Kinetics and Thermodynamics of Peppermint Oil Extraction from Peppermint Leaves


  • Badoor M. Kurji Chemical and Petrochemical Engineering Department, College of Engineering, University of Anbar, Iraq
  • Khalid M. Abed Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
  • Sarmad A. Rashid Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
  • Basma A. Abdulmajeed Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq



hydro-distillation, Arrhenius equation, entropy change, enthalpy change, change in free energy


This study aimed to extraction of essential oil from peppermint leaves by using hydro distillation methods. In the peppermint oil extraction with hydro distillation method is studied the effect of the extraction temperature to the yield of peppermint oil. Besides it also studied the kinetics during the extraction process. Then, 2nd -order mechanism was adopted in the model of hydro distillation for estimation many parameters such as the initial extraction rate, capacity of extraction and the constant rat of extraction with various temperature. The same model was also used to estimate the activation energy. The results showed a spontaneous process, since the  Gibbs free energy had a value negative sign.


Ouazzou A. A. ,Cherrat L., Espina L., Lorán S., Rota C., Pagán R., 2011. The antimicrobial activity of hydrophobic essential oil constituents acting alone or in combined processes of food preservation, Innovative Food Science and Emerging Technologies , 12 ( 3): 320-329.

Kusuma H. S. and Mahfud M., 2017. Microwave hydrodistillation for extraction of essential oil from PogostemoncablinBenth: Analysis and modelling of extraction kinetics, Journal of Applied Research on Medicinal and Aromatic Plants, 4:46-54.

Burt S., 2004. "Essential oils: their antibacterial properties and potential applications in foods—a review, 94 (3): 223-253.

Ali B., Al-Wabel N. A., Shams S., Ahamad A., Khan S. A., and Anwar F., 2015. Essential oils used in aromatherapy: A systemic review, Asian Pacific Journal of Tropical Biomedicine, 5( 8): pp. 601-611.

Tavares A. C., Gonçalves M. J. , Cruz M. T., Cavalerio C., LopesM. C., Canhoto J. and Salgueiro L. R. , 2010.Essential oils from Distichoselinum tenuifolium: chemical composition, cytotoxicity, antifungal and anti-inflammatory properties, Journal of Ethnopharmacology, 130(3): 593-598.

Abed K. M., Kurji B. M., and Abdulmajeed B. A.,2018.Extraction and Modelling of Oil from Eucalyptus camadulensis by Organic Solvent, Journal of Materials Science and Chemical Engineering, 2015(3): 35-42.

Loolaie M., Moasefi N., Rasouli H., and Adibi H.,2017. Peppermint and its functionality: A review, Archive of Clinical Microbiology, 8(4): 1-16.

Dai J., Orsat V., Raghavan G. V., and Yaylayan V., 2010. Investigation of various factors for the extraction of peppermint (Mentha piperita L.) leaves, Journal of Food Engineering, 96 (4): 540-543.

Grigoleit H.-G. and GrigoleitP. , 2005. Gastrointestinal clinical pharmacology of peppermint oil, Phytomedicine, 12(8): 607-611.

Gavahian M., Farahnaky A., Javidnia K., Majzoobi M. J. and Technologies E., 2012. Comparison of ohmic-assisted hydrodistillation with traditional hydrodistillation for the extraction of essential oils from Thymus vulgaris L, Innovative Food Science & Emerging Technologies (14) : 85-91.

Grigoleit H.-G. and Grigoleit P. J. P., 2005. Pharmacology and preclinical pharmacokinetics of peppermint oil, Phytomedicine, 12(8): 612-616.

Jeyaratnam N., Nour A. H., Kanthasamy R., Nour A. H., Yuvaraj A. R. and Akindoyo J. O. ,2016. Essential oil from Cinnamomum cassia bark through hydrodistillation and advanced microwave assisted hydrodistillation, Industrial Crops and Products, 92: pp. 57-66.

Rabesiaka L. R., Havet J. L., Porte C., Fauduet H., 2007. Solid–liquid extraction of protopine from Fumaria officinalis L.—analysis determination, kinetic reaction and model building, Separation and Purification Technology, 54(2): 253-261.

Abdulraheem I. F., Al-Rubaye R. T., Abed K. M. and Abdulmajeed B. A., 2019. Extraction of jojba oil using various concentrations of two different solvents, Iraqi Journal of Agricultural Sciences, 50(4): under press.

Eikani M. H., Golmohammad F., Homami S. S., 2012. Extraction of pomegranate (Punicagranatum L.) seed oil using superheated hexane, Food and Bioproducts Processing, 90(1): 32-36.

Kusuma H. and Mahfud M., 2018. Kinetic studies on extraction of essential oil from sandalwood (Santalum album) by microwave air-hydrodistillation method, Alexandria Engineering Journal, 57(2): 1163-1172.

Sulaiman S., Aziz A. A., and Aroua M. K., 2013. Optimization and modeling of extraction of solid coconut waste oil, Journal of Food Engineering, 114 (2): 228-234.

Abed K. M. and Naife T. M., 2018. Extraction of Essential Oil from Iraqi Eucalyptus Camadulensis Leaves by Water Distillation Methods," in IOP Conference Series: Materials Science and Engineering, 454 (1): 012163: IOP Publishing.

Ho Y.-S., Harouna-Oumarou H. A., Fauduet H. and Porte C. , 2005. Kinetics and model building of leaching of water-soluble compounds of Tilia sapwood, Separation and Purification Technology, 45(3):169-173.

Meziane S. and Kadi H., 2008. Kinetics and thermodynamics of oil extraction from olive cake, J Am Oil Chem Soc, 85:391–396.

Uhm J. T. and Yoon W. B., 2011. Effects of high‐pressure process on kinetics of leaching oil from soybean powder using hexane in batch systems, Journal of Food Science, 76(6): E444-E449.

Abed K. M., Kurji B. M., and Abdulmajeed B. A.,2018. Extraction of Ocimumbasillicum Oil by Solvents Methods," Asian Journal of Chemistry, 30(5): 958-960.

Azmir J., Zaidul I. S. M., Rahman M. M., Sharif K. M., Mohamed A., Shahen F., Jahurul M. H. A., Ghafoor K., Norulaini N. A. and Omar A. K. M. ,2013. Techniques for extraction of bioactive compounds from plant materials: a review, Journal of Food Engineering, 117 (4): 426-436.

Khasawneh R. F., 2017. Leaching of Jojoba Oil , Journal of Natural Sciences Research, 7(10): 49-62.

TOPALLAR H. and GEÇGEL Ü., 2000. Kinetics and Thermodynamics of Oil Extraction from Sun ower Seeds in the Presence of Aqueous Acidic, Turkish Journal of Chemistry, 24(3): 247-254.

Rodrigues C. E., Aracava K. K. and Abreu F. N., 2010. Thermodynamic and statistical analysis of soybean oil extraction process using renewable solvent, International Journal of Food Science and Technology, 45(11): 2407-2414.




How to Cite

M. Kurji, B., Abed, K. M., A. Rashid, S., & A. Abdulmajeed, B. (2019). Kinetics and Thermodynamics of Peppermint Oil Extraction from Peppermint Leaves. Iraqi Journal of Chemical and Petroleum Engineering, 20(4), 1-6.

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