Study the Performance of Nanozeolite NaA on CO2 Gas Uptake

Authors

  • Najwa Saber Majeed Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
  • Jwan Taher Majeed Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq

DOI:

https://doi.org/10.31699/IJCPE.2017.2.5

Keywords:

Carbon dioxide, Nanozeolite, Adsorption

Abstract

The adsorption isotherms and kinetic uptakes of CO2 were measured. Adsorption isotherms were measured at two temperatures 309 K and 333 K and over a pressure range of 1 to 7 bar. Experimental data of CO2 adsorption isotherms were modeled using Langmuir, Freundlich and Temkin. Based on coefficient of correlation it was found that Langmuir isotherm model was well suited with the experimental data of CO2 adsorption isotherms.  In addition, Adsorption kinetic of CO2 mixture with N2 containing 10 % by volume CO2 and 90 % by volume N2 were determined in a temperature 36 °C and under the atmospheric pressure .When the flow rate was increased from 0.5 l/min to 2 l/min the time required for complete column saturation decreased. Also the effect of bed length on breakthrough curves was studied. The adsorption capacity increases by bed length increasing for adsorption of carbon dioxide.

References

Yu, C.H., Huang, C.H. and Tan, C.S., 2012. A review of CO2 capture by absorption and adsorption”. Aerosol Air Qual. Res, 12 (5), pp.745-769.

Sabouni, R., 2013.Carbon dioxide adsorption by metal organic frameworks (Synthesis, Testing and Modeling). (Doctoral dissertation, University of Western Ontario).

Galhotra, P.,2010. Carbon dioxide adsorption on nanomaterials. (Doctoral dissertation, University of Iowa).

Mondal, M.K., Balsora, H.K. and Varshney, P.,2012. Progress and trends in CO 2 capture/separation technologies: a review. Energy, 46 (1), pp.431-441.

Siriwardane, R.V., Shen, M.S., Fisher, E.P. and Poston, J.A., 2001. Adsorption of CO2 on molecular sieves and activated carbon. Energy and Fuels, 15 (2), pp.279-284.

Shi, Y., Liu, Q. and He, Y.2015. CO2 Capture Using Solid Sorbents.

Pham, T.H., Lee, B.K. and Kim, J, 2016. Novel improvement of CO2 adsorption capacity and selectivity by ethylenediamine-modified nano zeolite. Journal of the Taiwan Institute of Chemical Engineers.

Pham, T.H., Lee, B.K., Kim, J. and Lee, C.H. 2016. Enhancement of CO2 capture by using synthesized nano-zeolite. Journal of the Taiwan Institute of Chemical Engineers, 64, pp.220-226.

Luciano S. R., 2012. Structured zeolite adsorbents for CO2 separation, MSC. thesis, College of Engineering, Luleå University of Technology.

Shakarova, D., Ojuva, A., Bergström, L. and Akhtar, F., 2014. Methylcellulose-Directed Synthesis of Nanocrystalline Zeolite NaA with High CO2 Uptake. Materials, 7 (8), pp.5507-5519.

Tan, I.A.W. and Hameed, B.H.,

Adsorption isotherms, kinetics, thermodynamics and desorption studies of basic dye on activated carbon derived from oil palm empty fruit bunch. Journal of applied sciences, 10, pp. 2565-2571.

Wu, X., Xu J., Tao J., 2013.13X-APG Granular Zeolite in a Fixed bed Adsorber of CO2 Adsorption Characteristics. New York Science Journal, 6 (11), pp.33-37.

Grande, C.A., Cavenati, S. and Rodrigues, A.E., 2005. “Pressure swing adsorption for carbon dioxide sequestration”. In 2nd Mercosur Congress on Chemical Engineering and 4th Mercosur Congress on Process Systems Engineering.

Downloads

Published

2017-06-30

How to Cite

Majeed, N. S., & Majeed, J. T. (2017). Study the Performance of Nanozeolite NaA on CO2 Gas Uptake. Iraqi Journal of Chemical and Petroleum Engineering, 18(2), 57-67. https://doi.org/10.31699/IJCPE.2017.2.5

Publication Dates

Most read articles by the same author(s)