Adsorption Isotherms and Isosteric Heat of Adsorption of Metal Organic Frameworks as Gas Storage for Liquefied Petroleum Gas Vehicle in Iraq
Keywords:metal organic frameworks, liquefied petroleum gas, adsorbed natural gas, Isosteric heat of Adsorption
This research provides a novel technique for using metal organic frameworks (HKUST-1) as a gas storage system for liquefied petroleum gas (LPG) in Iraqi vehicles to avoid the drawbacks of the currently employed method of LPG gas storage. A low-cost adsorbent called HKUST-1 was prepared and characterized in this research to investigate its ability for propane storage at different temperatures (25, 30, 35, and 40 oC) and pressures of (1-7) bar. HKUST-1 was made using a hydrothermal method and characterized using powder X-ray diffraction, BET surface area, scanning electron microscopic (SEM), and Fourier Transforms infrared spectroscopy (FTIR). The HKUST-1 was produced using a hydrothermal technique and possesses a high crystallinity of up to 97%, surface area 3400 m2/g, and pore volume 0.7 cm3/g. The prepared adsorbent (HKUST-1) tested using volumetric method, the maximum adsorption capacity of propane was (10.499 mmol/g) at a temperature of 298K and a pressure of 7 bar. Furthermore, adsorption isotherm study was conducted to understand the system equilibrium (i.e., the fitting with one of the known models Langmuir, Freundlich, and Temkin isotherm models). It was observed that the Freundlich isotherm model fitted well the experimental data. The Clausius-Clapeyron equation was used to determine the heat of adsorption, and the results revealed that the heat of adsorption increased as the propane adsorption capacity increased. The prepared HKUST-1, which has a large surface area and a high adsorption capacity, can be used as a major solution for gas storage for liquefied petroleum gas (LPG) in Iraqi vehicles.
Müller, U., Hesse, M., Pütter, H. and Yaghi, O.M., BASF SE and University of Michigan, 2008. Metal-organic framework materials for gaseous hydrocarbon storage. U.S. Patent 7,343,747.
Demirbas, A., 2002. Fuel properties of hydrogen, liquefied petroleum gas (LPG), and compressed natural gas (CNG) for transportation. Energy Sources, 24(7), pp.601-610.
Arapatsakos, Karkanis, Katirtzoglou and Pantokratoras, 2008. Liquid Petroleum Gas (LPG) and Natural Gas (NG) as fuels on diesel engine–dual fuel engine .Recent Advances in Fluid Mechanics and Heat & Mass Transfer, 154-161.
Raslavičius, L., Keršys, A., Mockus, S., Keršienė, N. and Starevičius, M., 2014. Liquefied petroleum gas (LPG) as a medium-term option in the transition to sustainable fuels and transport. Renewable and Sustainable Energy Reviews, 32, pp.513-525.
Makal, T.A., Li, J.R., Lu, W. and Zhou, H.C., 2012. Methane storage in advanced porous materials. Chemical Society Reviews, 41(23), pp.7761-7779.
Mason, J.A., Veenstra, M. and Long, J.R., 2014. Evaluating metal–organic frameworks for natural gas storage. Chemical Science, 5(1), pp.32-51.
Dobrota, Đ., Lalić, B. and Komar, I., 2013. Problem of boil-off in LNG supply chain. Transactions on maritime science, 2(02), pp.91-100.
Chang, K.J. and Talu, O., 1996. Behavior and performance of adsorptive natural gas storage cylinders during discharge. Applied Thermal Engineering, 16(5), pp.359-374.
Mota, J.B., Rodrigues, A.E., Saatdjian, E. and Tondeur, D., 1997. Dynamics of natural gas adsorption storage systems employing activated carbon. Carbon, 35(9), pp.1259-1270.
Chui, S.S.Y., Lo, S.M.F., Charmant, J.P., Orpen, A.G. and Williams, I.D., 1999. A chemically functionalizable nanoporous material [Cu3 (TMA)2 (H2O)3] n. Science, 283(5405), pp.1148-1150.
Menon, V.C. and Komarneni, S., 1998. Porous adsorbents for vehicular natural gas storage: a review. Journal of Porous Materials, 5(1), pp.43-58.
Morris, R.E. and Wheatley, P.S., 2008. Gas storage in nanoporous materials. Angewandte Chemie International Edition, 47(27), pp.4966-4981.
Furukawa, H., Ko, N., Go, Y.B., Aratani, N., Choi, S.B., Choi, E., Yazaydin, A.Ö., Snurr, R.Q., O’Keeffe, M., Kim, J. and Yaghi, O.M., 2010. Ultrahigh porosity in metal-organic frameworks. Science, 329(5990), pp.424-428.
Perry Iv, J.J., Perman, J.A. and Zaworotko, M.J., 2009. Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks. Chemical Society Reviews, 38(5), pp.1400-1417.
Yaghi, O.M., O'Keeffe, M., Ockwig, N.W., Chae, H.K., Eddaoudi, M. and Kim, J., 2003. Reticular synthesis and the design of new materials. Nature, 423(6941), pp.705-714.
Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O'keeffe, M. and Yaghi, O.M., 2001. Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal− organic carboxylate frameworks. Accounts of chemical research, 34(4), pp.319-330.
Li, J.R., Kuppler, R.J. and Zhou, H.C., 2009, “Selective gas adsorption and separation in metal–organic frameworks”, Chemical Society Reviews, 38(5), pp.1477-1504.
Kareem, H.M. and Alrubaye, R.T.A., 2019, “Synthesis and Characterization of Metal Organic Frameworks for Gas Storage”, In IOP Conference Series: Materials Science and Engineering, 518(6), p. 062013.
Li, H., Li, L., Lin, R.B., Zhou, W., Zhang, Z., Xiang, S. and Chen, B., 2019, “Porous metal-organic frameworks for gas storage and separation: Status and challenges”, EnergyChem, 1(1), p.100006.
Jarvelin, H. and Fair, J.R., 1993, “Adsorptive separation of propylene-propane mixtures”, Industrial & engineering chemistry research, 32(10), pp.2201-2207.
Divekar, S., Nanoti, A., Dasgupta, S., Chauhan, R., Gupta, P., Garg, M.O., Singh, S.P. and Mishra, I.M., 2016, “Adsorption equilibria of propylene and propane on zeolites and prediction of their binary adsorption with the ideal adsorbed solution theory”, Journal of chemical & engineering data, 61(7), pp.2629-2637.
Bao, Z., Alnemrat, S., Yu, L., Vasiliev, I., Ren, Q., Lu, X. and Deng, S., 2011, “Adsorption of ethane, ethylene, propane, and propylene on a magnesium-based metal–organic framework”, Langmuir, 27(22), pp.13554-13562.
Abedini, H., Shariati, A. and Khosravi-Nikou, M.R., 2020. Adsorption of propane and propylene on M-MOF-74 (M= Cu, Co): Equilibrium and kinetic study. Chemical Engineering Research and Design, 153, pp.96-106.
Hill, P., Al-Janabi, N., Torrente-Murciano, L., Garforth, A., Gorgojo, P., Siperstein, F., & Fan, X., 2015, “Mapping the Cu-BTC metal–organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases”, Chemical Engineering Journal, 281, pp. 669–677.
Li, Y., Wang, L.-J., Fan, H.-L., Shangguan, J., Wang, H., & Mi, J., 2015, “Removal of sulfur compounds by a copper-based metal organic framework under ambient conditions”, Energy and Fuels, 29(1), pp. 298–304.
Ahmed J .M, 2005, “Adsorption of Light Hydrocarbons by Molecular Sieves”, Ph.D. Thesis, College of Engineering, Baghdad University.
Smith, J. M., Van Ness, H.C. and Abbot, M. M. (2005) Introduction to Chemical Engineering Thermodynamics, 7th ed., New York, McGraw-Hill.
Furukawa, H. (2018) Synthesis and Characterization of Metal–Organic Frameworks.in: Glover, T.G. and Mu, B. (eds.) Gas adsorption in metal-organic frameworks: Fundamentals and applications. CRC Press., pp.19-70.
Langmuir, I., 1918. The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical society, 40(9), pp.1361-1403.
Freundlich, H.K., 1909. eine Darstellung der Chemie der Kolloide und verwandte Gebiete. Kapillarchemie. Leipzig.
Tempkin, M.I. and Pyzhev, V.J.A.P.C., 1940. Kinetics of ammonia synthesis on promoted iron catalyst. Acta Phys. Chim. USSR, 12(1), p.327.
Tsivadze, A.Y., Aksyutin, O.E., Ishkov, A.G., Knyazeva, M.K., Solovtsova, O.V., Men’shchikov, I.E., Fomkin, A.A., Shkolin, A.V., Khozina, E.V. and Grachev, V.A., 2019. Metal-organic framework structures: Adsorbents for natural gas storage. Russian Chemical Reviews, 88(9), p.925.
Du, Z., Nie, X., Deng, S., Zhao, L., Li, S., Zhang, Y. and Zhao, J., 2020, “Comparative analysis of calculation method of adsorption isosteric heat: Case study of CO2 capture using MOFs”, Microporous and Mesoporous Materials, 298, p.110053.
Sumida, K., Rogow, D.L., Mason, J.A., McDonald, T.M., Bloch, E.D., Herm, Z.R., Bae, T.H. and Long, J.R., 2012. Carbon dioxide capture in metal–organic frameworks. Chemical reviews, 112(2), pp.724-781.
Nuhnen, A. and Janiak, C., 2020, “A practical guide to calculate the isosteric heat/enthalpy of adsorption via adsorption isotherms in metal–organic frameworks, MOFs”, Dalton Transactions, 49(30), pp.10295-10307.
Alyassiry, A.A. and Alrubaye, R.T.A., 2020, March. Desulfurization of model gasoline using metal organic frame-work. In AIP Conference Proceedings (Vol. 2213, No. 1, p. 020090). AIP Publishing LLC.
Hoang, T. C., Nguyen Thi, T. V., Luu, C. L., Nguyen, T., Bui, T. H., Duy Nguyen, P. H., & Pham Thi, T. P., 2013, “Synthesis of MOF-199 and application to CO2 adsorption”, Advances in Natural Sciences: Nanoscience and Nanotechnology, 4(3), p. 035016.
Alrubaye, R.T.A. and Kareem, H.M., 2019, “Carbon Dioxide Adsorption on MOF-199 Metal-Organic Framework at High Pressure”, In IOP Conference Series: Materials Science and Engineering, 557(1), p. 012060.
Lin, K. S., Adhikari, A. K., Ku, C. N., Chiang, C. L., & Kuo, H. (2012) ‘Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage’, International Journal of Hydrogen Energy. Elsevier Ltd, 37(18), pp. 13865–13871.
Lamia, N., Jorge, M., Granato, M.A., Paz, F.A.A., Chevreau, H. and Rodrigues, A.E., 2009, “Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment”, Chemical Engineering Science, 64(14), pp.3246-3259.
Rubes, M., Wiersum, A.D., Llewellyn, P.L., Grajciar, L., Bludsky, O. and Nachtigall, P., 2013. Adsorption of propane and propylene on CuBTC metal–organic framework: combined theoretical and experimental investigation. The Journal of Physical Chemistry C, 117(21), pp.11159-11167.
Ponraj, Y.K. and Borah, B., 2020. Separation of methane from ethane and propane by selective adsorption and diffusion in MOF Cu-BTC: A molecular simulation study. Journal of Molecular Graphics and Modelling, 97, p.107574.
Tóth, J., 1995. Uniform interpretation of gas/solid adsorption. Advances in Colloid and Interface Science, 55, pp.1-239.
Received on 21/03/2022
Accepted on 11/07/2022
Published on 30/09/2022
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