Improved Method to Correlate and Predict Isothermal VLE Data of Binary Mixtures
DOI:
https://doi.org/10.31699/IJCPE.2011.4.4Keywords:
VLE, vapor liquid equilibrium, isothermal data prediction, new thermodynamic relation, VLE of binary mixtures.Abstract
Accurate predictive tools for VLE calculation are always needed. A new method is introduced for VLE calculation which is very simple to apply with very good results compared with previously used methods. It does not need any physical property except each binary system need tow constants only. Also, this method can be applied to calculate VLE data for any binary system at any polarity or from any group family. But the system binary should not confirm an azeotrope. This new method is expanding in application to cover a range of temperature. This expansion does not need anything except the application of the new proposed form with the system of two constants. This method with its development is applied to 56 binary mixtures with 1120 equilibrium data point with very good accuracy. The developments of this method are applied on 13 binary systems at different temperatures which gives very good accuracy.
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