The Decolorization of Reactive Yellow Dye by Advanced Oxidation Using Continuous Reactors
DOI:
https://doi.org/10.31699/IJCPE.2020.2.1Keywords:
Reactive yellow; Photo-degradation; advanced oxidation processes; Wastewater.Abstract
The reactive yellow azo dye (λmax = 420 nm) is widely utilized for textile coloring due to its low-cost stability and tolerance properties. Treatment of dye-containing wastewater by traditional methods is usually inadequate because of its resistance to biological and chemical degradation. From this research, the continuous reactor of an advanced oxidation method supported the use of H2O2/TiO2/UV to remove the coloration of the reactive yellow dye from the discharge. At constant best conditions obtained from the batch reactor tests pH=7, H2O2 dosage = 400 mg/l and TiO2=25mg/l , the aqueous solutions were tested in the continuous reactor at different dye concentration and different flow rates . The maximum removal efficiency was found to be 91.552% obtained at the flow rate 5 l/h, also the results of decomposition information proved that method was pseudo-first-order kinetics.
Received on 09/09/2019
Accepted on 31/10/2019
Published on 30/06/2020
References
Grčića I., and Koprivanaca N. (2018) Photocatalytic Oxidation of Azo Dyes and Oxalic Acid in Batch Reactors and CSTR: Introduction of Photon Absorption by Dyes to Kinetic Models .Chem. Biochem. Eng. Q., 32 (1) 71–81.
W. Taher Mohammed, H. F. Farhood, and A. Hassoon Bjaiyah Al-Mas’udi, “Removal of Dyes from Wastewater of Textile Industries Using Activated Carbon and Activated Alumina”, ijcpe, vol. 10, no. 1, pp. 43-52, Mar. 2009.
I. Faisal, “Removal of dyes from polluted water by adsorption on maize cob”, ijcpe, vol. 11, no. 1, pp. 55-57, Mar. 2010.
Mahmoodi N. Mohammad, Arami M., Limaee N. Yousefi, Tabrizi N. Salman (2006) “Kinetics of heterogeneous photocatalytic degradation of reactive dyes in an immobilized TiO2 photocatalytic reactor”. Journal of Colloid and Interface Science 295,159–164.
Reza, Khan Mamun, A. S. W. Kurny, and Fahmida Gulshan. "Parameters affecting the photocatalytic degradation of dyes using TiO 2: a review." Applied Water Science 7.4 (2017): 1569-1578.
F. M. Hameed and K. M. Mousa, “Study on Kinetic and Optimization of Continuous Advanced Oxidative Decolorization of Brilliant Reactive Red Dye”, ijcpe, vol. 20, no. 1, pp. 9-14, Mar. 2019.
Krishnan, S., Rawindran, H., Sinnathambi, C. M., & Lim, J. W. "Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants." IOP Conf. Ser. Mater. Sci. Eng. Vol. 206. No. 1. 2017.
Huang, M., Xu, C., Wu, Z., Huang, Y., Lin, J., and Wu, J.(2008) “Photocatalytic discolorization of methyl orange solution by Pt modified TiO2 loaded on natural zeolite,” Dye. Pigment., vol. 77, no. 2, pp. 327–334.
Zhiyong, Yu, H. Keppner, D. Laub, E. Mielczarski, J. Mielczarski, L. Kiwi-Minsker, A. Renken, and J. Kiwi. "Photocatalytic discoloration of Methyl Orange on innovative parylene–TiO2 flexible thin films under simulated sunlight." Applied Catalysis B: Environmental 79.1 (2008): 63-71.
Senthilkumaar, S., K. Porkodi, and R. Vidyalakshmi. "Photodegradation of a textile dye catalyzed by sol–gel derived nanocrystalline TiO2 via ultrasonic irradiation." Journal of Photochemistry and Photobiology A: Chemistry 170.3 (2005): 225-232.
Khan W., I. Najeeb, and S. Ishtiaque, (2016).“Photocatalytic degradation of a real textile wastewater using titanium dioxide, zinc oxide and hydrogen peroxide,” Int J Eng Sci, vol. 5, no. 7, pp.61–70.
Ali abd al hassan, 2017, “Treatment of produced water by Advanced Oxidation Processes”, M.SC., Thesis, Al-Nahrain University College of Engineering.
Chaudhuri, M., Elmolla, E. S. and Othman, R., 2009," Removal of Reactive Dyes from Aqueous Solution by Adsorption Coconut Coir Activated Carbon", 2nd International Conference on Engineering Technology (ICET 2009), December, Kuala Lumpur.
Saggioro E. M., Oliveira A. S., Thelma Pavesi, Cátia Gil Maia, et al.,(2011). “Use of Titanium Dioxide Photocatalysis on the Remediation of Model Textile Wastewaters Containing Azo Dyes” .Molecules ,vol.16, 10370-10386.
Thamaraiselvi K., Sivakumar T., Brindha A. , and Elangovan E. (2019). “Photocatalytic Degradation of Reactive Dyes Over Titanates”.Journal of Nanoscience and Nanotechnology.Vol. 19, 2087–2098.
Mitrović, Jelena, et al. "Decolorization of textile azo dye reactive orange 16 with UV/H2O2 process." Journal of the Serbian Chemical Society 77.4 (2012): 465-481.
Salman M. S., (2014). “Advanced Oxidation Processes for the Removal of Reactive Dyes from Simulated Wastewater”. Ph.D. Thesis, College of Engineering, University of Baghdad.
Crittenden, John C., R. Rhodes Trussell, David W. Hand, Kerry J. Howe, and George Tchobanoglous. MWH's water treatment: principles and design. John Wiley & Sons, 2012.
Qourzal, S., Tamimi, M., Assabbane, A. and Ait-Ichou, Y. (2007) TiO2 Photocatalytic Mineralization of β-Naphthol: Influence of Some Inorganic Ions, Ethanol, and Hydrogen Peroxide. Comptes Rendus Chimie, 10, 1187-1194.
Behnajady MA, Modirshahla N, Hamzavi R. Kinetic study on photocatalytic degradation of C.I. Acid Yellow 23 by ZnO photocatalyst.( 2006). J Hazard Mater. B 133; 226–232.
Muruganandham M. Swaminathan, 2004. “Photochemical oxidation of reactive azo dye with UV–H2O2 process”. Dyes and Pigments 62,269–275 .
Swaminathan K., Sandhya S., Carmalin S. A., Pachhade K., Subrahmanyam V. Y., (2003) “Decolorization and degradation of H-acid and other dyes using ferrous–hydrogen peroxide system”, Chemosphere , 50, pp. 619–625.
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