presence of errors in the results in this method. The results are shown that units YB2 and YB3 have best reservoir quality.

Synthesized 2nd Generation Zeolite as an Acid-Catalyst for Esterification Reaction

Ali H. Alfattal — 2019-09-30

MCM-48 zeolites have unique properties from the surfaces and structure point of view as it’s shown in the results ,and unique and very sensitive to be prepared, have been experimentally prepared and utilized as a second-generation/ acid - catalyst for esterification reactions of oleic acid as a model oil for a free fatty acid source with Ethanol. The characterization of the catalyst used in the reaction has been identified by various methods indicating the prepared MCM-48 is highly matching the profile of common commercial MCM-48 zeolite. The XRF results show domination of SiO₂ on the chemical structure with 99.1% and agreeable with the expected from MCM-48 for it's of silica-based, and the SEM results show the cubic crystallographic space group compatible with Ia3d space group giving the hexagonal surface structure. The AFM test gave an average particle diameter of 97.51 nm and an average catalyst roughness of 0.855 nm. Esterification reaction of oleic acid with ethanol on MCM-48 has been carried in a batch reactor with 5% the prepared MCM-48 zeolite catalyst loading gives 81% of conversion after one hour at 353K

Development of East Baghdad Oil Field By Clusters of Horizontal Wells

Ayad A.Alhaleem A.Alrazzaq — 2019-09-30

There are varieties of reasons lead for drilling horizontal wells rather than verticals. Increasing the recovery of oil, especially from thin or tight reservoir permeability is the most important parameter.

East Baghdad oil field considered as a giant field with approximately more than 1billion barrel of a proved reserves accompanying recently to low production rate problems in many of the existing wells.

It is important to say that presence of of horizontal wells in East Baghdad field especially by converting some of already drilled wells by re-entry drilling horizontal sections may provide one of best solutions for the primary development stage in East Baghdad field which may be followed by drilling new horizontal wells or using multilateral wells.

Advance software (Well Test/FAST) has been used to convert the production data for the already drilled vertical wells to horizontals to simulate the productivity. It can be concluded that no measurements available for the ratio of anisotropy (Kv/Kh); in East Baghdad Oil Field therefore, the wells productivity has been estimated using wide range of anisotropy ratios that will help the field operator to determine exactly wells productivity. Moreover, it helps to recommend the effectiveness of applying hydraulic fracturing in improving horizontal well productivity.

The results show that it could be used well EB-32 as a re-entry horizontal well with an optimum section length of 1500-2000ft wich give the best production rate. The same result could be stated for EB-10 with somewhat higher productivity than EB-32.