Adsorption of methyl violet dye using MgO nanoparticles: Synthesis and kinetics
DOI:
https://doi.org/10.31699/IJCPE.2026.1.10Keywords:
Magnesium Oxide Nanoparticles; Methyl Violet Dye; Adsorption Isotherm; Adsorption kineticsAbstract
A scalable method of oxalate co-precipitation was used to prepare magnesium oxide (MgO) nanoparticles. The precipitant used was oxalic acid and the source of soluble magnesium was magnesium sulfate. Highly crystalline MgO nanoparticles prepared by calcining at 700 were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Atomic Force Microcopy Analysis (AFM). The (MgO) nanoparticles were employed to investigate the adsorption performance of Methyl Violet (MV) dye from aqueous solutions under different conditions, i.e., contact time, pH, dye concentration and temperature. Maximum adsorption (96%) was obtained at time (60 min.), pH 6, at (20 ) and adsorbent dosage (0.05 g/L). It was found that the effect of temperature is inversely proportional to the percentage of dye removal in the studied range (20-50 ). Pseudo-second-order (R2=0.9968) and Langmuir models (R2=0.9931) described excellent fits in kinetic and isotherm experiments, respectively, indicating monolayer coverage and chemisorption. The greater adsorption capability of MgO was verified in comparison to equivalent adsorbents (qmax=83.1 mg/g).
Received on 26/10/2025
Received in Revised Form on 02/01/2026
Accepted on 03/01/2026
Published on 30/03/2026
References
[1] D. A. Yaseen and M. Scholz, “Textile dye wastewater characteristics and constituents of synthetic effluents: A critical review,” International Journal of Environmental Science and Technology, Vol. 17, No. 2, 2019, pp. 113–140. https://doi.org/10.1007/s13762-018-2130-z
[2] R. Al-Tohamy, S. S. Ali, F. Li, K. M. Okasha, Y. A.-G. Mahmoud, T. Elsamahy, H. Jiao, Y. Fu, and J. Sun, “A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety,” Ecotoxicology and Environmental Safety, Vol. 231, 2022. https://doi.org/10.1016/j.ecoenv.2021.113160
[3] Y. Shi, Z. Yang, L. Xing, X. Zhang, X. Li, and D. Zhang, “Recent advances in the biodegradation of azo dyes,” World Journal of Microbiology and Biotechnology, Vol. 37, No. 8, 2021. https://doi.org/10.1007/s11274-021-03110-6
[4] B. Pizzicato, S. Pacifico, D. Cayuela, G. Mijas, and M. Riba Moliner, “Advancements in sustainable natural dyes for textile applications: A review,” Molecules, Vol. 28, No. 16, 2023. https://doi.org/10.3390/molecules28165954
[5] M. Bilal, I. Ihsanullah, M. U. H. Shah, A. V. B. Reddy, and T. M. Aminabhavi, “Recent advances in the removal of dyes from wastewater using low-cost adsorbents,” Journal of Environmental Management, Vol. 321, 2022. https://doi.org/10.1016/j.jenvman.2022.115981
[6] K. H. H. Aziz, F. N. Majeed, and M. K. Taib, “Advancements in application of modified biochar as a green and low-cost adsorbent for wastewater remediation from organic dyes,” Royal Society Open Science, Vol. 11, 2024. https://doi.org/10.1098/rsos.232033
[7] N. S. Ali, N. M. Jabbar, S. M. Alardhi, H. Sh. Majdi, and T. M. Albayati, “Adsorption of methyl violet dye onto a prepared bio-adsorbent from date seeds: Isotherm, kinetics, and thermodynamic studies,” Heliyon, Vol. 8, No. 8, 2022. https://doi.org/10.1016/j.heliyon.2022.e10276
[8] M. G. Ghoniem, F. A. M. Ali, B. Y. Abdulkhair, M. R. A. Elamin, A. M. Alqahtani, S. Rahali, and M. A. Ben Aissa, “Highly selective removal of cationic dyes from wastewater by MgO nanorods,” Nanomaterials, Vol. 12, No. 6, 2022. https://doi.org/10.3390/nano12061023
[9] Z. Raji, A. Karim, A. Karam, and S. Khalloufi, “Adsorption of heavy metals: Mechanisms, kinetics, and applications of various adsorbents in wastewater remediation—A review,” Waste, Vol. 1, No. 3, 2023, pp. 775–805. https://doi.org/10.3390/waste1030046
[10] P. Yadav, R. Saini, and A. Bhaduri, “Facile synthesis of MgO nanoparticles for effective degradation of organic dyes,” Environmental Science and Pollution Research, Vol. 30, No. 28, 2023, pp. 71439–71453. https://doi.org/10.1007/s11356-022-21925-0
[11] M. G. Ghoniem et al., “Highly selective removal of cationic dyes from wastewater by MgO nanorods,” Nanomaterials, Vol. 12, No. 6, 2022. https://doi.org/10.3390/nano12061023
[12] H. Hegazey and E. A. Abdelrahman, “Efficient removal of methylene blue dye from aqueous media using magnesium borate/magnesium oxide (Mg₃B₂O₆/MgO) nanostructures,” Molecules, Vol. 29, No. 14, 2024. https://doi.org/10.3390/molecules29143392
[13] T. S. Priya et al., “Structural and optical properties of MgO nanoparticles synthesized by wet chemical route,” Journal of Materials Research and Technology, Vol. 17, 2022, pp. 1–11.
[14] A. Muhaymin, H. E. A. Mohamed, K. Hkiri, A. Safdar, S. Azizi, and M. Maaza, “Green synthesis of magnesium oxide nanoparticles using Hyphaene thebaica extract and their photocatalytic activities,” Scientific Reports, Vol. 14, No. 1, 2024. https://doi.org/10.1038/s41598-024-71149-0
[15] T. T. N. Nguyen et al., “Enhancing methyl violet adsorption on sugarcane bagasse-based biochar via modification with sodium dodecyl sulfate,” Vietnam Journal of Catalysis and Adsorption, Vol. 13, No. 4, 2024, pp. 26–31. https://doi.org/10.62239/jca.2024.069
[16] M. Alsuhybani et al., “High removal of methylene blue and methyl violet dyes from aqueous solutions using efficient biomaterial byproduct,” Heliyon, Vol. 10, No. 17, 2024. https://doi.org/10.1016/j.heliyon.2024.e36731
[17] H. Tahir, “Enhancement of adsorption and photocatalytic activity of MgO nanoparticles for the treatment of textile dye using ultrasound-assisted process by response surface methodology,” Desalination and Water Treatment, Vol. 319, 2024. https://doi.org/10.1016/j.dwt.2024.100429
[18] V. N. Hegde et al., “Effect of calcination temperature on structural, morphological, elastic and electrical properties of MgO nanoparticles synthesized by combustion method,” Journal of Physics and Chemistry of Solids, Vol. 192, 2024. https://doi.org/10.1016/j.jpcs.2024.112071
[19] M. Sadiku et al., “Removal of methyl violet from aqueous solution by adsorption onto halloysite nanoclay: Experiment and theory,” Toxics, Vol. 10, No. 8, 2022. https://doi.org/10.3390/toxics10080445
[20] O. H. Fadhil et al., “Adsorption of indigo carmine dye using corn leaves as natural adsorbent material,” Al-Khwarizmi Engineering Journal, Vol. 17, No. 1, 2021. https://doi.org/10.22153/kej.2021.11.002
[21] A. D. Prasetya et al., “X-ray diffraction profile analysis of pure ECAP-annealed nickel samples,” Journal of Physics: Conference Series, Vol. 1436, 2020. https://doi.org/10.1088/1742-6596/1436/1/012113
[22] U.-S. B. Mahmood et al., “Adsorption of eosin yellow dye by nickel oxide nanoparticles synthesized via oxalate co-precipitation method: Isotherm, kinetic and thermodynamic studies,” Physica Scripta, Vol. 96, 2021. https://doi.org/10.1088/1402-4896/ac326e
[23] Z. R. Zair et al., “Optimization, equilibrium, kinetics and thermodynamic study of Congo red dye adsorption from aqueous solutions using Iraqi porcelanite rocks,” Heat and Mass Transfer, Vol. 58, No. 8, 2022, pp. 1393–1410. https://doi.org/10.1007/s00231-022-03182-6
[24] O. P. Murphy, M. Vashishtha, P. Palanisamy, and K. V. Kumar, “A review on the adsorption isotherms and design calculations for the optimization of adsorbent mass and contact time,” ACS Omega, Vol. 8, No. 4, 2023, pp. 17407–17430. https://doi.org/10.1021/acsomega.2c08155
[25] H. Abdelmenim et al., “Removal of cationic dyes from water using nano-adsorbents sulfonated carboxymethyl cellulose: Characterization, isotherm, kinetics and thermodynamics,” Port-Said Engineering Research Journal, 2023. https://doi.org/10.21608/pserj.2023.195709.1223
[26] M. Yadav, S. Thakore, and R. Jadeja, “Removal of organic dyes using Fucus vesiculosus seaweed bioadsorbent: Equilibrium, kinetics and thermodynamic studies,” Environmental Chemistry and Ecotoxicology, Vol. 4, 2022, pp. 67–77. https://doi.org/10.1016/j.enceco.2021.12.003
[27] İ. Uzun and F. Güzel, “Kinetics and thermodynamics of the adsorption of some dyestuffs and p-nitrophenol by chitosan and MCM-chitosan from aqueous solution,” Journal of Colloid and Interface Science, Vol. 274, No. 2, 2004, pp. 398–412. https://doi.org/10.1016/j.jcis.2004.02.022
[28] M. ElKammah, E. Elkhatib, and M. Moubarak, “Effective elimination of indigo carmine in wastewater using green nanostructured modified biochar: Optimization, sorption equilibrium, kinetics, thermodynamics and mechanisms,” Applied Water Science, Vol. 15, 2025. https://doi.org/10.1007/s13201-025-02556-5
[29] A. Gürses, K. Güneş, E. Şahin, and M. Açıkyıldız, “Investigation of the removal kinetics, thermodynamics and adsorption mechanism of Remazol Red RB using powder pumice,” Frontiers in Chemistry, Vol. 11, 2023. https://doi.org/10.3389/fchem.2023.1156577
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