Emulsion Liquid Membrane for Pesticides Removal from Aqueous Solution: Emulsion Stability, Extraction Efficiency and Mass Transfer Studies
Keywords:Emulsion liquid membrane, Pesticides, Stability, Extraction
The current study investigated the stability and the extraction efficiency of emulsion liquid membrane (ELM) for Abamectin pesticide removal from aqueous solution. The stability was investigated in terms of droplet emulsion size distribution and emulsion breakage percent. The proposed ELM included a mixture of corn oil and kerosene (1:1) as a diluent, Span 80 (sorbitan monooleate) as a surfactant and hydrochloric acid (HCl) as a stripping agent without utilizing a carrier agent. Parameters such as homogenizer speed, surfactant concentration, emulsification time and internal to organic volume ratio (I/O) were evaluated. Results show that the lower droplet size of 0.9 µm and higher stable emulsion in terms of breakage percent of 1.12 % were formed at 5800 rpm of homogenizer speed, 4 v% of span 80 surfactant, 8 min of emulsification time and 1:1 (I/O) ratio while 86.4% of Abamectin pesticides were extracted under these conditions. Extraction kinetics and mass transfer study were also accomplished. The outcome of this study can be extended to the removal of other type of pesticides from water and wastewater.
S.Yavari, A. Malakahmad, N.B. Sapari, and S. Yavari, "Sorption-desorption mechanisms of imazapic and imazapyr herbicides on biochars produced from agricultural wastes", Journal of Environmental Chemical Engineering, 4(4), 3981-3989, 2016, https://doi.org/10.1016/j.jece.2016.09.003
J.O. Ighalo, A.A. Adelodun, A.G. Adeniyi, and C.A. Igwegbe, "Modelling the Effect of sorbate –sorbent Interphase on the Adsorption of pesticideses and Herbicides by Historical Data Design", Iranian Journal of Energy and Environment, 11(4), 253-259, 2020, https://dx.doi.org/10.5829/ijee.2020.11.04.02
A. Belguet, S. Dahamna, A. Abdessemed, K. Ouffroukh, and A. Guendouz, "Determination of abamectin pesticide residues in green pepper and courgette growing under greenhouse conditions (Eastern of Algeria –setif)", EurAsian Journal of BioSciences, 13(2),1741–1745, 2019.
W. Lu, W. Chen, N. Li, M. Xu, and Y. Yao, "oxidative removal of 4-nitrophenol using activated carbon fiber and hydrogen peroxide to enhance reactivity of metallophthalocyanine", Applied Catalysis B: Environmental,87(3–4),146–151,2009, https://doi.org/10.1016/j.apcatb.2008.08.024
J.A. Rodriguez-Liebana, A. Lopez-Galindo, C. Jiménez de Cisneros, A. Galves, M. Rozalen, R. Sanchez-Espejo, E.Caballero, and A. Pena, "Adsorption/desorption of fungicides in natural clays from southeastren Spain", Applied Clay Science, 132-133, 402–411, 2016, https://doi.org/10.1016/j.clay.2016.07.006
A. Mukherjee, R. Mehta, S. Saha, A. Bhattacharya, P. K. Biswas,and R. K. Kole, "Removal of multiple pesticide residues from water by low-pressure thin-film composite membrane", Applied Water Science. 10,1–8, 2020, https://doi.org/10.1007/s13201-020-01315-y
N. Modirshahla, M.A. Behnajady, and S. Mohammadi-Aghdam, "Investigation of the effect of different electrodes and their connections on the removal efficiency of 4-nitrophenol from aqueous solution by electrocoagulation", Journal of Hazardous Materials. 154 (1-3), 778–786, 2008, https://doi.org/10.1016/j.jhazmat.2007.10.120
M.Takht Ravanchi, T. Kaghazchi, and A.Kargari, "Application of membrane separation processes in petrochemical industry: a review", Desalination, 235(1-3),199–244, 2009, https://doi.org/10.1016/j.desal.2007.10.042
P. Kaghazchi, T. Jacob, , H.Wang, W.Chen, and T. E. Madey," First-principles studies on adsorbate-induced faceting of Re (11 2̄ 1)", Physical Review B - Condensed Matter and Materials Physics, 79(13),1–4, 2009, https://doi.org/10.1103/PhysRevB.79.132107
H. E. Mahmoud, and A. A. AL-Hemiri, "Minimization of toxic ions in wastewater using emulsion liquid membrane technique", Iraqi Journal of chemical and petroleum engineering, V.11, No.1, 11- 19, 2010.
A. A. Mohammed, and R. W. Al-Khateeb, "Application of Emulsion Liquid Membrane Using Green Surfactant for Removing Phenol from Aqueous Solution: Extraction, Stability and Breakage Studies", Journal of Ecological Engineering, 23(1), 305–314, 2022, https://doi.org/10.12911/22998993/143970
H. M.Salman, and A. A. Mohammed," Removal of copper ions from aqueous solution using liquid surfactant membrane technique", Iraqi Journal of chemical and petroleum engineering, V.20 , No.3 ,31 – 37, 2019, https://doi.org/10.31699/IJCPE.2019.3.5
K. Anarakdim, G. Gutiérrez, Á.Cambiella, O.Senhadji-Kebiche, and M.Matos, "The effect of emulsifiers on the emulsion stability and extraction efficiency of Cr(Vi) using emulsion liquid membranes (ELMS) formulated with a green solvent", Membranes. 10, 2020, https://doi.org/10.3390/membranes10040076
A. L. Ahmad, A. Kusumastuti, C. J.C. Derek, and B. Ooi, "Emulsion liquid membrane for heavy metal removal: an overview on emulsion stabilization and destabilization", Chemical Engineering Journal, 171(3) 870–882, 2011, https://doi.org/10.1016/j.cej.2011.05.102
R. M. Pfeiffer, "Leakage and swell in emulsion liquid membranes: experimental studies and corrected computational methods",Colorado School of Mines ProQuest Dissertations Publishing, 13884892, 2019.
M. A. Hussein, A. A. Mohammed, and M. A. Atiya, "Application of emulsion and Pickering emulsion liquid membrane technique for wastewater treatment: an overview", Environmental Science and Pollution Research, (Vol. 26, Issue 36, pp. 36184–36204). Springer, 2019, https://doi.org/10.1007/s11356-019-06652-3
Y. Wan, and X. Zhang," Swelling determination of W/O/W emulsion
liquid membranes", Journal of Membrane Science, 196185–201, 2002, https://doi.org/10.1016/S0376-7388(01)00554-3
A. L. Ahmad, , N. D. Zaulkiflee, A. Kusumastuti, and M. M. H. S Buddin,"Removal of Acetaminophen from Aqueous Solution by Emulsion Liquid Membrane: Emulsion Stability Study", Industrial and Engineering Chemistry Research, 58(2), 713–719, 2019, https://doi.org/10.1021/acs.iecr.8b03562
N. D. Zaulkiflee, A. L. Ahmad, J. Sugumaran, and N. F. C. Lah, "Stability Study of Emulsion Liquid Membrane via Emulsion Size and Membrane Breakage on Acetaminophen Removal from Aqueous Solution Using TOA", ACS Omega, 5(37), 23892–23897, 2020, https://doi.org/10.1021/acsomega.0c03142
A. Shokri, P. Daraei, and S. Zereshki, "Water decolorization using waste cooking oil: An optimized green emulsion liquid membrane by RSM", Journal of water process engineering, 33, 101021, 2020, https://doi.org/10.1016/j.jwpe.2019.101021
N. S. Majeed and M. A. Mohammed, "Phenol Removal from Aqueous Solution Using Emulsion Liquid Membrane Process: Batch Experimental Studies" Association of Arab Universities Journal of Engineering Sciences, 24(3), 135-149, 2017.
L. Bahloul, F.Ismail, and M.E. H. Samar, "Extraction and de-extraction of cationic dye using an emulsified liquid membrane in an aqueous solution", Energy procedia Journal, 36, 1232-1240, 2013, https://doi.org/10.1016/j.egypro.2013.07.139
M. A. Mohammed, W. O. Noori, and H. A. Sabbar,"Application of Emulsion Liquid Membrane Process for Cationic Dye Extraction". Iraqi Journal of Chemical and Petroleum Engineering, 21(3), 39–44, 2020, https://doi.org/10.31699/IJCPE.2020.3.5
M. Mesli, and N. E. Belkhouche, "Emulsion ionic liquid membrane for recovery process of lead. Comparative study of experimental and response surface design", Chemical Engineering Research and Design. 129,160–169, 2018, https://doi.org/10.1016/j.cherd.2017.11.011
A. A. Mohammed, M. A. Atiya, and M. A. Hussein, "Simultaneous studies of emulsion stability and extraction capacity for the removal of tetracycline from aqueous solution by liquid surfactant membrane", Chemical Engineering Research and Design, 159,225–235, 2020, https://doi.org/10.1016/j.cherd.2020.04.023
N. Jusoh, N.F.M. Noah, and N. Othman, "Double emulsion (water-in-oil-in-water) system in succinic acid extraction - a stability study", Chemical Engineering Transactions, 63-523–528, 2018, https://doi.org/10.3303/CET1863088
R. Sabry, A.Hafez, M. Khedr, and A. El-Hassanin, "Removal of lead by an emulsion liquid membrane: part I", Desalination. 212, 165–175, 2007, https://doi.org/10.1016/j.desal.2006.11.006
A. A. Mohammed, H. M .Selman, and G.Abukhanafer, "Liquid surfactant membrane for lead separation from aqueous solution: Studies on emulsion stability and extraction efficiency".Journal of Environmental Chemical Engineering, 6,6923–6930, 2018, https://doi.org/10.1016/j.jece.2018.10.021
Zaulkiflee, N. D., Shah Buddin, M. M. H., and Ahmad, A. L. (2018). Extraction of Acetaminophen from Aqueous Solution by Emulsion Liquid Membrane Using Taylor-Couette Column. International Journal of Engineering, 31(8), 1413-1420.
H. R. Mortaheb, M. H. Amini, F. Sadeghian, B. Mokhtarani, and H. Daneshyar, "Study on a new surfactant for removal of phenol from wastewater by emulsion liquid membrane", Journal of Hazardous Materials, 160-582-588, 2008, https://doi.org/10.1016/j.jhazmat.2008.03.095
B. Abismail, J.P. Canselier, A.M. Wihelm, H. Delmas, and C.Gourdon, "Emulsification by ultrasound: drop size distribution and stability", Ultrasonics Sonochemistry, 6(1-2), 75 -83, 1999, https://doi.org/10.1016/S1350-4177(98)00027-3
A. L. Ahmad, A. Kusumastuti, C. J. C.Derek ,and B. S.Ooi, "Emulsion liquid membrane for cadmium removal: Studies on emulsion diameter and stability", Desalination, 287, 30–34, 2012, https://doi.org/10.1016/j.desal.2011.11.002
M. B. Rosly, N . Jusoh, N. Othman, H. A.Rahman, R. N. R. Sulaiman, and N. F. M. Noah, "Stability of emulsion liquid membrane using bifunctional diluent and blended nonionic surfactant for phenol removal", Chemical Engineering and Processing - Process Intensification, 148, 107790, 2020, https://doi.org/10.1016/j.cep.2019.107790
R. A. Kumbasar, and O.Tutkun, "Separation of cobalt and nickel from acidic leach solutions by emulsion liquid membranes using Alamine 300 (TOA) as a mobile carrier", Desalination. 224, 201–208, 2008, https://doi.org/10.1016/j.desal.2007.04.088
R. N. R. Suleiman, and N. Othman, N.A.S. Amin, "Recovery of ionized nanosilver by emulsion liquid membrane process and parameters optimization using response surface methodology", Desalination and Water Treatment, 57(8) - 3339-3349, 2016, https://doi.org/10.1080/19443994.2014.985724
S. Chaouchi, and O. Hamdaoui, "Acetaminophen extraction by emulsion liquid membrane using Aliquat 336 as extractant", Separation and Puriﬁcation Technology, 129 - 32– 40, 2014, https://doi.org/10.1016/j.seppur.2014.03.021
I. Salahshoori, A. Seyfaee, A. Babapoor, and I. Cacciohi , "Recovery of manganese ions from aqueous solutions with cyanex 272 using emulsion liquid membrane technique: A design experment study", Journal of sustainable metallurgy,7(3), 1074–1090, 2021, https://doi.org/10.1007/s40831-021-00396-6
Z. Y. Ooi, N. Othman, M. Mohamed, and R. Rashid, "Removal performance of lignin compound from simulated pulping wastewater using emulsion liquid membrane process", International Journal of Global 2014, https://doi.org/10.1504/IJGW.2014.061021
R. S. Juang, and K. H. Lin, "Ultrasound assisted production of W/O emulsion in liquid surfactant membrane processes", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 238(1-3),43-49, 2004, https://doi.org/10.1016/j.colsurfa.2004.02.028
A. Daas, and O. Hamdaoui ,"Extraction of bisphenol Afrom aqueous solutions by emulsion liquid membrane",Journal of Membrane science, 348(1-2), 360-368, 2010, https://doi.org/10.1016/j.jhazmat.2010.02.033
M. Raji, M. E. M. Mekhzoum, D. Rodrigue, A.Qaiss el kacem,and R.Bouhfid, "Effect of silane functionalization on properties of polypropylene/clay nanocomposites",Composites Part B: Engineering. 146,106–115, 2018, https://doi.org/10.1016/j.compositesb.2018.04.013
H. P.Kohli, S. Gupta, and M.Chakraborty, "Stability and performance study of emulsion nanofluid membrane: A combined approach of adsorption and extraction of Ethylparaben",Colloids and Surfaces A: Physicochemical and Engineering Aspects,579, 123675, 2019, https://doi.org/10.1016/j.colsurfa.2019.123675
H. Kasaini, F. Nakashio, and M. Goto, "Application of emulsion liquid membranes to recover cobalt ions from a dual component sulphate solution containing nickel ions", Journal of Membrane Science, 146, 159–168 ,1998, https://doi.org/10.1016/S0376-7388(98)00105-7
R. E. Treybal, "Mass – Transfer Operations, third ed., McGraw - Hill Book Company", Malaysia. ISBN-0-07-065176-0, 1980.
V. Karcher, F. Perrechil, and A. Bannwart, "Interfacial energy during the emulsification of water-in-heavy crude oil emulsions", Brazilian Journal of Chemical Engineering,32, 127–137, 2015, https://doi.org/10.1590/0104-6632.20150321s00002696
Received on 08/10/2022
Received in Revised Form on 25/10/2022
Accepted on 05/11/2022
Published on 30/06/2023
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