Synthesis and Characterization of Nano Y Zeolite Using MWCNT as Media for Crystal Growth
DOI:
https://doi.org/10.31699/IJCPE.2019.4.8Keywords:
Carbon nanotube, catalytic synthesis, Nano Y zeolite, MWCNTAbstract
The present research was conducted to synthesis Y-Zeolite by sol-gel technique using MWCNT (multiwalled carbon nanotubes) as crystallization medium to get a narrow range of particle size distribution with small average size compared with ordinary methods. The phase pattern, chemical structure, particle size, and surface area were detected by XRD, FTIR, BET and AFM, respectively. Results shown that the average size of Zeolite with and without using MWCNT were (92.39) nm and (55.17) nm respectively .Particle size range reduced from (150-55) nm to (130-30) nm. The surface area enhanced to be (558) m2/g with slightly large pore volume (0.231) km3/g was obtained. Meanwhile, degree of crystallization decreased to 120%.
Received on 21/01/2019
Accepted on 25/02/2019
Published on 30/12/2019
References
Zeng Y., JuShengui,* Xing Weihong and Chen Changlin, 2008 ," Adsorption of Mercaptan from Model Gasoline on 13X Loaded with ZN2+", the Canadian journal of chemical engineering, 86,186-187.
Mirfendereski, Mojtaba, and Toraj Mohammadi. "Effects of Synthesis Parameters on the Characteristics of Naa Type Zeolite Nanoparticles." Proceedings of the World Congress on Recent Advances in Nanotechnology (RAN’16). 2016.
Severance, Michael A. Nanocrystalline Zeolites: Synthesis, Mechanism, and Applications. Diss. The Ohio State University, 2014.
Ansari, M., Aroujalian, A., Raisi, A., Dabir, B. and Fathizadeh, M., 2014. Preparation and characterization of nano-NaX zeolite by microwave assisted hydrothermal method. Advanced Powder Technology, 25(2), pp.722-727.
Chen, X., Wendell, K., Zhu, J., Li, J., Yu, X. and Zhang, Z., 2012. Synthesis of nano-zeolite from coal fly ash and its potential for nutrient sequestration from anaerobically digested swine wastewater. Bioresource technology, 110, pp.79-85.
Valtchev, V.P., Tosheva, L. and Bozhilov, K.N., 2005. Synthesis of zeolite nanocrystals at room temperature. Langmuir, 21(23), pp.10724-10729.
Lee, N. S., et al. "Application of carbon nanotubes to field emission displays." Diamond and related materials 10.2 (2001): 265-270.
Fonseca, A., Hernadi, K., Piedigrosso, P., Colomer, J.F., Mukhopadhyay, K., Doome, R., Lazarescu, S., Biro, L.P., Lambin, P., Thiry, P.A. and Bernaerts, D., 1998. Synthesis of single-and multi-wall carbon nanotubes over supported catalysts. Applied Physics A, 67(1), pp.11-22.
C. Baerlocher, Meier, L.B. McCusker, D.H. Olson, “Atlas of Zeolite Framework Types”,6th Edition, Elsevier, Amsterdam (2007).
Treacy M.M.J. and Higgins J.B., 2001, “Collection of Simulated XRD Powder Patterns for Zeolites”, 4th edition Amsterdam: Elsevier,
Zhang, W., Bao, X., Guo, X., and Wang, X. (1999). A high-resolution solid-state NMR study on nano-structured HZSM-5 zeolite. Catal. Lett. 60:89–94.
Ban and Nada S., 2016. AbdaulRahman Catalytic Reforming of Naphtha Using Novel Prepared Pt-Ti / HY Zeolite chemical engineering department thesis
Iver Schmidt, I., Boisen, A., Gustavsson, E., Ståhl, K., Pehrson, S., Dahl, S., Carlsson, A. and Jacobsen, C.J., 2001. Carbon nanotube templated growth of mesoporous zeolite single crystals. Chemistry of Materials, 13(12), pp.4416-4418.
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