Photocatalytic Degradation of Reactive Yellow Dye in Wastewater using H2O2/TiO2/UV Technique
DOI:
https://doi.org/10.31699/IJCPE.2020.1.3Keywords:
Reactive Yellow dye; Titanium dioxide; Hydrogen peroxide; Advanced oxidation processesAbstract
In the present study, advanced oxidation treatment, the TiO2 /UV/H2O2 process was applied to decolorisation of the reactive yellow dyes in aqueous solution. The UV radiation was carried out with a 6 W low-pressure mercury lamp. The rate of color removal was studied by measuring the absorbency at a characteristic wavelength. The effects of H2O2 dosage, dye initial concentration and pH on decolorisation kinetics in the batch photoreactor were investigated. The highest decolorisation rates were observed (98.8) at pH range between 3 and 7. The optimal levels of H2O2 needed for the process were examined. It appears that high levels of H2O2 could reduce decolorisation by scavenging the *OH. The color degradation rate decreases as the dye concentration increases. The rate coefficient (k=0.0319 min-1) of degradation, follows the pseudo-first-order kinetics.
Received on 13/05/2019
Accepted on 08/07/2019
Published on 30/03/2020
References
I. Faisal, “Removal of dyes from polluted water by adsorption on maize cob”, ijcpe, vol. 11, no. 1, pp. 55-57, Mar. 2010.
W. Taher Mohammed, H. F. Farhood, and A. Hassoon Bjaiyah Al-Mas’udi, “Removal of Dyes from Wastewater of Textile Industries Using Activated Carbon and Activated Alumina”, ijcpe, vol. 10, no. 1, pp. 43-52, Mar. 2009.
M. Yousuf, A. Molla, R. Schennach, J.R. Parga, D.L .Cocke ( (2001,Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters,J. Hazard. Mater. B, vol. 84 , p.29.
Huseyin Selcuk (2005) , Decolorization and detoxification of textile wastewater by ozonation and coagulation processes , Dyes and Pigments 64, p 217-222.
N. Daneshvar, , D. Salari, , & A. R. Khataee, "Photocatalytic degradation of azo dye acid red 14 in water on ZnO as an alternative catalyst to TiO2" , Journal of photochemistry and photobiology A: chemistry 162.2-3 (2004): 317-322.
W.S. Kuo, P.H. Ho, Solar "Solar photocatalytic decolorization of methylene blue in water." Chemosphere 45, no. 1, pp. 77-83 (2001).
Garcia, J.C., Oliveira, J.L., Silva, A.E.C., Oliveira, C.C., Nozaki, J.,Souza, N.E., 2007. Comparative study of the degradation of real textile effluents by photocatalytic reactions involving UV/TiO2/H2O2 and UV/Fe2+/H2O2 systems. Journal of Hazardous Materials 147, 105–110.
Pe´rez, M., Torrades, F., Domenech, X., Peral, J., 2002. Fenton and photo-Fenton oxidation of textile effluents. Water Research 36, 2703–2710.
Azbar, N., Yonar, T., Kestioglu, K., 2004. Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent. Chemosphere 55, 35–43.
Rodrigues, A.C., Boroski, M., Garcia, J.C., Shimada, N.S., Nozaki, J.,Hioka, N., 2008. Treatment of paper pulp and paper mill wastewater by coagulation–flocculation followed by heterogeneous photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry ,vol.194, p.1–10.
A.H. Mounteer, R.O. Pereira, A.A. Morais, D.B. Ruas, D.S.A. Silveira, D.B. Viana and R.C. Medeiros. (2007). Advanced oxidation of bleached eucalypt kraft pulp mill effluent ,Vol .55 ,No. 6 , p. 109–116.
Qamar, M., Saquib, M., Muneer, M.,(2005). Photocatalytic degradation of two selected dye derivatives, chromotrope 2B and amido black 10B, in aqueous suspensions of titanium dioxide. Dyes and Pigments 65, 1–9.
I.K. Konstantinou, T.A. Albanis, "TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: A review, Appl. Catal. B, vol. 49 ,p.1–14, 2004.
Rachakornlij, M., Ruangch, S. and Teachakul, S., 2004, "Removal of Reactive Dyes from Aqueous Solution Using Bagasse Fly Ash", Journal of Science and Technology Thailand, vol. 26, No. 1, pp. 13-24.
Manu, B. and Chaudhari, B. M., 2003,"Decolorization of Indigo and Azo Dyes in Semi Continuous Reactors" J. Process Biochemistry, March, vol. 38, Issue 8, pp. 1213-1221.
E. M. Saggioro, A. S. Oliveira, T. Pavesi, C. G. Maia, L. F. V. Ferreiea, and J. C. Moreira, (2011).Use of Titanium Dioxide Photocatalysis on the Remediation of Model Textile Wastewaters Containing Azo Dyes, Molecules 16, 10370
Daneshvar N. , Salari D. , Khataee A.R., (2003) , Photocatalytic degradation of azo dye acid red 14 in water : investigation of the effect of operational parameters , Journal of Photochemistry and Photobiology Chemistry vol. 157, p. 111–116
V. Maurino, C. Minero, E. Pelizzetti, M. Vincenti, Coll. Surf. A , (1999) Chemical Processes in Marine Environments ,151 , p.329.
S.R. Cater, M.I. Stefan, J.R. Bolton, A. Safarzadeh-Amiri, (2000) ,Photocatalytic degradation of azo dye acid red 14 in water:investigation of the effect of operational parameters, Environ. Sci. Technol.,vol. 34, p. 659.
M. Stylidi, D.I. Kondarides, X.E. Verykios, (2004) Visible light-induced photocatalytic degradation of Acid Orange 7 in aqueous TiO2 suspensions, Appl. Catal. B, vol. 47, p. 189–201.
Rossetti, I. Compagnoni, M. Ramis ,G. Freyria, Francesca, (2017). Development of Unconventional Photocatalytic Reactors and Processes for the Abatement of Harmful N -containing Pollutants, Chemical Engineering Transactions, vol.57 , p.319-324.
Muruganandham, M., Sobana, N. and Swaminathan, M. (2006) Solar Assisted Photocatalytic and Photochemical Degradation of Reactive Black 5. Journal of Hazardous Materials, 137, 1371-1376.
Lachheb, H., Puzenat, E., Houas, A., Ksibi, M., Elaloui, E., Guillard, C and Herrmann, J.-M. (2002) Photocatalytic Degradation of Various Types of Dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in Water by UV Irradiated Titania. Applied Catalysis B: Environmental,vol. 39, p. 75-90.
Chaudhuri, M., Elmolla, E. S. and Othman, R., 2009," Removal of Reactive Dyes from Aqueous Solution by Adsorption Coconut Coir Activated Carbon", 2nd International Conference on Engineering Technology (ICET 2009), December, Kuala Lumpur.
F. M. Hameed and K. M. Mousa, “Study on Kinetic and Optimization of Continuous Advanced Oxidative Decolorization of Brilliant Reactive Red Dye”, ijcpe, vol. 20, no. 1, pp. 9-14, Mar. 2019.
Downloads
Published
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.