Corrosion of Carbon Steel in Oxygen and NaCl Concentration Cells: the Influence of Solution Temperature and Aeration

Authors

  • Muayad F. Hamad Department of Chemical Engineering, Al-Nahrain University, Iraq
  • Huda D. Abdul Kader Department of Chemical Engineering, Al-Nahrain University, Iraq
  • Hussein A. Alabdly Department of Chemical Engineering, Al-Nahrain University, Iraq
  • Basim O. Hasan Department of Chemical Engineering, Al-Nahrain University, Iraq
  • Israa S. M. Ali Department of Chemical Engineering, Al-Nahrain University, Iraq

DOI:

https://doi.org/10.31699/IJCPE.2019.3.7

Keywords:

carbon steel, corrosion rate, concentration cell, galvanic current, temperature, Sodium chloride

Abstract

Corrosion rate tests were carried out on carbon steel under concentration cells conditions of oxygen and sodium chloride. The effect of aeration in one compartment on the corrosion rate of both coupled metals was determined. In addition, the effects of time and temperatures on the corrosion rate of both coupled metals and galvanic currents between them were investigated. Corrosion potentials for the whole range of operating conditions under concentration cell conditions were also studied.   The results showed that under aeration condition, the formation of concentration cell caused a considerable corrosion rate of the Carbon steel specimens coupled in different concentrations of O2 and NaCl due to the galvanic effect. Aerating one compartment caused a noticeable increase in the corrosion rate of the coupled specimen in the other compartment due to the galvanic effect. Increasing temperature caused unstable trends in the free and galvanic corrosion potentials. Increasing the temperature led to an increase in the corrosion rate for both metals.

References

J. O. Bockris, D. Drazic, and A. R. Despic, “The Electrode Kinetics of the Deposition and Dissolution of Iron,” Electrochimica Acta, vol.4, pp.325–361, Aug.1961.

J. D. Gruyter, S. F. Mertens, L. E. Temmerman, , "Corrosion due to differential aeration reconsidered", Journal of Electroanalytical Chemistry vol.506 ,pp. 61–63,Jun.2001.

R.W.Revie and H. H.Uhlig, “Corrosion and Corrosion Control an Introduction to Corrosion Science and Engineering” fourth edition, John Wiley & Sons, Inc., Hoboken New Jersey, 2008.

G.P.Hinds, , S.Zhou, and A.Turnbull, “Underdeposit Test Method for Assessing Performance of Corrosion Inhibitors,” in EUROCORR 2008 (European Federation of Corrosion, 2008),pp. 1–11.

G.P.Hinds, Cooling, and A.Turnbull, “Testing of Inhibitors for Underdeposit Corrosion in Sour Conditions,” in EUROCORR 2009 (European Federation of Corrosion, 2009), pp. 1–9.

F.LaQue, “Theoretical Studies and Laboratory Techniques in Sea Water Corrosion Testing Evaluation” Corrosion, vol.13, pp. 33 – 44, May 1957.

F.LaQue,, “Electrochemistry and Corrosion (Research and Tests),” Journal of The Electrochemical Society, vol.116 ,pp. 73C–77C,1969.

C. G. Law, and J. Newman , “Corrosion of a Rotating Iron Disk in Laminar, Transition, and Fully Developed Turbulent Flow” Journal of the Electrochemical Society, vol. 133 , pp. 37 – 42,1986.

N.Vahdat, and J.Newman, “Corrosion of an Iron Rotating Disk” Journal of the Electrochemical Society, vol.120 pp.1682 – 1686,1973.

B. K. Mahato, C. Y. Cha, and W. Shemlit, , “Unsteady State Mass Transfer Coefficients Controlling Steel Pipe Corrosion under Isothermal Flow Conditions”, Corrosion Science, vol.20, pp.421–441, 1980.

B. O.Hasan, "Galvanic corrosion of carbon steel–brass couple in chloride containing water and the effect of different parameters", Journal of Petroleum Science and Engineering, vol. 124, pp.137–14, Dec.2014.

B.O. Hasan, S.A. Sadiq, “Corrosion of carbon steel in acidic salt solutions under flow conditions”, MSC. Thesis Dept. of Chem. Eng., University of AL-Nahrain, Baghdad, 2012.

B. O. Hasan, "Galvanic corrosion of aluminum-steel under two-phase flow dispersion conditions of CO2 gas in CaCO3 solution", Journal of Petroleum Science and Engineering, vol. 133, pp. 76–84, Sep. 2015.

Q. J. Slaiman and B. O. Hasan, “Study on Corrosion Rate of Carbon Steel Pipe under Turbulent Flow Conditions” The Canadian Journal of Chemical Engineering, vol. 88, pp. 1114- 1120, Nov. 2010.

B. K.Mahato, F. R.Stewrd, , and L. W.Shimlit, “Steel Pipe Corrosion under Flow Condition - II Mass Transfer Correlations with Temperature Effects”, Corrosion Science J., vol.8, pp.737–749, 1968.

N. D. Tomashov, “Underground corrosion of metals,” in Theory of Corrosion and Protection of Metals, 2nd ed., Macmillan, 1966, , pp. 399–421.

L.S.Selwyn, W. R. Mckinnon, and V.Argyropoulos, “Maney Publishing Models for Chloride Ion Diffusion in Archaeological Iron,” vol. 46, no. 2, pp. 109–120, 2001.

N. D. Tomashov, Passivity and Protection of Metals Against Corrosion. Springer US, 1967.

B. R.Tzaneva, L. B.Fachikov, R. G.Raicheff, “Effect of halide anions and temperature on initiation of pitting in Cr–Mn–N and Cr–Ni steel”, Corros. Eng. Sci. Technol., vol.41, pp.62, 2006.

A.Guenbour, R. Sanchez-Tavar , M.T.Montanes, J.García-Antón , “Effect of temperature on galvanic corrosion of non- weld/weld AISI 316L stainless steel in H3PO4 ” ECS Transactions 25( 37) ,2010,pp. 63–81.

B. O. Hasan, S. M. Aziz, "Corrosion of carbon steel in two phase flow (CO2 gas-CaCO3 solution) controlled by sacrificial anode", Journal of Natural Gas Science and Engineering ,vol.46, pp. 71-79,Oct. 2017.

S. K. Hasan and P. Sisodia, “Paniala (Flacourtia Jangomas) Plant Extract as Eco Friendly Inhibitor on the Corrosion of Mild Steel in Acidic Media”, Rasayan J. Chem. No. 3, vol.4, p.548-553, 2011.

S. S. Hussein, , B. O.Hasan, N. A.Al-Haboubi, "Galvanic Corrosion of Copper / Nickel-Chrome Alloy in an Agitated Sulfuric Acid Solution", Al-Nahrain Journal for Engineering Sciences (NJES) Vol.21 No.1, pp.133-140,2018.

S. Yaro, M. A. Idan, "Corrosion Inhibition of Galvanic Couple Copper Alloy/Mild Steel in) Cooling Water System", Iraqi Journal of Chemical and Petroleum Engineering, Vol. 14, No.4, 19-25, 2013.

Q. J. M. Slaiman and J. C. Eirs, " Corrosion Inhibition of Carbon Steel in Hydrochloric Acid under Dynamic Conditions", Iraqi Journal of Chemical and Petroleum Engineering, Vol.17 No.4, 1- 10, 2016.

S.M. Mahmood, B. O. Hasan, Q. J. Slaiman, "The Effect of Time and Corrosion Products Formation on Corrosion Rate of Carbon Steel Pipe Under Turbulent Flow Conditions”, Iraqi Journal of Chemical and Petroleum Engineering, Vol. 8, No. 4, 63-71, 2007.

L. L. Shreir, R.A.Jarman, , and G.T.Burstein, , “ Corrosion Metal / Environment Reactions” third edition, Butterworth-Heinemann Volume I, Great Britain, 2000.

B. O. Hasan, M.F. Abdul-Jabbar, “Cathodic protection of carbon steel in 0.1N NaCl solution under flow condition using rotating cylinder electrode”, Iraqi Journal of Chemical and Petroleum Engineering, Vol. 18, No.4, , 2012.

Downloads

Published

2019-09-30

How to Cite

Hamad, M. F., Abdul Kader, H. D., Alabdly, H. A., Hasan, B. O., & Ali, I. S. M. (2019). Corrosion of Carbon Steel in Oxygen and NaCl Concentration Cells: the Influence of Solution Temperature and Aeration. Iraqi Journal of Chemical and Petroleum Engineering, 20(3), 49-57. https://doi.org/10.31699/IJCPE.2019.3.7

Publication Dates

Most read articles by the same author(s)