Catalytic Reforming of Iraqi Naphtha over Pt-Ti / HY Zeolite Catalyst
Keywords:Zeolite Y, Sol-gel method., Naphtha catalytic reforming.
In the present work, zeolite Y has been synthesized successfully by sol-gel method.Zeolite was synthesized by crystallization of the final gel which consist from seeding and feed stock gels at 85 oC. HY zeolite was prepared by an ion exchange process with ammonium chloride solution and then loaded with different percentages of platinum and titanium by the wet - impregnation method.
X-ray Diffraction (XRD), X-ray Florescence (XRF), Scanning Electron Microscopy (SEM), BET surface area and, Crushing strength were used to characterize the synthesized and prepared catalysts . Results showed high crystallinity 90% with silica to alumina ratio 5 for HY, high surface area of 600 m2/g and pore volume of 0.38 cm3/g.
The activity of the prepared zeolite was investigated using a pilot plant unit for the catalytic reforming of Iraqi heavy naphtha. All prepared catalysts were investigated at temperatures of 490,500 and 510oC ,pressure of 20 bar, H2 /HC ratio 3 and LHSV 1.4.hr-1.
Reformate was produced with 86 RON and 94% yield at 510ºC and 20 bar using 0.13 wt.% Pt - 0.75 wt.% Ti loaded on synthesized HY.
How to Cite
For papers published in IJCPE, authors and their institutions all have the same rights to reuse articles published in the journal in accordance with the journal by IJCPE is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. This permits users to copy, redistribute, remix, transmit and adapt the work provided the original work and source is appropriately cited. Please check the license for full license terms and attribution requirements.