Effect of Operating Cconditions on Hydrodesulfurization of Vacuum Gas Oil

Authors

  • Abdul Halim A. Karim Mohammed
  • Abdul Mun’m A.KARIM
  • Haider A.Areff

DOI:

https://doi.org/10.31699/IJCPE.2008.2.7

Abstract

This study was conducted according to contract with the North Refineries Company-Baiji and deals with the hydrodesulphurization of vacuum gas oil of Kirkuk crude oil, boiling range 611-833 K. A trickle bed reactor packed with a commercial cobalt-molybdenum on alumina catalyst was used. The operating conditions were: temperature range 583-643 K, liquid hourly space velocity range 1.50-3.75 1/h, hydrogen to oil ratio about 250 l/l and pressure kept constant at 3.5MPa.
The results showed that the aromatic content decreased and sulfur removal increased with increasing temperature and decreasing space velocity. The properties (viscosity, density, flash point and carbon residue) of the products decrease with temperature increasing, but the aniline point increased.

References

Mc Culloch, D, C. , Catalytic Hydrotreating in Petroleum Refining, Applied Industrial Catalysis, Ed.B.E. Leach, Akademic Press, Vol. 1, p 69, 1983.

Bartholomew, C. H., Catalyst Deactivation in Hydrotreating of Residue, Applied Industrial Catalysis, Ed. B.E. Leach, Academic Press, Vol. 1, p 64.

Speight, J. G. , The desulfurization of Heavy Oils Residua, 1981.

Hobson, G.D., Modern Petroleum Technology, 5 th Ed.,Part 1, 1984.

Antos, G. J and Wang, L., Successful Commercial Hydrocracking Catalysts, Tools and Methodologies, 2000.

Grirais, M, J and Gates, B. C. , Ind. Eng. Chem. Res., Vol. 30, pp 2021-2058, 1991.

Vicic, D. A and Jones, W. D., Hydrodesulfurization of Thiophene and Benzothiophene to Butane and Ethyl benzene by a Homogeneous Iridium Complex, Organomet.,Voi. 16, pp 1912-1919, 1997.

Antonio Iannibllo, Sergio Marengo, Geriendo Burgio, Glancario Baldi and Vito Specchia, Ind. Eng. Chem. Process Des. Dev., Vol. 24, pp 531-537, 1985.

Mann, R. S, Sambi, L. S and Khulba, C. K., Ind. Eng. Chem. Res, Vol, 27, pp 1788-1792, 1988.

Froment, G. F., Depauw, G, A and Vanrysselberghe, V., Ind. Eng. Chem. Res., Vol. 33, pp 2975-2988, 1994.

Downloads

Published

2008-06-30

How to Cite

A. Karim Mohammed, A. H., A.KARIM, A. M., & A.Areff, H. (2008). Effect of Operating Cconditions on Hydrodesulfurization of Vacuum Gas Oil. Iraqi Journal of Chemical and Petroleum Engineering, 9(2), 57-67. https://doi.org/10.31699/IJCPE.2008.2.7

Publication Dates