FLUID CATALYTIC CRACKING OF PETROLEUM FRACTION (VACUUM GAS OIL) TO PRODUCE GASOLINE

Authors

  • Abdul Halim A-K Mohammed
  • Karim Khalifa Esgair

DOI:

https://doi.org/10.31699/IJCPE.2010.4.4

Keywords:

Fluid catalytic cracking ; gasoline production ; vacuum gasoil cracking

Abstract

In this work, fluid catalytic cracking of vacuum gas oil to produce gasoline over prepared faujasite type Y zeolite was investigated using experimental laboratory plant scale of fluidized bed reactor.
The catalytic activity of prepared faujasite type NaY, NaNH4Y and NaHY zeolites was investigated. The cracking process was carried out in the temperature range 440 to 500 oC, weight hourly space velocity (WHSV) range 10 to 25 h-1 ,and atmospheric pressure . The catalytic activities of the prepared faujasite type NaY , NaNH4Y and NaHY zeolites were determined in terms of vacuum gas oil (VGO) conversion, and gasoline yield . The conversion at 500oC and WHSV10 hr-1 by using faujasite type NaY, NaNH4Y and NaHY zeolite were 50.2%, 64.1% and 69.5wt% respectively. The gasoline yield using the same operating conditions were 24.8%, 30.5% and 36.8wt% respectively. Gas chromatographic analysis of produced gasoline shows that the paraffin, olefin, and aromatic content change considerably with the end point temperature of gasoline fraction.

References

Barajasa,J.R.H., Roma´na,R.V., and Sotelob,D.S., (2006),“ Multiplicity of steady states in FCC units: effect of operating conditions ”, Fuel, 85, 849–859.

Reza Sadeghbeigi, (2000), “Fluid Catalytic Cracking Handbook Design, Operation and Troubleshooting of FCC Facilities”, Elsevier Inc.

Magee, J. S., and Mitchell, M. M., (1993), “Fluid Catalytic Cracking Science and Technology”, Elsevier, Amsterdam,.

Wilson, J.W., (1997), “Fluid Catalytic Cracking Technology and Operation”, Pennwell, Tulsa,.

Habib, E.T., Zhao, X., Yaluris, G., Cheng, W.C., Boock, L.T., Gilson, J.-P., in: Guisnet, M., Gilson, J.-P.(Eds.), (2002), “Zeolites for Cleaner Technologies”, Imperial College Press, London, , p. 105.

Corma, A., Forne´s, V., Martinez, A. , Melo, F.V. , Pallota, O. , in: Grobet, P., Mortier, W.J., Vansant, E.F., SchulzEkloff, G. (Eds.), (1988), “Innovation in Zeolite Materials Science”, Studies in Surface Science and Catalysis, vol. 37, Elsevier, Amsterdam, , p. 495.

Sie, S.T., in: Jansen, J.C., Sto¨cker, M., Karge, H.G., Weitkamp, J. (Eds.), (1994), “Advanced Zeolite Science and Applications”, Studies in Surface Science and Catalysis, vol. 85, Elsevier, Amsterdam, , p. 587.

Dwyer, F.G., Degnan, T.F., in: Magee, J.S., Mitchell M.M., (Eds.), (1993), “Shape Selectivity in Catalytic Cracking in FCC: Science and Technology”, Studies in Surface Science and Catalysis, vol. 76, Elsevier, Amsterdam, p. 499.

Fu, A., Hunt, D., Bonilla, J. A., and Batachari, A., (1998), “Deep catalytic cracking plant produces propylene in Thailand”, Oil and Gas Journal, January 12, 49–53.

Michael Stocker, (2005),“ Gas phase catalysis by zeolites”, Microporous and Mesoporous Materials, 82, 257–292

Danial Decroocq , ,(1984) ,“Catalytic Cracking of Heavy Petroleum Fractions”, Imprimerir Louis-Jean, Paris.

Weitkamp, J. , Traa, Y. , in: Ertl, G. , Kno' zinger, H., Weitkamp, J. (Eds.), (1997) “Handbook of Heterogeneous Catalysis”, Wiley-VCH, Weinheim, , p. 2039.

Eastwood B.,S.C., Plank,C.J., and Weisz.P.. ,(1971). “Proceedings of the eight word petroleum congress“, vol. 4 p.245. Applied science publishers, London.

Baker,R.W., (1972) “ Presentation at the Davison – Crosfield catalyst symposium” Great British, April 10-11.

Whittington, F.L., Murphy,J.R., and Lutz,I.K., ,(1972) ,Oil and Gas journal , Oct.3059.

Downloads

Published

2010-12-30

How to Cite

A-K Mohammed, A. H., & Khalifa Esgair, K. (2010). FLUID CATALYTIC CRACKING OF PETROLEUM FRACTION (VACUUM GAS OIL) TO PRODUCE GASOLINE. Iraqi Journal of Chemical and Petroleum Engineering, 11(4), 33-45. https://doi.org/10.31699/IJCPE.2010.4.4

Publication Dates