Investigating the effects of ultrasonic waves and nanosilica on the viscosity reduction of Sharqy Baghdad heavy crude oil

Authors

  • Athraa W. Azeez Department of Chemical Engineering, College of Engineering, University of Baghdad, Baghdad, Iraq
  • Hussein Q. Hussein Department of Chemical Engineering, College of Engineering, University of Baghdad, Baghdad, Iraq https://orcid.org/0000-0002-3364-3139

DOI:

https://doi.org/10.31699/IJCPE.2024.4.6

Keywords:

Asphaltene; Heavy crude oil; Viscosity reduction; Ultrasonic waves; and Nanosilica.

Abstract

The current study examines the combined impacts of ultrasonic waves and nano silica (NS) on reducing the viscosity Sharqy Baghdad heavy crude oil with an API gravity of 20.32. NS of an average particle size of 59.93 nm and 563.23 m²/g surface area were produced utilizing the sol-gel technique from Iraqi sand. The XRD analysis indicates the existence of an amorphous silica, the SEM analysis showed that NS tends to agglomerate, and the FTIR spectra exhibited the presence of siloxane and silanol groups. In addition, the TGA analysis demonstrated a total weight loss of 15.62%, validating the thermal stability of the NS. The experiments included a study of the impact of ultrasonic power, exposure time, duty cycle, temperature, and the combined effects of the ultrasonic waves and silica nanoparticles on the degree of viscosity reduction percentage (DVR%). The results demonstrated that the viscosity of the heavy crude oil decreased by 27.83% at an irradiation time of 2 min, power of 360 W, 0.8 duty cycle, a temperature of 35 ⁰C, assisted by nano silica at a concentration of 1500 mg/L.

References

H. H. Jasim, “Evaluation the Effect of Velocity and Temperature on the Corrosion Rate of Crude Oil Pipeline in the Presence of CO2/H2S Dissolved Gases,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 20, no. 2, pp. 41–50, 2019, https://doi.org/10.31699/ijcpe.2019.2.6

S. Thomas, “Enhanced Oil Recovery - An Overview,” Oil & Gas Science and Technology, vol. 63, no. 1, pp. 9–19, 2008, https://doi.org/10.2516/ogst:2007060

H. Q. Hussein and Z. A. Khedheer, “Study the Effect of Using Microwave Radiation and H-Donors on Improving Heavy Oil,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 18, no. 4, pp. 1–13, 2017, https://doi.org/10.31699/IJCPE.2017.4.1

F. Shakir, H. Q. Hussein, and Z. T. Abdulwahhab, “Influence of Nanosilica on Solvent Deasphalting for Upgrading Iraqi Heavy Crude Oil,” Baghdad Science Journal, vol. 20, pp. 144–156, 2022, https://doi.org/10.21123/bsj.2022.6895

R. G. Santos, W. Loh, A. C. Bannwart and O. V. Trevisan, “An overview of heavy oil properties and its recovery and transportation methods,” Brazilian Journal of Chemical Engineering, vol. 31, no. 03, pp. 571–590, 2014, https://doi.org/10.1590/0104-6632.20140313s00001853

N. M. Ali and T. M. Naife, “Removal of Vanadium and Nickel Ions from Iraqi Atmospheric Residue by Using Solvent Extraction Method,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 22, no. 1, pp. 15–20, 2021, https://doi.org/10.31699/ijcpe.2021.1.2

H. Q. Hussein and S. A. Mohammad, “Viscosity Reduction of Sharqi Baghdad Heavy Crude Oil Using Different Polar Hydrocarbons, Oxygenated Solvents,” Iraqi Journal of Chemical and Petroleum Engineering, vol. 15, no. 2, pp. 39–48, 2014, https://doi.org/10.31699/IJCPE.2014.2.5

S. W. Hasan, M. T. Ghannam, and N. Esmail, “Heavy crude oil viscosity reduction and rheology for pipeline transportation,” Fuel, vol. 89, no. 5, pp. 1095–1100, 2010, https://doi.org/10.1016/j.fuel.2009.12.021

M. A. Rahimi, H. A. Alijanvand, A. R. SaadatAbadi, M. H. Ghazanfari, and M. Ghanavati, “Effect of ultrasonic irradiation treatment on rheological behaviour of extra heavy crude oil: A solution method for transportation improvement,” Canadian Journal of Chemical Engineering, vol. 95, no. 1, pp. 83–91, 2016, https://doi.org/10.1002/cjce.22676

O. Gizem Gunal and M. R. Islam, “Alteration of asphaltic crude rheology with electromagnetic and ultrasonic irradiation,” Journal of Petroleum Science and Engineering, vol. 26, no. 1–4, pp.263–272, 2000, https://doi.org/10.1016/S0920-4105(00)00040-1

E. López-Salinas, J. G. Espinosa, J. G. Hernández-Cortez, J. Sánchez-Valente, and J. Nagira, “Long-term evaluation of NiMo/alumina–carbon black composite catalysts in hydroconversion of Mexican 538 C+ vacuum residue,” Catalysis today, vol. 109, no. 1–4, pp. 69–75, 2005, https://doi.org/10.1016/j.cattod.2005.08.011

D. A. Shafeeq, R. I. Ibrahim, and J. A. Mohammed, “An experimental investigation for flow characteristics of heavy oil in pipelines using dilution technique with different solvents,” Iraqi Journal of Oil & Gas Research, vol. 4, no. 1, pp. 16–27, 2024, https://doi.org/10.55699/ijogr.2024.0401.1058

X. Li, F. Zhang, and G. Liu, “Review on new heavy oil viscosity reduction technologies,” IOP Conference Series: Earth and Environmental Science, vol. 983, no. 1, 2022, https://doi.org/10.1088/1755-1315/983/1/012059

L. Liu, H. Lu, J. Qian, and J. Xing, “Progress in the technology for desulfurization of crude oil,” China Petroleum Processing and Petrochemical Technology, vol.12, no. 4, pp. 1–6, 2010.

R. K. Gupta and P. Gera, “Process for the Upgradation of Petroleum Residue: Review,” International Journal of Advanced Technology in Engineering and Science, vol. 3, no. 02, pp. 643–656, 2015.

A. Kadyirov and J. Karaeva, “Ultrasonic and heat treatment of crude oils,” Energies, vol. 12, no. 16, 2019, https://doi.org/10.3390/en12163084

L. C. Castaneda, J. A. D. Munoz, and J. Ancheyta, “Current situation of emerging technologies for upgrading of heavy oils,” Catalysis Today, vol. 220, pp. 248–273, 2014, https://doi.org/10.1016/j.cattod.2013.05.016

J. R. Lin and T. F. Yen, “An upgrading process through cavitation and surfactant,” Energy & Fuels, vol. 7, no. 1, pp. 111–118, 1993, https://doi.org/10.1021/ef00037a018

V. O. Abramov, A. V. Abramova, V. M. Bayazitov, M. S. Mullakaev, A. V. Marnosov, and A. V. Ildiyakov, “Acoustic and sonochemical methods for altering the viscosity of oil during recovery and pipeline transportation,” Ultrasonics Sonochemistry, vol. 35, pp. 389–396, 2017, https://doi.org/10.1016/j.ultsonch.2016.10.017

I. Najafi, S.M.R. Mousavi, M. H. Ghazanfari, C. Ghotbi, A. Ramazani, R. Kharrat and M. Amani, “Quantifying the role of ultrasonic wave radiation on kinetics of asphaltene aggregation in a toluene-pentane mixture,” Petroleum Science and Technology, vol. 29, no. 9, pp. 966–974, 2011, https://doi.org/10.1080/10916460903394144

C. A. Franco, T. Montoya, N. N. Nassar, P. Pereira-Almao, and F. B. Cortés, “Adsorption and subsequent oxidation of colombian asphaltenes onto nickel and/or palladium oxide supported on fumed silica nanoparticles,” Energy and Fuels, vol. 27, no. 12, pp. 7336–7347, 2013, https://doi.org/10.1021/ef4018543

N. Savage and M. S. Diallo, “Nanomaterials and Water Purification: Opportunities and Challenges,” Journal of Nanoparticle Research, vol.7, pp.331–342, 2005, https://doi.org/10.1007/s11051-005-7523-5

Y. Kazemzadeh, S. E. Eshraghi, K. Kazemi, S. Sourani, M. Mehrabi, and Y. Ahmadi, “Behavior of asphaltene adsorption onto the metal oxide nanoparticle surface and its effect on heavy oil recovery,” Industrial and Engineering Chemistry Research, vol. 54, no. 1, pp. 233–239, 2015, https://doi.org/10.1021/ie503797g

D. Montes, F. B. Cortés, and C. A. Franco, “Reduction of heavy oil viscosity through ultrasound cavitation assisted by NiO nanocrystals-functionalized SiO2 nanoparticles,” DYNA, vol. 85, no. 207, pp. 153–160, 2018, https://doi.org/10.15446/dyna.v85n207.71804

H. M. Hussain and A. A. K. Mohammed, “Preparation and Characterization of mordenite Zeolite from Iraqi Sand,” IOP Conference Series: Materials Science and Engineering, vol. 518, no. 6, 2019, https://doi.org/10.1088/1757-899X/518/6/062002

D. An, Y. Guo, Y. Zhu, and Z. Wang, “A green route to preparation of silica powders with rice husk ash and waste gas,” Chemical Engineering Journal, vol. 162, no. 2, pp. 509–514, 2010, https://doi.org/10.1016/j.cej.2010.05.052

H. X. Nguyen, N. T. T. Dao, H. T. T. Nguyen, and A. Q. T. Le, “Nanosilica synthesis from rice husk and application for soaking seeds,” IOP Conference Series: Earth and Environmental Science, vol. 266, no. 1, 2019, https://doi.org/10.1088/1755-1315/266/1/012007

R. R. Jalil and H. Q. Hussein, “The Influence of Nano Fluid Compared with Polyethylene Glycol and Surfactant on Wettability Alteration of Carbonate Rock,” IOP Conference Series: Materials Science and Engineering, vol. 454, no. 1, 2018, https://doi.org/10.1088/1757-899X/454/1/012046

R. Sharafudeen, J. M. Al-Hashim, M. O. Al-Harbi, A. I. Al-Ajwad, and A. A. Al-Waheed, “Preparation and Characterization of Precipitated Silica using Sodium Silicate Prepared from Saudi Arabian Desert Sand,” Silicon, vol. 9, no. 6, pp. 917–922, 2017, https://doi.org/10.1007/s12633-016-9531-8

N. J. Saleh, A. A. Abdulrahman, and Z. A. Yousif, “Characterization of Nano Silica prepared from Iraqi Rice Husk and its Application in Oil Well’s Cement,” Journal of Petroleum Research and Studies, pp. 236–257, 2017, https://doi.org/10.52716/jprs.v7i1.179

R. Rajan, Y. Zakaria, S. Shamsuddin, and N. F. Nik Hassan, “Robust synthesis of mono-dispersed spherical silica nanoparticle from rice husk for high definition latent fingermark development,” Arabian Journal of Chemistry, vol. 13, no. 11, pp. 8119–8132, 2020, https://doi.org/10.1016/j.arabjc.2020.09.042

E. A. Okoronkwo, P. E. Imoisili, S. A. Olubayode, and S. O. O. Olusunle, “Development of Silica Nanoparticle from Corn Cob Ash,” Advances in Nanoparticles, vol. 05, no. 02, pp. 135–139, 2016, https://doi.org/10.4236/anp.2016.52015

R. Foroutan, R. Mohammadi, S. J. Peighambardoust, S. Jalali, and B. Ramavandi, “Application of nano-silica particles generated from offshore white sandstone for cadmium ions elimination from aqueous media,” Environmental Technology and Innovation, vol. 19, p. 101031, 2020, https://doi.org/10.1016/j.eti.2020.101031

A. M. Doust, M. Rahimi, and M. Feyzi,” Effects of solvent addition and ultrasound waves on viscosity reduction of residue fuel oil,” Chemical Engineering and Processing, vol. 95, pp. 353-361, 2015, https://doi.org/10.1016/j.cep.2015.07.014

F. H. Abbas, T. M. Naife, D. J. Ahmed, and E. B. Hasan, “Enhancement of Vacuum Gas Oil Viscosity Using Ultrasound,” Journal of Petroleum Research and Studies, vol. 13, no. 2, pp. 86–99, 2023, https://doi.org/10.52716/jprs.v13i2.695

H. Mansouri, A. Mohammadidoust, and F. Mohammadi, “An optimization study on quality promotion of heavy crude oil exposed ultrasonic waves and magnetic nanoparticles addition,” Chemical Engineering and Processing - Process Intensification, vol. 167, p. 108542, 2021, https://doi.org/10.1016/j.cep.2021.108542

W. Setyaningsih, Karmila, R. N. Fathimah, and M. N. Cahyanto, “Process optimization for ultrasound-assisted starch production from cassava (manihot esculenta crantz) using response surface methodology,” Agronomy, vol. 11, no. 1, 2021, https://doi.org/10.3390/agronomy11010117

E. A. Taborda, V. Alvarado, C. A. Franco, and F. B. Cortés, “Rheological demonstration of alteration in the heavy crude oil fluid structure upon addition of nanoparticles,” Fuel, vol. 189, pp. 322–333, 2017, https://doi.org/10.1016/j.fuel.2016.10.110

H. X. Xu and C. S. Pu, “Experimental study of heavy oil underground aquathermolysis using catalyst and ultrasonic,” Journal of Fuel Chemistry and Technology, vol. 39, no. 8, pp. 606–610, 2011, https://doi.org/10.1016/s1872-5813(11)60037-6

Downloads

Published

2024-12-30

How to Cite

Azeez, A. W., & Hussein, H. Q. (2024). Investigating the effects of ultrasonic waves and nanosilica on the viscosity reduction of Sharqy Baghdad heavy crude oil. Iraqi Journal of Chemical and Petroleum Engineering, 25(4), 61-71. https://doi.org/10.31699/IJCPE.2024.4.6