Experimental Study for the Influence of Operating Parameters on Copper Electrorefining Process
DOI:
https://doi.org/10.31699/IJCPE.2018.1.3Keywords:
Copper electrorefining process, Purity, Morphology, Deposition rate, Current efficiency, Power consumption, Electrolyte residence time.Abstract
Copper electrodeposition by electrorefining process in acidic sulfate media contains 40 g/l of cupric ions and 160 g/l of sulfuric acid was achieved to study the influence of the operating parameters on cathode purity, surface morphology, deposition rate, current efficiency and power consumption. These operating parameters and there ranges are: current density 200, 300 and 400 A/m2, electrolyte temperature 35, 50 and 65 oC, electrodes spacing 15, 30 and 45 mm and electrolyte residence time 6, 4 and 2 h were utilized. XRF, SEM and EDX analyses were attained to clarify the properties of the produced cathode.
References
Lusty P., and Gunn A., “Challenges to global mineral resource security and options for future supply”, Geological Society, London, Special Publications 393, no. 1, pp. 265-276, (2015).
Eugie K. and Wang Y., “Analysis of copper‘s market and price-focus on the last decade‘s change and its future trend”, International Journal of Scientific & Technology Research, VOL. 4, pp. 54-61, (2015).
Boulamanti A and Jose A., “Production costs of the non-ferrous metals in the EU and other countries: Copper and zinc”, Resources Policy
, pp. 112-118,(2016).
Ghodrat M., Rhamdhani M., Brooks G., Masood S., and Corder G., “ Techno economic analysis of electronic waste processing through black copper smelting route”, J. of Cleaner Production 126, pp.178-190, (2016).
Stelter M., and Hartmut B., “Process optimization in copper electrorefining” Advanced Engineering Materials 6, no. 7, pp 558-562, (2004).
John J. and Martin T., “The International Copper Industry”, Woodhead Publishing Ltd, (2002).
Schlesinger M. and Paunovic M., “Modern Electroplating”, Fifth Edition, John Wiley & Sons, (2010).
Mark E., Matthew J., Kathryn C.., and William G., “Extractive Metallurgy of Copper”, Fifth Edition, Elsevier Ltd, (2011).
Ntengwe F., Mazana N, Samadi F, “The Effect of Impurities and Other Factors on the Current Density in Electro-Chemical Reactors”, International Journal of ChemTech Research, Vol.2, No.2, pp 1289-1300, (2010).
Ntengwe F., “The Effect of Impurities, Smootheners and other Factors on the recovery of copper from solutions”, M.Sc. Thesis, South Africa University, Zambia, (2008).
Derek P. and Frank W., “Industrial Electrochemistry”, Second edition, springer science + business media, LLC, (1993).
Fischer, H., “Electrolytic deposition of metals and Electrocrystallization” Berlin, Springer, (1954).
Lee S., “Encyclopedia of Chemical Processing”, Taylor & Francis Group, LLC, (2006).
Kalliomaki T.,"Effect of composition and temperature on physico-chemical properties of copper electrolyte", M.Sc. Thesis, Aalto University School for Chemical Technology, (2015).
Aromaa, J.,“Electrochemical Engineering” in Encyclopedia of Electrochemistry, Wiley-VHC Verlag GmbH & Co. KGaA, pp. 161–196, (2007).
L.Kruyswijk., “Electrorefining of Base Metal Refinery Residue Copper Alloy for Platinum Group Metal Recovery”, M.Sc. Thesis, University of Cape Town, (2009).
Free M., Moats M., Houlachi G., E. Asselin, A. Allanore, J. Yurko and S.Wang, “Electrometallurgy 2012”, Held during the TMS 2012 Annual Meeting & Exhibition, John Wiley & Sons, (2002).
Najim S. T., " Estimation of Mass Transfer Coefficient for Copper Electrowinning Process", Journal of Engineering, Vol.22, p.158-168, (2016)
Ibrahim M., H., Najim S. T., "Determination of Mass Transfer Coefficient for Copper Electrodeposition by Limiting Current Technique", Al-Nahrain Journal for Engineering Sciences, Vol.20 (3), p.666-672, (2017)
Downloads
Published
Issue
Section
License
Copyright (c) 2023 Iraqi Journal of Chemical and Petroleum Engineering
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.