Investigation of Ozone Microbubbles for the Degradation of Methylene Orange Contaminated Wastewater
DOI:
https://doi.org/10.31699/IJCPE.2020.2.4Keywords:
Methylene orange, Ozone microbubble, Ozone generation rate, Removal efficiencyAbstract
In the present study, semi – batch experiments were conducted to investigate the efficiency of ozone microbubbles (OMBs) in the treatment of aqueous dye solutions methylene orange under different reaction conditions such as effect of initial solution pH , ozone generation rate and initial MO-concentration. The results showed that the removal of MO by OMBs were very high at the acidic and alkaline media and upon increasing the generation rate of ozone from 0.498 to 0.83 mg/s, the removal efficiency dramatically increased from 75to 100% within 15 min. The rate of oxidation reaction followed a pseudo first- order kinetic model. The results demonstrated that OMBs is efficient in terms of the decline of methylene orange concentration and its total mineralization.
Received on 13/10/2019
Accepted on 23/02/2020
Published on 30/06/2020
References
Ali, I.; Asim, M.; Khan, T.A. Low cost adsorbents for the removal of organic pollutants from wastewater. J. Environ. Manag. 2012, 113, 170–183.
Ramakrishna, K. R., & Viraraghavan, T. (1997). Dye removal using low cost adsorbents. Water Science and Technology, 36(2-3), 189–196.
Oliver J. Hao , Hyunook Kim & Pen-Chi Chiang (2000) Decolorization of Wastewater, Critical Reviews in Environmental Science and Technology, 30:4, 449-505.
M. A. Hanoon and M. J. Ahmed(2019). Adsorption of Methyl Orange from Wastewater by using Biochar. Iraqi Journal of Chemical and Petroleum Engineering, Vol.20 No.3 (September 2019).
Carmen, Z., & Daniel, S. (2012). Textile Organic Dyes – Characteristics, Polluting Effects and Separation/Elimination Procedures from Industrial Effluents – A Critical Overview. Organic Pollutants Ten Years After the Stockholm Convention - Environmental and Analytical Update.
A. Abbas Najim and A. A. Mohammed, “Biosorption of Methylene Blue from Aqueous Solution Using Mixed Algae”, ijcpe, vol. 19, no. 4, pp. 1-11, Dec. 2018.
Jones, K.C.; De Voogt, P. Persistent organic pollutants (POPs): State of the science. Environ. Pollut. 1999, 100, 209–221.
Liu, Z.; Kanjo, Y.; Mizutani, S. Removal mechanisms for endocrine disrupting compounds (EDCs) in wastewater treatment- physical means, biodegradation, and chemical advanced oxidation: A review. Sci. Total Environ. 2009, 407, 731–748.
Ikehata, K.; Gamal EI-Din, M.; Snyder, S.A. Ozonation and advanced oxidation treatment of emerging organic pollutants in water and wastewater. Ozone-Sci. Eng. 2008, 30, 21–26.
Lefebvre, O.; Moletta, R. Treatment of organic pollution in industrial saline wastewater: A literature review. Water Res. 2006, 40, 3671–3682.
Sun, L.; Li, Y.; Li, A.M. Treatment of actual chemical wastewater by a heterogeneous fenton process using natural pyrite. Int. J. Environ. Res. Public Health 2015, 12, 13762–13778.
Asghar, A.; Raman, A.A.A.; Daud, W.M.A.W. Advanced oxidation processes for in-sit production of hydrogen peroxide/hydroxyl radicals for textile wastewater treatment: A review. J. Clean. Prod. 2015, 87, 826–838.
Oturan, M.A.; Aaron, J.J. Advanced oxidation processes in water/wastewater treatment: Principles and applications. A review. Crit. Rev. Env. Sci. Technol. 2014, 44, 2577–2641.
Llyas, H.; Masih, L.; van der Hoek, J.P. Disinfection methods for swimming pool water: Byproduct formation and control. Water 2018, 10, 797.
Gomes, J.; Costa, R.; Quinta-Ferreira, R.M.; Martins, R.C. Application of ozonation for pharmaceuticals and personal care products removal from water. Sci. Total Environ. 2017, 586, 265–283.
Oller, I.; Malato, S.; Sánchez-Pérez, J.A. Combination of advanced oxidation processes and biological treatments for wastewater decontamination—A review. Sci. Total Environ. 2011, 409, 4141–4166.
Zhang, F., Xi, J., Huang, J.-J., Hu, H.-Y., 2013. Effect of inlet ozone concentration on the performance of a micro-bubble ozonation system for inactivation of Bacillus subtilis spores. Sep. Purif. Technol. 114, 126e133.
Seddon, J.R.T.; Lohse, D.; Ducker, W.A.; Craig, V.S.J. A deliberation on nanobubbles at surfaces and in bulk. ChemPhysChem 2012, 13, 2179–2187.
Li, H.; Hu, L.; Song, D.; Lin, F. Characteristics of micro-nano bubbles and potential application in groundwater bioremediation. Water Environ. Res. 2014, 86, 844–851.
Agarwal, A.; Ng, W.J.; Liu, Y. Principle and applications of microbubble and nanobubble technology for water treatment. Chemosphere 2011, 84, 1175–1180.
Hu, L.M.; Xia, Z.R. Application of ozone micro-nano-bubbles to groundwater remediation. J. Hazard. Mater. 2018, 342, 446–453.
Jabesa, A., & Ghosh, P. (2016). Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant. Journal of Environmental Management, 180, 476–484.
F.Banat, S. Al.-Asheh, M. Al.-Rawashdeh, M. Nusair, “Photodegradation of methylene blue dye by UV/H2O2 and UV/acetone oxidation processes”, Desalination, 181(2005)225.
Chu W. and Chi-Wai M. (1999). Quantitative prediction of direct and indirect dye ozonation kinetics. Water Res. 34 (12), 3153-3160.
Yurteri, C., and Gürol, M.D. (1988). Ozone Consumption in Natural Waters: Effects of Background Organic Matter, pH and Carbonate Species. Ozone Sci. Eng., 10, 272- 282.
Lopez-Lopez, A., Pic, J.S., Debellefontaine, H. (2007). Ozonation of azo dye in a semi-batch reactor: A determination of the molecular and radical contributions, Chemosphere, 66(11), 2120-2126.
Soares G.P., Saloma O., Orfao J.J.M., Portela D., Vieira A., Pereira M.R., (2006), Ozonation of Textile Effluents and Dye Solutions under Continuous Operation: Influence of Operating Parameters. J. Hazard. Mater. B137, 1664- 1673.
Hoigne, J., Bader, H., 1983. Rate constants of reactions of ozone with organic and inorganic compounds in watereI: non-dissociating organic compounds. Water Res. 17 (2), 173-183.
Park J.S., Choi H., Cho J. (2004). Kinetic decomposition of ozone and parachlorobenzoic acid (p-CBA) during catalytic ozonation. Water Res. 38(9), 2285-2292.
Oyama, S.T. (2000). Chemical and Catalytic Properties of Ozone. Catal. Today, 42(3), 279-322.
Staehelin, J. and Hoigne, J. (1985). Decomposition of Ozone in Water in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactions. Environ. Sci. Technol., 19(12), 1206-1213.
Ayana SHIMIZU , Yasuhiko TAKUMA , Shigeru KATO , Akihiro YAMASAKI, Toshinori KOJIMA , Kohei URASAKI , Shigeo SATOKAWA. Degradation kinetics of azo dye by ozonation in water, J. Fac. Sci.Tech., Seikei Univ. Vol.50 No.2 (2013)pp.1-4.
Beltran, F.J., 2004. Ozone Reaction Kinetics for Water and Wastewater Systems. Lewis Publishers, Boca Raton.
Staehelin, J., Buehler, R.E., Hoigne, J., Ozone decomposition in water studied by pulse radiolysis. 2. Hydroxyl and hydrogen tetroxide (HO4) as chain intermediates. J. Phys. Chem. 88 (24), 5999-6004, 1984.
Tomiyasu, H., Fukutomi, H., Gordon, G., Kinetics and mechanism of ozone decomposition in basic aqueous solution. Inorg. Chem. 24 (19), 2962-2966, 1985.
Gardoni, D., Vailati, A., Canziani, R., 2012. Decay of ozone in water: a review. Ozone Sci. Eng. 34 (4), 233-242.
Sehested, K., Corfitzen, H., Holcman, J., Fischer, C.H., Hart, E.J., 1991. The primary reaction in the decomposition of ozone in acidic aqueous solutions. Environ. Sci. Technol. 25 (9), 1589-1596.
Khuntia, S., Majumder, S.K., Ghosh, P., Quantitative prediction of generation of hydroxyl radicals from ozone microbubbles. Chem. Eng. Res. Des. 98, 231-239, 2015.
Rice R. G., "Applications of ozone for industrial wastewater treatment": A review. Ozone Sci. & Eng. 18, 477-515, 1996.
Grabowski, L. R., Veldhuizen, E. M. van, Pemen, A. J. M., & Rutgers, W. R. "Breakdown of methylene blue and methyl orange by pulsed corona discharge". Plasma Sources Science and Technology, 16(2), 226–232, 2007.
Chen, L.C. Effects of factors and interacted factors on the optimal decolorization process of methyl orange by ozone. Water Res. 2000, 34, 974–982.
Petrella, A.; Mascolo, G.; Murgolo, S.; Petruzzelli, V.; Ranieri, E.; Spasiano, D.; Petruzzelli, D. Photocatalytic oxidation of organic micro-pollutants: Pilot plant investigation and mechanistic aspects of the degradation reaction. Chem. Eng. Commun. 2016, 203, 1298–1307.
Devi, L.G.; Kumar, S.G.; Reddy, K.M.; Munikrishnappa, C. Photo degradation of methyl orange an azo dye by advanced Fenton process using zero valent metallic iron: Influence of various reaction parameters and its degradation mechanism. J. Hazard. Mater. 2009, 164, 459–467.
Ge, D.M.; Zeng, Z.Q.; Arowo, M.; Zou, H.K.; Chen, J.F.; Shao, L. Degradation of methyl orange by ozone in the presence of ferrous and persulfate ions in a rotating packed bed. Chemosphere 2016, 146, 413–418.
Sevimli, M.F.; Sarikaya, H.Z. Ozone treatment of textile effluents and dyes: Effect of applied ozone dose, pH and dye concentration. J. Chem. Technol. Biotechnol. 2002, 77, 842–850.
Constapel, M.; Schellenträger, M.; Marzinkowski, J.M.; Gäb, S. Degradation of reactive dyes in wastewater from the textile industry by ozone: Analysis of the products by accurate masses. Water. Res. 2009, 43, 733–743.
Khuntia S, Majumder SK, Ghosh P. Removal of ammonia from water by ozone microbubbles. Ind Eng Chem Res. 2013;52:318–326.
Sotelo JL, Beltrán FJ, Benitez FJ, et al. Henry’s law constant for the ozone–water system. Water Res. 1989;23:1239– 1246.
Sotelo JL, Beltran FJ, Benitez FJ, et al. Ozone decomposition in water: kinetic study. Ind Eng Chem Res. 1987;26:39–43.
Gao M-T, Hirata M, Takanashi H, et al. Ozone mass transfer in a new gas–liquid contactor – Karman contactor. Sep Purif Technol. 2005;42:145–149.
Kukuzaki M, Fujimoto K, Kai S, et al. Ozone mass transfer in an ozone–water contacting process with Shirasu porous glass (SPG) membranes – a comparative study of hydrophilic and hydrophobic membranes. Sep Purif Technol. 2010;72:347–356.
YC Hsu, TY Chen, JH Chen and C. W. Lay, Ozone transfer into water in a gas-inducing reactor. Ind Eng Chem Res. 2002; 41:120–127.
Grima, N. M. M. Kinetic and mass transfer studies of ozone degradation of organics in liquid/gas-ozone and liquid/solid-ozone systems. Diss. University of Bradford, 2009.
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