Synthesis of Novel Porphyrin Derivatives and Investigate their Application in Sensitized Solar Cells


  • Mohammed Thamer Jaafar Department of Petroleum Engineering, College of Engineering, Kerbala University, Karbala, Iraq / Department of Chemistry, College of Science, Kerbala University, Karbala, Iraq
  • Luma Majeed Ahmed Department of Chemistry, College of Science, Kerbala University, Karbala, Iraq
  • Rahman Tama Haiwal Department of Chemistry, College of Science, Kerbala University, Karbala, Iraq



Synthesis Porphyrin, Porphyrin Derivatives, power conversion efficiency, Solar Cells


Solar energy has significant advantages compared to conventional sources such as coal and natural gas, including no emissions, no need for fuel, and the potential for installation in a wide range of locations with access to sunlight. In this investigation, heterocyclic derivatives were synthesized from several porphyrin derivatives (4,4',4",4"'-(porphyrin-5,10,15,20-tetrayl) tetra benzoic acid) compound (3), obtained by reaction Pyrrole with 4-formyl benzoic acid. Subsequently, porphyrin derivative-component amides 5a, 5b, and 5c were produced by reacting compound (3) with amine derivatives at a 1:4 molar ratio. These derivatives exhibited varying sensitivities for utilization in solar cells, with compound 5a displaying the highest power conversion efficiency (PCE) at 1.37%, as determined by measuring the short circuit current (Jsc), open-circuit voltage (Voc), and fill factor (FF) (Jsc = 2.24 mA cm-2, Voc = 0.80 mV, FF = 76.5%). Meanwhile, compound 5c exhibited the lowest PCE at 0.94% (Jsc = 1.55 mA cm-2, Voc = 0.750 mV, FF = 76.4%).


H. Lin et al., “Preparation of Single Substituted Phenyl Porphyrins Form Meso-Tetraphenyl Porphyrin-Synthetic Example from Symmetric Porphyrin into Asymmetric Porphyrins,” Open J Inorg Chem, vol. 08, no. 01, pp. 21–27, 2018,

W. Lian, Y. Sun, B. Wang, N. Shan, and T. Shi, “Synthesis and properties of 5,10,15,20-tetrakis [4-(3,5-dioctyloxybenzamido) phenyl] porphyrin and its metal complexes,” Journal of the Serbian Chemical Society, vol. 77, no. 3, pp. 335–348, 2012,

P. I. Premovi, I. R. Tonsa, D. M., and M. S. Pavlovi, “Air oxidation of the kerogen/asphaltene vanadyl porphyrins: an electron spin resonance study,” Journal of the Serbian Chemical Society, Volume 65, Issue 2, Pages: 113-121 2000.

R. K. Lammi et al., “Structural control of photoinduced energy transfer between adjacent and distant sites in multiporphyrin arrays,” J Am Chem Soc, vol. 122, no. 31, pp. 7579–7591, Aug. 2000,

O. M. Opeyemi, H. Louis, C. I. Opara, O. O. Funmilayo, and T. O. Magu, “Porphyrin and Phthalocyanines-Based Solar Cells: Fundamental Mechanisms and Recent Advances,” Advanced Journal of Chemistry-Section A, 2(1), 21-44 2019.

K. Sakamoto and E. Ohno-Okumura, “Syntheses and functional properties of phthalocyanines,” Materials, vol. 2, no. 3, pp. 1127–1179, 2009,

J. L. Suk, J. T. Hupp, and S. B. T. Nguyen, “Growth of narrowly dispersed porphyrin nanowires and their hierarchical assembly into macroscopic columns,” J Am Chem Soc, vol. 130, no. 30, pp. 9632–9633, Jul. 2008,

E. Önal, “Matériaux moléculaires magnétiques à base de porphyrines,” Université Claude Bernard-Lyon I, 2014.

H. Kim, R. Manivannan, G. Heo, J. W. Ryu, and Y. A. Son, “Porphyrin dye/TiO2 entrenched in PET to attain self-cleaning property through visible light photocatalytic activity,” Research on Chemical Intermediates, vol. 45, no. 7, pp. 3655–3671, Jul. 2019,

A. M. Shultz, O. K. Farha, J. T. Hupp, and S. B. T. Nguyen, “Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks,” Chem Sci, vol. 2, no. 4, pp. 686–689, 2011,

K. Zhang, Y. Yu, S. T. Nguyen, J. T. Hupp, L. J. Broadbelt, and O. K. Farha, “Epoxidation of the commercially relevant divinylbenzene with [tetrakis-(pentafluorophenyl)porphyrinato] iron(III) chloride and its derivatives,” Ind Eng Chem Res, vol. 54, no. 3, pp. 922–927, Jan. 2015,

A. Heydari-turkmani and S. Zakavi, “The first solid state porphyrin-weak acid molecular complex: A novel metal free, nanosized and porous photocatalyst for large scale aerobic oxidations in water,” J Catal, vol. 364, pp. 394–405, Aug. 2018,

Y. Ding, W. H. Zhu, and Y. Xie, “Development of Ion Chemosensors Based on Porphyrin Analogues,” Chem Rev, vol. 117, no. 4, pp. 2203–2256, Feb. 2017,

M. Jurow, A. E. Schuckman, J. D. Batteas, and C. M. Drain, “Porphyrins as molecular electronic components of functional devices,” Coordination Chemistry Reviews, vol. 254, no. 19–20. pp. 2297–2310, Oct. 2010.

W. J. Cho, Y. Cho, S. K. Min, W. Y. Kim, and K. S. Kim, “Chromium porphyrin arrays as spintronic devices,” J Am Chem Soc, vol. 133, no. 24, pp. 9364–9369, Jun. 2011,

P. Zhang, M. Wang, C. Li, X. Li, J. Dong, and L. Sun, “Photochemical H2 production with noble-metal-free molecular devices comprising a porphyrin photosensitizer and a cobaloxime catalyst,” Chemical Communications, vol. 46, no. 46, pp. 8806–8808, Dec. 2010,

M. Noori et al., “Tuning the electrical conductance of metalloporphyrin supramolecular wires,” Sci Rep, vol. 6, Nov. 2016,

M. Adineh, P. Tahay, M. Ameri, N. Safari, and E. Mohajerani, “Fabrication and analysis of dye-sensitized solar cells (DSSCs) using porphyrin dyes with catechol anchoring groups,” RSC Adv, vol. 6, no. 18, pp. 14512–14521, 2016,

N. Santhanamoorthi, C. M. Lo, and J. C. Jiang, “Molecular design of porphyrins for dye-sensitized solar cells: A DFT/TDDFT study,” Journal of Physical Chemistry Letters, vol. 4, no. 3, pp. 524–530, Feb. 2013,

M. R. Samantaray et al., “Synergetic effects of hybrid carbon nanostructured counter electrodes for dye-sensitized solar cells: A review,” Materials, vol. 13, no. 12. MDPI AG, pp. 1–34, Jun. 02, 2020.

G. E. Zervaki et al., “A propeller-shaped, triazine-linked porphyrin triad as efficient sensitizer for dye-sensitized solar cells,” Eur J Inorg Chem, no. 6, pp. 1020–1033, 2014,

Xavier A. Jeanbourquin, Xiaoe Li, ChunHung Law, Piers R.F. Barnes, Robin Humphry-Baker, Peter Lund, Muhammad I. Asghar, and Brian C. O’Regan . Rediscovering a Key Interface in Dye-Sensitized Solar Cells: Guanidinium and Iodine Competition for Binding Sites at the Dye/Electrolyte Surface. Journal of the American Chemical Society 2014, 136 (20) , 7286-7294.

H. Gerischer, M.E. Michel-Beyerle, F. Rebentrost, H. Tributsch, Sensitization of charge injection into semiconductors with large band gap, Electrochimica Acta, 13(6),1968, 1509-1515,

S. Sharma, Bulkesh Siwach, S. K. Ghoshal, and D. Mohan, “Dye sensitized solar cells: From genesis to recent drifts,” Renewable and Sustainable Energy Reviews, vol. 70. Elsevier Ltd, pp. 529–537, Apr. 01, 2017.

S. Kannan Balasingam, M. Lee, M. Gu Kang, and Y. Jun, “Improvement of dye-sensitized solar cells toward the broader light harvesting of the solar spectrum,” Chemical Communications, vol. 49, no. 15, pp. 1471–1487, Jan. 2013,

M. R. S. A. Janjua et al., “Theoretical and Conceptual Framework to Design Efficient Dye-Sensitized Solar Cells (DSSCs): Molecular Engineering by DFT Method,” J Clust Sci, vol. 32, no. 2, pp. 243–253, Mar. 2021,

M. Q. Lokman et al., “Enhancing photocurrent performance based on photoanode thickness and surface plasmon resonance using Ag-TiO2 nanocomposites in dye-sensitized solar cells,” Materials, vol. 12, no. 13, Jul. 2019,

U. I. Ndeze, J. Aidan, S. C. Ezike, and J. F. Wansah, “Comparative performances of nature-based dyes extracted from Baobab and Shea leaves photo-sensitizers for dye-sensitized solar cells (DSSCs),” Current Research in Green and Sustainable Chemistry, vol. 4, Jan. 2021,

M. Halka, S. Smoleń, I. Ledwożyw-Smoleń, and W. Sady, “Comparison of Effects of Potassium Iodide and Iodosalicylates on the Antioxidant Potential and Iodine Accumulation in Young Tomato Plants,” J Plant Growth Regul, vol. 39, no. 1, pp. 282–295, Mar. 2020,

C. Longo and M.-A. de Paoli, “Dye-Sensitized Solar Cells: A Successful Combination of Materials,” 2003.

S. Umale, V. Sudhakar, S. M. Sontakke, K. Krishnamoorthy, and A. B. Pandit, “Improved efficiency of DSSC using combustion synthesized TiO2,” Mater Res Bull, vol. 109, pp. 222–226, Jan. 2019,

N. Kutlu, “Investigation of electrical values of low-efficiency dye-sensitized solar cells (DSSCs),” Energy, vol. 199, May 2020,




How to Cite

Jaafar, M. T., Ahmed, L. M., & Haiwal, R. T. (2023). Synthesis of Novel Porphyrin Derivatives and Investigate their Application in Sensitized Solar Cells. Iraqi Journal of Chemical and Petroleum Engineering, 24(2), 113-122.

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