Green synthesis of NiO nanoparticles with activated carbon from Ficus carica leaf and extract for malachite green removal
DOI:
https://doi.org/10.31699/IJCPE.2025.4.12Keywords:
Ficus carica leaf; green synthesis nanoparticles; activated carbon; malachite greenAbstract
The green synthesis of nanoparticles and activated carbon has attracted researchers' interest due to its rapid, cost-effective, sustainable, and environmentally friendly nature. In this paper, the synthesis of activated carbon (AC) and nickel oxide nanoparticles (NiO-NPs) from Ficus carica leaf and their extracts for the removal of malachite green from aqueous solutions. activated carbon (AC) was synthesized from Ficus carica leaves using a pyro-carbonic acid microwave method. In contrast, nickel oxide nanoparticles were produced using leaf extracts as a reducing and stabilizing agent. The manufactured activated carbon and NiO nanoparticles were characterized by Brunauer-Emmett-Teller analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The influence of various factors, including malachite green concentration, pH, contact time, and dosages of NiO, AC, and NiO/AC, was examined using Response Surface Methodology (RSM) in Design-Expert (13 Stat-Ease). the optimal parameters for achieving maximum removal efficiency of malachite green dye were determined to be an initial concentration of 150 mg/L, pH of 4, a contact period of 120 minutes, and an adsorbent dosage of 0.25 g/L, resulting in removal efficiencies of 97.9202%, 98.8932%, and 99.9776%, respectively. The equilibrium adsorption data were analyzed using the Langmuir, Freundlich, and pseudo-first- and second-order kinetic models. the results indicated that the Freundlich isotherm and pseudo-second-order kinetic models were the most effective in representing the equilibrium adsorption data.
Received on 16/06/2025
Received in Revised Form on 08/08/2025
Accepted on 08/08/2025
Published on 30/12/2025
References
[1] G. Crini, "Non-conventional low-cost adsorbents for dye removal: A review," Bioresource Technology, vol. 97, no. 9, pp. 1061-1085, 2006, https://doi.org/10.1016/j.biortech.2005.05.001
[2] M. Abbas, M. Adil, S. Ehisham-ul-Haque, B. Munir, M. Yasmeen, A. Ghaffar, G.A. Shar, M. Asif Tahir, "Vibrio fischeri bioluminescence inhibition assay for ecotoxicity assessment: A review," Science of The Total Environment, vol. 626, pp. 1295-1309, 2018, https://doi.org/10.1016/j.scitotenv.2018.01.066
[3] S. De Gisi, G. Lofrano, M. Grassi, and M. Notarnicola, "Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: A review," Sustainable Materials and Technologies, vol. 9, pp. 10-40, 2016, https://doi.org/10.1016/j.susmat.2016.06.002
[4] J. Hashimoto, J. Paschoal, J. Queiroz, and F. Reyes, "Considerations on the Use of Malachite Green in Aquaculture and Analytical Aspects of Determining the Residues in Fish: A Review," Journal of Aquatic Food Product Technology, vol. 20, pp. 273-294, 2011,
https://doi.org/10.1080/10498850.2011.569643
[5] J. Sharma, S. Sharma, and V. Soni, "Toxicity of malachite green on plants and its phytoremediation: A review," Regional Studies in Marine Science, vol. 62, p. 102911, 2023, https://doi.org/10.1016/j.rsma.2023.102911
[6] K. Mohammadi, S. Khalesro, Y. Sohrabi, and G. Heidari, "A Review: Beneficial Effects of the Mycorrhizal Fungi for Plant Growth," Journal of Applied Environment Biological Sciences, vol. 1, pp. 310-319, 2011.
[7] H. N. J. Hoong and N. Ismail, "Removal of Dye in Wastewater by Adsorption-Coagulation Combined System with Hibiscus sabdariffa as the Coagulant," MATEC Web Conference, vol. 152, p. 01008, 2018. https://doi.org/10.1051/matecconf/201815201008
[8] P. V. Nidheesh, M. Zhou, and M. A. Oturan, "An overview on the removal of synthetic dyes from water by electrochemical advanced oxidation processes," Chemosphere, vol. 197, pp. 210-227, 2018, https://doi.org/10.1016/j.chemosphere.2017.12.195
[9] J. Sarasa, M. P. Roche, M. P. Ormad, E. Gimeno, A. Puig, and J. L. Ovelleiro, "Treatment of a wastewater resulting from dyes manufacturing with ozone and chemical coagulation," Water Research, vol. 32, no. 9, pp. 2721-2727, 1998, https://doi.org/10.1016/S0043-1354(98)00030-X
[10] A. E. Abdelhamid, A. E. Elsayed, M. Naguib, and E. A. Ali, "Effective Dye Removal by Acrylic-Based Membrane Constructed from Textile Fibers Waste," Fibers and Polymers, vol. 24, no. 7, pp. 2391-2399, 2023,
https://doi.org/10.1007/s12221-023-00247-z
[11] S. Selvakumar, R. Manivasagan, and K. Chinnappan, "Biodegradation and decolourization of textile dye wastewater using Ganoderma lucidum," 3 Biotech, vol. 3, no. 1, pp. 71-79, Feb 2013, https://doi.org/10.1007/s13205-012-0073-5
[12] Removal of Malachite Green from Aqueous Solution using Ficus Benjamina Activated Carbon-Nonmetal Oxide synthesized by pyro Carbonic Acid Microwave," Al-Khwarizmi Engineering Journal, vol. 19, no. 2, pp. 26- 38, 2023, https://doi.org/10.22153/kej.2023.03.002
[13] K. E. Talib and S. D. Salman, "Removal of malachite green from aqueous solution using Ficus benjamina activated carbon-metal oxide synthesized by pyrocarbonic acid microwave," Desalination and Water Treatment, vol. 302, pp. 195-209, 2023, https://doi.org/10.5004/dwt.2023.29620
[14] Momina and K. Ahmad, "Feasibility of the adsorption as a process for its large scale adoption across industries for the treatment of wastewater: Research gaps and economic assessment," Journal of Cleaner Production, vol. 388, p. 136014, 2023, https://doi.org/10.1016/j.jclepro.2023.136014
[15] Y. Alhamed, "Activated Carbon from Date Stone by ZnCl2 Activation," Journal of King Saud University Engineering Science, vol. 17, 2006.
[16] O. Ioannidou and A. Zabaniotou, "Agricultural residues as precursors for activated carbon production—A review," Renewable Sustainable Energy Reviews, vol. 11, no. 9, pp. 1966-2005, 2007, https://doi.org/10.1016/j.rser.2006.03.013
[17] M. Ajmal, R. A. K. Rao, and M. A. Khan, "Adsorption of copper from aqueous solution on Brassica cumpestris (mustard oil cake)," Journal of Hazardous Materials, vol. 122, no. 1, pp. 177-183, 2005, https://doi.org/10.1016/j.jhazmat.2005.03.029
[18] H. Demiral and C. Güngör, "Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse," Journal of Cleaner Production, vol. 124, pp. 103-113, 2016, https://doi.org/10.1016/j.jclepro.2016.02.084
[19] R. Baccar, J. Bouzid, M. Feki, and A. Montiel, "Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions," Journal of Hazardous Materials, vol. 162, no. 2, pp. 1522-1529, 2009, https://doi.org/10.1016/j.jhazmat.2008.06.041
[20] N. Fiol, I. Villaescusa, M. Martínez, N. Miralles, J. Poch, and J. Serarols, "Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste," Separation and Purification Technology, vol. 50, no. 1, pp. 132-140, 2006, https://doi.org/10.1016/j.seppur.2005.11.016
[21] A.-N. A. El-Hendawy, A. J. Alexander, R. J. Andrews, and G. Forrest, "Effects of activation schemes on porous, surface and thermal properties of activated carbons prepared from cotton stalks," Journal of Analytical and Applied Pyrolysis, vol. 82, no. 2, pp. 272-278, 2008, https://doi.org/10.1016/j.jaap.2008.04.006
[22] J. M. V. Nabais, C. E. C. Laginhas, P. J. M. Carrott, and M. M. L. Ribeiro Carrott, "Production of activated carbons from almond shell," Fuel Processing Technology, vol. 92, no. 2, pp. 234-240, 2011, https://doi.org/10.1016/j.fuproc.2010.03.024
[23] Q. Cao, K.-C. Xie, Y.-K. Lv, and W.-R. Bao, "Process effects on activated carbon with large specific surface area from corn cob," Bioresource Technology, vol. 97, no. 1, pp. 110-115, 2006, https://doi.org/10.1016/j.biortech.2005.02.026
[24] B. M. W. P. K. Amarasinghe and R. A. Williams, "Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater," Chemical Engineering Journal, vol. 132, no. 1, pp. 299-309, 2007, https://doi.org/10.1016/j.cej.2007.01.016
[25] S. Erdoğan, Y. Önal, C. Akmil-Başar, S. Bilmez-Erdemoğlu, Ç. Sarıcı-Özdemir, E. Köseoğlu, G. İçduygu , "Optimization of nickel adsorption from aqueous solution by using activated carbon prepared from waste apricot by chemical activation," Applied Surface Science, vol. 252, no. 5, pp. 1324-1331, 2005, https://doi.org/10.1016/j.apsusc.2005.02.089
[26] Y.-z. Cui and M.-c. Tian, "Three-dimensional numerical simulation of thermal-hydraulic performance of a circular tube with edgefold-twisted-tape inserts," Journal of Hydrodynamics, vol. 22, no. 5, pp. 662-670, 2010, https://doi.org/10.1016/s1001-6058(09)60101-3
[27] C. J. Durán-Valle, M. Gómez-Corzo, V. Gómez-Serrano, J. Pastor-Villegas, and M. L. Rojas-Cervantes, "Preparation of charcoal from cherry stones," Applied Surface Science, vol. 252, no. 17, pp. 5957-5960, 2006, https://doi.org/10.1016/j.apsusc.2005.11.004
[28] R. M. Suzuki, A. D. Andrade, J. C. Sousa, and M. C. Rollemberg, "Preparation and characterization of activated carbon from rice bran," Bioresource Technology, vol. 98, no. 10, pp. 1985-1991, 2007, https://doi.org/10.1016/j.biortech.2006.08.001
[29] T. C. Chandra, M. M. Mirna, J. Sunarso, Y. Sudaryanto, and S. Ismadji, "Activated carbon from durian shell: Preparation and characterization," Journal of the Taiwan Institute of Chemical Engineers, vol. 40, no. 4, pp. 457-462, 2009/07/01/ 2009, https://doi.org/10.1016/j.jtice.2008.10.002
[30] Khatab E. Talib and S. D. Salman, "Removal of Malachite Green from Aqueous Solution using Ficus Benjamina Activated Carbon-Metal Oxide synthesized by pyro carbonic acid microwave," Desalination and Water Treatment, vol. 302, no. August 2023, pp. 105-209, 2023, https://doi.org/10.5004/dwt.2023.29620
[31] N. Rani, P. Singh, S. Kumar, P. Kumar, V. Bhankar, and K. Kumar, "Plant-mediated synthesis of nanoparticles and their applications: A review," Materials Research Bulletin, vol. 163, p. 112233, 2023, https://doi.org/10.1016/j.materresbull.2023.112233
[32] M. A. Rahman, R. Radhakrishnan, and R. Gopalakrishnan, "Structural, optical, magnetic and antibacterial properties of Nd doped NiO nanoparticles prepared by co-precipitation method," Journal of Alloys and Compounds, vol. 742, pp. 421-429, 2018, https://doi.org/10.1016/j.jallcom.2018.01.298
[33] F. L. Jia, L. Z. Zhang, X. Y. Shang, and Y. Yang, "Non-Aqueous Sol–Gel Approach towards the Controllable Synthesis of Nickel Nanospheres, Nanowires, and Nanoflowers," Advanced Material, vol. 20, no. 5, pp. 1050-1054, 2008, https://doi.org/10.1002/adma.200702159
[34] B. Nagaraj, N. B. Krishnamurthy, P. Liny, and R. DivyaTkAndDinesh, "Biosynthesis of Gold Nanoparticles of Ixora Coccinea Flower Extract & Their Antimicrobial Activities," International journal of pharma and bio sciences, 2011.
[35] A. E. Ferenji, Y. E. Hassen, S. L. Mekuria, and W. M. Girma, "Biogenic mediated green synthesis of NiO nanoparticles for adsorptive removal of lead from aqueous solution," Heliyon, vol. 10, no. 11, p. e31669, 2024, https://doi.org/10.1016/j.heliyon.2024.e31669
[36] C. J. Pandian, R. Palanivel, and S. Dhananasekaran, "Green synthesis of nickel nanoparticles using Ocimum sanctum and their application in dye and pollutant adsorption," Chinese Journal of Chemical Engineering, vol. 23, no. 8, pp. 1307-1315, 2015, https://doi.org/10.1016/j.cjche.2015.05.012
[37] S. Hussain, M. A. Muazzam, M. Ahmed, M. Ahmad, Z. Mustafa, S. Murtaza, J. Ali, M. Ibrar, M. Shahid, M. Imran, "Green synthesis of nickel oxide nanoparticles using Acacia nilotica leaf extracts and investigation of their electrochemical and biological properties," Journal of Taibah University for Science, vol. 17, no. 1, p. 2170162, 2023, https://doi.org/10.1080/16583655.2023.2170162
[38] A. Kiran, S. Hussain, I. Ahmad, M. Imran, M. Saqib, B. Parveen, K. S. Munawar, W. Mnif, M. Al Huwayz, N. Alwadai, M. Iqbal, "Green synthesis of NiO and NiO@graphene oxide nanomaterials using Elettaria cardamomum leaves: Structural and electrochemical studies," Heliyon, vol. 10, no. 20, p. e38613, 2024, https://doi.org/10.1016/j.heliyon.2024.e38613
[39] H. G. Gebretinsae, M. G. Tsegay, and Z. Y. Nuru, "Biosynthesis of nickel oxide (NiO) nanoparticles from cactus plant extract," Materials Today: Proceedings, vol. 36, pp. 566-570, 2021, https://doi.org/10.1016/j.matpr.2020.05.331
[40] S. Prabhu, T. Daniel Thangadurai, P. Vijai Bharathy, and P. Kalugasalam, "Synthesis and characterization of nickel oxide nanoparticles using Clitoria ternatea flower extract: Photocatalytic dye degradation under sunlight and antibacterial activity applications," Results in Chemistry, vol. 4, p. 100285, 2022, https://doi.org/10.1016/j.rechem.2022.100285
[41] M. I. Din, A. G. Nabi, A. Rani, A. Aihetasham, and M. Mukhtar, "Single step green synthesis of stable nickel and nickel oxide nanoparticles from Calotropis gigantea: Catalytic and antimicrobial potentials," Environmental Nanotechnology, Monitoring & Management, vol. 9, pp. 29-36, 2018, https://doi.org/10.1016/j.enmm.2017.11.005
[42] B. T. Sone, X. G. Fuku, and M. Maaza, "Physical & Electrochemical Properties of Green Synthesized Bunsenite NiO Nanoparticles via Callistemon Viminalis’ Extracts," International Journal of Electrochemical Science, vol. 11, no. 10, pp. 8204-8220, 2016, https://doi.org/10.20964/2016.10.17
[43] J. Iqbal, B. Abbasi, T. Mahmood, S. Hameed, A. Munir, and S. Kanwal, "Green synthesis and characterizations of Nickel oxide nanoparticles using leaf extract of Rhamnus virgata and their potential biological applications," Applied Organometallic Chemistry, 2019, https://doi.org/10.1002/aoc.4950
[44] Z. Sabouri et al., "Plant-based synthesis of NiO nanoparticles using salvia macrosiphon Boiss extract and examination of their water treatment," Rare Metals, vol. 39, no. 10, pp. 1134-1144, 2020, https://doi.org/10.1007/s12598-019-01333-z
[45] S. N. Shintre, S. Wadhai, and P. Thakur, "Synthesis of Ag/ZnO-AC composite photocatalyst: spectroscopic investigation, parameter optimization, synergistic effect and performance enhancement for cost-effective photocatalytic degradation of phenols and dyes," Water Science and Technology, vol. 85, no. 9, pp. 2663-2681, 2022, htpps://doi.org/10.2166/wst.2022.137
[46] A. Jain, M. Michalska, A. Zaszczyńska, and P. Denis, "Surface modification of activated carbon with silver nanoparticles for electrochemical double layer capacitors," Journal of Energy Storage, vol. 54, p. 105367, 2022, https://doi.org/10.1016/j.est.2022.105367
[47] Ç. d. Şentorun-Shalaby, M. G. Uçak-Astarlıogˇlu, L. Artok, and Ç. Sarıcı, "Preparation and characterization of activated carbons by one-step steam pyrolysis/activation from apricot stones," Microporous and Mesoporous Materials, vol. 88, no. 1, pp. 126-134, 2006, https://doi.org/10.1016/j.micromeso.2005.09.003
[48] A. A. Al. Swat, T. A. Saleh, S. A. Ganiyu, M. N. Siddiqui, and K. R. Alhooshani, "Preparation of activated carbon, zinc oxide and nickel oxide composites for potential application in the desulfurization of model diesel fuels," Journal of Analytical and Applied Pyrolysis, vol. 128, pp. 246-256, 2017, https://doi.org/10.1016/j.jaap.2017.10.004
[49] S. D. Salman, I. M. Rasheed, and M. M. Ismaeel, "Removal of diclofenac from aqueous solution on apricot seeds activated carbon synthesized by pyro carbonic acid microwave," Chemical Data Collections, vol. 43, p. 100982, 2023, https://doi.org/10.1016/j.cdc.2022.100982
[50] W. Salah, W. Djeridi, A. Houas, and L. Elsellami, "Synergy between activated carbon and ZnO: a powerful combination for selective adsorption and photocatalytic degradation," Materials Advances, 2024, https://doi.org/10.1039/D3MA01171B
[51] A. Nasrullah, H. Khan, A. S. Khan, Z. Man, N. Muhammad, M. I. Khan, and N. M. Abd El-Salam,, "Potential biosorbent derived from Calligonum polygonoides for removal of methylene blue dye from aqueous solution," Scientific World Journal, vol. 2015, p. 562693, 2015, https://doi.org/10.1155/2015/562693
[52] P. Khare and B. P. Baruah, "Structural Parameters of Perhydrous Indian Coals," International Journal of Coal Preparation and Utilization, vol. 30, no. 1, pp. 44-67, 2010, https://doi.org/10.1080/19392691003781616
[53] Ş. Taşar, F. Kaya, and A. Özer, "Biosorption of lead(II) ions from aqueous solution by peanut shells: Equilibrium, thermodynamic and kinetic studies," Journal of Environmental Chemical Engineering, vol. 2, no. 2, pp. 1018-1026, 2014, https://doi.org/10.1016/j.jece.2014.03.015
[54] T. Benzaoui, A. Selatnia, and D. Djabali, "Adsorption of coper (II) ions from aqueous solution using bottom ash of expired drugs incineration," Adsorption Science & Technology, vol. 36, no. 1-2, pp. 114-129, 2018. https://doi.org/10.1177/0263617416685099
[55] R. Labied, O. Benturki, A. Y. Eddine Hamitouche, and A. Donnot, "Adsorption of hexavalent chromium by activated carbon obtained from a waste lignocellulosic material (Ziziphus jujuba cores): Kinetic, equilibrium, and thermodynamic study," Adsorption Science & Technology, vol. 36, no. 3-4, pp. 1066-1099, 2018, https://doi.org/10.1177/0263617417750739
[56] Freeman, I. J., Salmon, J. L., & Coburn, J. Q. “CAD Integration in Virtual Reality Design Reviews for Improved Engineering Model Interaction”, In ASME 2016 International Mechanical Engineering Congress & Exposition, 2016, https://doi.org/10.1115/IMECE2016-66948
[57] S. Ilyas, H. Heryanto, and D. Tahir, "Correlation between structural and optical properties of CuO/carbon nanoparticle in supports the photocatalytic performance and attenuate the electromagnetic wave," Journal of Environmental Chemical Engineering, vol. 9, no. 1, p. 104670, 2021, https://doi.org/10.1016/j.jece.2020.104670
[58] S. Saini, J. Chawla, R. Kumar, and I. Kaur, "Response surface methodology (RSM) for optimization of cadmium ions adsorption using C16-6-16 incorporated mesoporous MCM-41," SN Applied Sciences, vol. 1, 2019, https://doi.org/10.1007/s42452-019-0922-5
[59] DESIGN EXPERT 13. Stat-Ease Inc.
[60] B. H. Hameed and M. I. El-Khaiary, "Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: Equilibrium isotherms and kinetic studies," Journal of Hazardous Materials, vol. 154, no. 1, pp. 237-244, 2008, https://doi.org/10.1016/j.jhazmat.2007.10.017
[61] B. H. Hameed and M. I. El-Khaiary, "Malachite green adsorption by rattan sawdust: Isotherm, kinetic and mechanism modeling," Journal of Hazardous Materials, vol. 159, no. 2, pp. 574-579, 2008, https://doi.org/10.1016/j.jhazmat.2008.02.054
[62] M. Hema and S. Arivoli, "Adsorption kinetics and thermodynamics of malachite green dye unto acid activated low cost carbon," Journal of applied sciences and environmental management, vol. 12, no. 1, 2008, https://doi.org/10.4314/jasem.v12i1.55568
[63] A. E. Nemr, "Potential of pomegranate husk carbon for Cr(VI) removal from wastewater: Kinetic and isotherm studies," Journal of Hazardous Material, vol. 161, no. 1, pp. 132-141, 2009, https://doi.org/10.1016/j.jhazmat.2008.03.093
[64] X.-E. Shen, X.-Q. Shan, D.-M. Dong, X.-Y. Hua, and G. Owens, "Kinetics and thermodynamics of sorption of nitroaromatic compounds to as-grown and oxidized multiwalled carbon nanotubes," Journal of Colloid and Interface Science, vol. 330, no. 1, pp. 1-8, 2009, https://doi.org/10.1016/j.jcis.2008.10.023
[65] A. Behnamfard and M. M. Salarirad, "Equilibrium and kinetic studies on free cyanide adsorption from aqueous solution by activated carbon," Journal of Hazardous Materials, vol. 170, no. 1, pp. 127-133, 2009, https://doi.org/10.1016/j.jhazmat.2009.04.124
[66] T. Farías, L. C. de Ménorval, J. Zajac, and A. Rivera, "Benzalkonium chloride and sulfamethoxazole adsorption onto natural clinoptilolite: effect of time, ionic strength, pH and temperature," Journal of Colloid and Interface Science, vol. 363, no. 2, pp. 465-475, 2011, https://doi.org/10.1016/j.jcis.2011.07.067
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