Treatment of Simulated Oily Wastewater by Ultrafiltration and Nanofiltration Processes

Authors

  • Ahmed Faiq Al-Alawy Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq
  • Mohammed Kamil Al-Ameri Chemical Engineering Department, College of Engineering, University of Baghdad, Baghdad, Iraq

DOI:

https://doi.org/10.31699/IJCPE.2017.1.6

Keywords:

Taguchi, UF, NF, membrane, oily wastewater, reuse.

Abstract

A study in the treatment and reuse of oily wastewater generated from the process of fuel oil treatment of gas turbine power plant was performed. The feasibility of using hollow fiber ultrafiltration (UF) membrane and nanofiltration (NF) membrane type polyamide thin-film composite in a pilot plant was investigated. Three different variables: pressure (0.5, 1, 1.5 and 2 bars), oil content (10, 20, 30 and 40 ppm), and temperature (15, 20, 30 and 40 ᵒC) were employed in the UF process while TDS was kept constant at 150 ppm. Four different variables: pressure (2, 3, 4 and 5 bar), oil content (2.5, 5, 7.5 and 10 ppm), total dissolved solids (TDS) (100, 200,300 and 400 ppm), and temperature (15, 20, 30 and 40 ᵒC) were manipulated with the help of statistical method of Taguchi in the RO process. Analysis of variable (ANOVA) and optimum condition was investigated. The study shows that pressure has the greatest impact on the flux of UF process, while temperature and pressure have similar contribution on flux of NF process. The temperature seems to have the greatest effect on TDS rejection. It was noticed that more than 96% oil removal can be achieved with flux of 624 L/m2.hr by UF process and that the fouling mechanism of UF process follows the cake/gel layer filtration model. It was observed that 100% removal of oil content can be achieved along with 79% for the TDS rejection and flux of 65 L/m2.hr by NF process. The result shows fouling in NF process follows the cake filtration model. It was concluded that the observed values are within ±5% of that the predicted which reflects a strong representative model. The treated wastewater has the characteristics that it can be reused in the process to reduce the operating cost.

References

J. Marchese, N. A. Ochoa, C. Pagliero, and C. Almandoz, “Pilot-scale ultrafiltration of an emulsified oil wastewater,” Environ. Sci. Technol., vol. 34, no. 14, pp. 2990–2996, 2000.

K. Karakulski, A. Kozlowski, and A. W. Morawski, “Purification of oily wastewater by ultrafiltration,” Sep. Technol., vol. 5, no. 4, pp. 197–205, 1995.

H. Kaplan and K. E. Majchrzak, “Liquid Fuel Treatment Systems,” GER-3481, General Electric. 1996.

G. R. Alther, “OILS FOUND IN WASTEWATER, What Are They?, How to Separate and Eliminate Them From Wastewater, A Layman’s Guide to Emulsion Breaking,” no. 248, 2014.

Y. S. Li, L. Yan, C. B. Xiang, and L. J. Hong, “Treatment of oily wastewater by organic–inorganic composite tubular ultrafiltration (UF) membranes,” Desalination, vol. 196, no. 1, pp. 76–83, 2006.

S. Mondal and S. R. Wickramasinghe, “Produced water treatment by nanofiltration and reverse osmosis membranes,” J. Memb. Sci., vol. 322, no. 1, pp. 162–170, 2008.

K. C. Channabasappa, “Membrane technology for water reuse application,” Desalination, vol. 23, no. 1, pp. 495–514, 1977.

B. Nicolaisen, “Developments in membrane technology for water treatment,” Desalination, vol. 153, no. 1, pp. 355–360, 2003.

J.-J. Qin, M. H. Oo, H. Lee, and R. Kolkman, “Dead-end ultrafiltration for pretreatment of RO in reclamation of municipal wastewater effluent,” J. Memb. Sci., vol. 243, no. 1, pp. 107–113, 2004.

A. Salahi, T. Mohammadi, and F. Rekabdar, “Reverse osmosis of refinery oily wastewater effluents,” Iranian J. Environ. Health Sci. Eng., vol. 7, no. 5, pp. 413–422, 2010.

A. Orecki and M. Tomaszewska, “The oily wastewater treatment using the nanofiltration process,” Polish J. Chem. Technol., vol. 9, no. 4, pp. 40–42, 2007.

A. Rahimpour, B. Rajaeian, A. Hosienzadeh, S. S. Madaeni, and F. Ghoreishi, “Treatment of oily wastewater produced by washing of gasoline reserving tanks using self-made and commercial nanofiltration membranes,” Desalination, vol. 265, no. 1, pp. 190–198, 2011.

J. K. Milić, I. Petrinić, A. Goršek, and M. Simonič, “Ultrafiltration of oil-in-water emulsion by using ceramic membrane: Taguchi experimental design approach,” Cent. Eur. J. Chem., vol. 12, no. 2, pp. 242–249, 2014.

S. Santos and M. Wiesner, “Ultrafiltration of water generated in oil and gas production‏,” 1997.

S. S. Madaeni and S. Koocheki, “Application of taguchi method in the optimization of wastewater treatment using spiral-wound reverse osmosis element,” Chem. Eng. J., vol. 119, no. 1, pp. 37–44, 2006.

E. Park and S. M. Barnett, “Oil/Water Separation Using Nanofiltration Membrane Technology,” Sep. Sci. Technol., vol. 36, no. 7, pp. 1527–1542, 2001.

M. S. H. Bader, “Nanofiltration for oil-fields water injection operations: analysis of concentration polarization,” Desalination, vol. 201, no. 1, pp. 106–113, 2006.

M. Tomaszewska, A. Orecki, and K. Karakulski, “Treatment of bilge water using a combination of ultrafiltration and reverse osmosis,” Desalination, vol. 185, no. 1–3, pp. 203–212, Nov. 2005.

X. Yu, Z. Zhong, and W. Xing, “Treatment of vegetable oily wastewater using an integrated microfiltration-reverse osmosis system,” in Water Science and Technology, 2010, vol. 61, no. 2, pp. 455–462.

A. Salahi and T. Mohammadi, “Experimental investigation of oily wastewater treatment using combined membrane systems,” Water Sci. Technol., vol. 62, no. 2, pp. 245–255, 2010.

R. K. Roy, A primer on the Taguchi method. Society of Manufacturing Engineers, 2010.

E. R. Ziegel, “Taguchi Techniques for Quality Engineering,” Technometrics, vol. 39, no. 1, pp. 109–110, 1997.

A. Salahi, T. Mohammadi, R. M. Behbahani, and M. Hemmati, “Experimental investigation and modeling of industrial oily wastewater treatment using modified polyethersulfone ultrafiltration hollow fiber membranes,” Korean J. Chem. Eng., pp. 1–18, 2015.

N. Eliaz, G. Shemesh, and R. M. Latanision, “Hot corrosion in gas turbine components,” Eng. Fail. Anal., vol. 9, no. 1, pp. 31–43, 2002.

L. Yu, M. Han, and F. He, “A review of treating oily wastewater,” Arab. J. Chem., 2013.

I. W. Cumming, R. G. Holdich, and I. D. Smith, “The rejection of oil by microfiltration of a stabilised kerosene/water emulsion,” J. Memb. Sci., vol. 169, no. 1, pp. 147–155, 2000.

A. B. Koltuniewicz, R. W. Field, and T. C. Arnot, “Cross-flow and dead-end microfiltration of oily-water emulsion. Part I: Experimental study and analysis of flux decline,” J. Memb. Sci., vol. 102, pp. 193–207, 1995.

A. Salahi, T. Mohammadi, F. Rekabdar, and H. Mahdavi, “Reverse osmosis of refinery oily wastewater effluents,” Iranian J. Environ. Health Sci. Eng., vol. 7, no. 5, p. 413, 2010.

M. Kazemimoghadam and T. Mohammadi, “Chemical cleaning of ultrafiltration membranes in the milk industry,” Desalination, vol. 204, no. 1, pp. 213–218, 2007.

S. M. Kumar and S. Roy, “Recovery of water from sewage effluents using alumina ceramic microfiltration membranes,” Sep. Sci. Technol., vol. 43, no. 5, pp. 1034–1064, 2008.

H. Susanto, Y. Feng, and M. Ulbricht, “Fouling behavior of aqueous solutions of polyphenolic compounds during ultrafiltration,” J. Food Eng., vol. 91, no. 2, pp. 333–340, 2009.

M. C. V. Vela, S. Á. Blanco, J. L. García, and E. B. Rodríguez, “Analysis of membrane pore blocking models applied to the ultrafiltration of PEG,” Sep. Purif. Technol., vol. 62, no. 3, pp. 489–498, 2008.

J. Kim, A. Chinen, and H. Ohya, “Membrane microfiltration of oily water,” in Macromolecular Symposia, 1997, vol. 118, no. 1, pp. 413–418.

Downloads

Published

2017-03-30

How to Cite

Al-Alawy, A. F., & Al-Ameri, M. K. (2017). Treatment of Simulated Oily Wastewater by Ultrafiltration and Nanofiltration Processes. Iraqi Journal of Chemical and Petroleum Engineering, 18(1), 71-85. https://doi.org/10.31699/IJCPE.2017.1.6

Publication Dates