Preparation and characterization of smart hydrogels (magnetic field responsive)
DOI:
https://doi.org/10.31699/IJCPE.2024.3.8Keywords:
Magnetic nanoparticle; hydrogel; Polyvinyl alcohol; Smart hydrogelsAbstract
Iron nanoparticles were prepared by using the co-precipitation process, and then used to fabricate magnetic field-responsive hydrogel films. The magnetic nanoparticles' structural, physical-chemical, morphological, and magnetic characteristics and the effect of hydrogel films' coating concentration were studied. The properties of the hydrogel film responsive to the magnetic field were investigated using Fourier analysis spectroscopy infrared (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and a vibration sample magnetometer (VSM). The results indicated that all samples showed good inter-integration of the constituent materials and their functional groups. The hydrogel film samples which were polycrystalline, had broad diffraction peaks and showed constant particle size with nearly spherical particles with rounded edges. The SEM image of the magnetic nanoparticles with and without coating was established for the accumulation of numerous nanoparticles with a 17 nm mean diameter. In addition, the magnetic properties of the magnetic field-sensitive hydrogel films were evident and sufficient for drug delivery to the desired location.
References
B. Mishra, M. Upadhyay, SK Reddy Adena, BG Vasant, “Hydrogels: An Introduction to a Controlled Drug Delivery Device, Synthesis and Application in Drug Delivery and Tissue Engineering”. Austin Journal of Biomedical Engineering, 4(1):1037, 2017.
A. Bordbar-Khiabani, and M. Gasik, “Smart hydrogels for advanced drug delivery systems”, International Journal of Molecular Sciences, 23(7), 3665, 2022, https://doi.org/10.3390/ijms23073665
A.Kasiński, , M. Zielińska-Pisklak, ,E. Oledzka, and M. Sobczak, “Smart hydrogels–synthetic stimuli-responsive antitumor drug release systems”, International journal of nanomedicine, 4541-4572, 2020, https://doi.org/10.2147/IJN.S248987
A. Merati, N.Hemmatinejad; M. Shakeri, A. Bashari, “Preparation, Classification, and Applications of Smart Hydrogels. Advanced Functional Textiles and Polymers: Fabrication, Processing”, Applied physics letters, 337–364, 2019, https://doi.org/10.1002/9781119605843
E. Askari, A. Seyfoori, M. Amereh, S.S. Gharaie, H.S. Ghazali, Z.S.Ghazali, B. Khunjush, M. Akbari, “Stimuli-responsive hydrogels for local post-surgical drug delivery”, Gels, 6, 14, 2020, https://doi.org/10.3390/gels6020014
D. D. Chakraborty, L.K. Nath, P. Chakraborty, “Recent progress in smart polymers: Behavior, mechanistic understanding and application”, Polymer Plastic Technology Engineering, 57, 945–957, 2017, https://doi.org/10.1080/03602559.2017.1364383
P. Davoodi, L.Y. Lee, Q. Xu, V. Sunil, Y. Sun, S. Soh, C.H. Wang, “Drug delivery systems for programmed and on-demand release”, Advanced Drug Delivery Reviews, 132, 104–138, 2018, https://doi.org/10.1016/j.addr.2018.07.002
B. A Abdul-Majeed, H.K. Hussain, and N.A.K. Al-Sultanee, “ Effect of annealing on the crystallization of poly vinyl chloride for drug delivery system”, Iraqi Journal of chemical and petroleum engineering, 13(2), 29-36, 2012, https://doi.org/10.31699/IJCPE.2012.2.3
A. Al-delfi, and F.H. M. Al-Mahdawi, “Polyacrylamide Polymer Gel Systems for Conformance Control Technology: A Review”, Iraqi Journal of Chemical and Petroleum Engineering, 23(3), 75–83, 2022, https://doi.org/10.31699/IJCPE.2022.3.10
S. Jacob, A. B. Nair, J. Shah, N. Sreeharsha, S. Gupta, P. Shinu, “Emerging role of hydrogels in drug delivery systems, tissue engineering and wound management”, Pharmaceutics, 13, 357, 2021, https://doi.org/10.3390/pharmaceutics13030357
N. S. Majeed and D. M. Naji, “Synthesis and Characterization of Iron Oxide Nanoparticles by Open Vessel Ageing Process”, Iraqi Journal of Chemical and Petroleum Engineering, 19(2), 27–31, 2018, https://doi.org/10.31699/IJCPE.2018.2.5
N. Morishita, H. Nakagami, R. Morishita, S.I. Takeda, F. Mishima, B. Terazono, S. Nishijima, Y. Kaneda, N. Tanaka, “Magnetic nanoparticles with surface modification enhanced gene delivery of HVJ-E vector”, Biochemical and biophysical research communications, 334, 1121–1126, 2005, https://doi.org/10.1016/j.bbrc.2005.06.204
K. Haweel, C., and H. Ammar, “SPreparation of Polyvinyl Alcohol from Local Raw Material”, Iraqi Journal of Chemical and Petroleum Engineering, 9(1), 15–21, 2008, https://doi.org/10.31699/IJCPE.2008.1.3
R.K. Ibrahim, A. I. Mahmood, V. Gdovinova, and P. Kopcansky, “Magnetic Liquid Switching Using RodlikeFerronematic 6CHBT Liquid Crystal Mixture Depending on the Diffraction Patterns”, Iraqi Journal of Science, 465-474, 2021, https://doi.org/10.24996/ijs.2021.62.2.12
M. S. Darwish, L. M. Al-Harbi, and A. Bakry, “Synthesis of magnetite nanoparticles coated with polyvinyl alcohol for hyperthermia application”, Journal of Thermal Analysis and Calorimetry, 147(21), 11921-1193, 2022, https://doi.org/10.1007/s10973-022-11393-6
S. R. Ahmed , S. Ogale ,G. C. Papaefthymiou, R. Ramesh, P. Kofinas, “Magnetic properties of CoFe2O4 nanoparticles synthesized through a block copolymer nanoreactor route”, Applied physics letters, 80(9):1616–8, 2002, .https://doi.org/10.1063/1.1456258
H. H. Nguyen, H. K. T. Ta, S. Park, T. B. Phan, and N. K. Pham, “Resistive switching effect and magnetic properties of iron oxide nanoparticles embedded-polyvinyl alcohol film”, RSC advances, 10(22), 12900-12907, 2020, https://doi.org/10.1039/C9RA10101B
S. S. Behera, J. K. Patra, K. Pramanik, N. Panda, and H. Thatoi, “Characterization and evaluation of antibacterial activities of chemically synthesized iron oxide nanoparticles”, World Journal of Nano Science and Engineering, 2012, https://dx.doi.org/10.4236/wjnse.2012.24026
M. Chastellain, A. Petri, H. Hofmann, “Particle size investigations of a multistep synthesis of PVA coated superparamagnetic nanoparticles”, Journal of colloid and interface science, 278(2):353–60, 2004, https://doi.org/10.1016/j.jcis.2004.06.025
Downloads
Published
Issue
Section
License
Copyright (c) 2024 The Author(s). Published by College of Engineering, University of Baghdad.
This work is licensed under a Creative Commons Attribution 4.0 International License.