MXenes: Types, preparation, and applications in water treatment
DOI:
https://doi.org/10.31699/IJCPE.2026.3.5Keywords:
MXene; 〖Ti〗_3 C_2 T_x; membranes; water treatment; nanofiltrationAbstract
MXenes have attracted significant attention as advanced 2D materials for water treatment, but previous assessments have been largely descriptive and have not adequately compared material types, manufacturing strategies, and practical performance. This paper aims to evaluate MXene-based membranes in terms of composition, surface chemistry, interlayer engineering and membrane design and to relate properties to water flux, rejection efficiency, adsorption capacity, antifouling behaviour and stability. Our goal is not to provide general summaries, but to highlight the critical points that will guide MXenes from laboratory demonstrations to real-world applications in water purification. This review also addresses major challenges including oxidation, restacking, swelling, mechanical fragility, scalability and environmental safety. Such a contrast between existing gaps and present advances provides a more lucid basis for the selection and design of MXene membranes in sustainable water treatment applications.
Received on 03/06/2026
Received in Revised Form on 31/07/2026
Accepted on 31/07/2026
Published on 30/09/2026
References
[1] A.K. Mohammed, S.M. Saadoon, Z.T. Abd Ali, I.M. Rashid, N. Hussin AL Sbani, "Removal of amoxicillin from contaminated water using modified bentonite as a reactive material," Heliyon. 10, 2024. https://doi.org/10.1016/j.heliyon.2024.e24916
[2] M.M.H. Hammad, K.W. Hameed, H.A. Sabti, "Reducing the Pollutants from Municipal Wastewater by Chlorella Vulgaris Microalgae," Al-Khwarizmi Engineering Journal. 15, 2019, 97–108. https://doi.org/10.22153/kej.2019.09.001
[3] R. Sangamnere, T. Misra, H. Bherwani, A. Kapley, R. Kumar, "A critical review of conventional and emerging wastewater treatment technologies," Sustainable Water Resources Management. 9, 2023, 58. https://doi.org/10.1007/s40899-023-00829-y
[4] K. Ji, Z. Liang, P. Wang, Z. Li, Q. Ma, X. Su, "Mxene-based capacitive enzyme-free biofuel cell Self-Powered sensor for lead ion detection in human plasma, " Chemical Engineering Journal. 495, 2024, 153598. https://doi.org/10.1016/J.CEJ.2024.153598
[5] D. Dhamodharan, M.A. Al-Harthi, B. Ramya, A. Bafaqeer, F. Alam, "MXenes: A promising material with multifunctional applications," Journal of Environmental Chemical Engineering. 12, 2024, 112316. https://doi.org/10.1016/J.JECE.2024.112316
[6] V. Hada, D. Malvi, M. Mili, M.M. Khan, G. Chaturvedi, S.A.R. Hashmi, A.K. Srivastava, S. Verma, "MXenes: promising 2D materials for wound dressing applications - a perspective review," Materials Advances. 3, 2022, 7445–7462. https://doi.org/10.1039/d1ma01199e
[7] S. Kumar, N. Kumari, Y. Seo, "MXenes: Versatile 2D materials with tailored surface chemistry and diverse applications," Journal of Energy Chemistry. 90, 2024, 253–293. https://doi.org/10.1016/J.JECHEM.2023.11.031
[8] T.K. Paul, M.A. Khaleque, M.R. Ali, M. Aly Saad Aly, M.S. Bacchu, S. Rahman, M.Z.H. Khan, "MXenes from MAX phases: synthesis, hybridization, and advances in supercapacitor applications," RSC Advances. 15, 2025, 8948–8976. https://doi.org/10.1039/d5ra00271k
[9] L. Liu, H. Zschiesche, M. Antonietti, M. Gibilaro, P. Chamelot, L. Massot, P. Rozier, P.L. Taberna, P. Simon, "In Situ Synthesis of MXene with Tunable Morphology by Electrochemical Etching of MAX Phase Prepared in Molten Salt," Advanced Energy Materials. 13, 2023. https://doi.org/10.1002/aenm.202203805
[10] Y. Liu, Y. Wu, X. Wang, "Thermal transports in the MXenes family: Opportunities and challenges," Nano Research. 17, 2024, 7700–7716. https://doi.org/10.1007/s12274-024-6763-6
[11] Z. Said, M.A. Sohail, H. Tabassum, I.H. Sajid, H.M. Ali, F. Jamil, Y.K. Mishra, A.K. Pandey, "MXenes at the forefront: advances in energy storage and nanofluidic applications," Springer International Publishing, 2025. https://doi.org/10.1007/s42114-025-01404-z
[12] R. Ghanbari, E. Nazarzadeh Zare, "Engineered MXene-polymer composites for water remediation: Promises, challenges and future perspective," Coordination Chemistry Reviews. 518, 2024, 216089. https://doi.org/10.1016/J.CCR.2024.216089
[13] Y. Sun, J. Lu, S. Li, C. Dai, D. Zou, W. Jing, "MXene-based membranes in water treatment: Current status and future prospects," Separation and Purification Technology. 331, 2024, 125640. https://doi.org/10.1016/J.SEPPUR.2023.125640
[14] T. Zhang, Z. Huang, D. Cui, Z. Luo, X. Zhuo, Y. Liu, X. Wang, K. Wu, J. Zhang, G. Li, S. Sun, H. Zuilhof, H. Lu, "2D lamellar membranes with defect-engineered hierarchical channels impart ultrafast and selective dye/salt separation," Journal of Membrane Science. 735, 2025, 124602. https://doi.org/10.1016/j.memsci.2025.124602
[15] C. Qiao, H. Wu, X. Xu, Z. Guan, W. Ou-Yang, "Electrical Conductivity Enhancement and Electronic Applications of 2D Ti3C2Tx MXene Materials," Advanced Materials Interfaces. 8, 2021, 2100903. https://doi.org/10.1002/admi.202100903
[16] Z. Hu, Y. Li, A. Li, H.H. Wang, X.F. Wang, "Dye-sensitized solar cells based on highly catalytic CNTs/Ti3C2Tx MXenes composite counter electrode," RSC Advances. 13, 2023, 34808–34816. https://doi.org/10.1039/d3ra06814e
[17] T. Jabeen, M. Rashid, S. Haider, M. Azam, "MXenes-based nanofiltration membranes for improved desalination performance: Recent advances and future prospects," Journal of Hazardous Materials Advances. 19, 2025, 100814. https://doi.org/10.1016/J.HAZADV.2025.100814
[18] S. Jayakumar, P.C. Santhosh, S. Ramakrishna, A. V. Radhamani, "2D (Ti3C2Tx) MXene: A comprehensive review of advancements in synthesis protocols, applications in supercapacitors, sustainability targets and future prospects," Journal of Energy Storage. 97, 2024, 112741. https://doi.org/10.1016/J.EST.2024.112741
[19] Z.W.S. Yuanjian Li, Xiang Feng, Wei Ying Lieu, Lin Fu, Chang Zhang, Tanmay Ghosh, Anupma Thakur, Brian C. Wyatt, Babak Anasori, Wei Liu, Qianfan Zhang, Jun Lu, "MXene-Based Anode-Free Magnesium Metal Battery," Advanced Functional Materials. 33, 2023. https://doi.org/10.1002/adfm.202303067
[20] B. Pant, M. Park, A.A. Kim, "MXene-Embedded Electrospun Polymeric Nanofibers for Biomedical Applications: Recent Advances," Micromachines. 14, 2023, 1–19. https://doi.org/10.3390/mi14071477
[21] N. Goel, A. Kushwaha, M. Kumar, "Two-dimensional MXenes: recent emerging applications," RSC Advances. 12, 2022, 25172–25193. https://doi.org/10.1039/d2ra04354h
[22] A. Koyappayil, S.G. Chavan, Y.-G. Roh, M.-H. Lee, "Advances of MXenes; Perspectives on Biomedical Research.," Biosensors. 12, 2022. https://doi.org/10.3390/bios12070454
[23] K.A. Papadopoulou, A. Chroneos, S.-R.G. Christopoulos, "Latest advances and comparative analysis of MXenes as anode and cathode electrodes in secondary batteries," Journal of Applied Physics. 133, 2023, 30901. https://doi.org/10.1063/5.0136840
[24] F. Dixit, K. Zimmermann, R. Dutta, N.J. Prakash, B. Barbeau, M. Mohseni, B. Kandasubramanian, "Application of MXenes for water treatment and energy-efficient desalination: A review," Journal of Hazardous Materials. 423, 2022, 127050. https://doi.org/10.1016/j.jhazmat.2021.127050
[25] H. Meskher, A.K. Thakur, S.K. Hazra, M.S. Ahamed, A.M. Saleque, Q.F. Alsalhy, M.W. Shahzad, M.N. Al Subri Ivan, S. Saha, I. Lynch, "Recent advances in applications of MXenes for desalination, water purification and as an antibacterial: a review," Environmental Science: Nano. 12, 2025, 1012–1036. https://doi.org/10.1039/d4en00427b
[26] Z.E. AlHadithy, A.A. AbdulRazak, A.M.H.A. Al-Ghaban, Q.F. Alsalhy, H. Meskher, R.A. Al-Juboori, K.K. Katibi, D.U. Lawal, "Advancements in Water Treatment with MXene-Enhanced Membranes: A Review of Current Progress and Future Directions," Springer International Publishing, 2024. https://doi.org/10.1007/s11270-024-07628-x
[27] A.M. Amani, M. Abbasi, A. Najdian, F. Mohamadpour, S.R. Kasaee, H. Kamyab, S. Chelliapan, M. Shafiee, L. Tayebi, A. Vaez, A. Najafian, E. Vafa, S. Mosleh-Shirazi, "MXene-based materials for enhanced water quality: Advances in remediation strategies," Ecotoxicology and Environmental Safety. 291, 2025, 117817. https://doi.org/10.1016/j.ecoenv.2025.117817
[28] C. Bhuyan, P. Bora, S. Hazarika, "MXenes in membrane engineering: Unlocking the new potential for water treatment," Water Supply. 25, 2025, 1209–1234. https://doi.org/10.2166/ws.2025.072
[29] E.S. Sowbakkiyavathi, P. Dhandapani, M. Neelakandan, G. Murali, I. In, S.J. Lee, A. Subramania, "A comprehensive review on MXenes: synthesis, stability, properties and their functionalization for M-ion batteries and supercapacitors," Nanoscale. 18, 2026, 640–693. https://doi.org/10.1039/d5nr03760c
[30] M.I.H. Protyai, A. Bin Rashid, "A comprehensive overview of recent progress in MXene-based polymer composites: Their fabrication processes, advanced applications, and prospects," Heliyon. 10, 2024, e37030. https://doi.org/10.1016/j.heliyon.2024.e37030
[31] Y. Jiang, "Applications and perspectives of Ti3C2Tx MXene in electrochemical energy storage systems," International Journal of Electrochemical Science. 20, 2025, 100948. https://doi.org/10.1016/j.ijoes.2025.100948
[32] Soni, M. Ahuja, P.K. Jagtap, V. Chauhan, S.K. Raj, P.P. Sharma, "The Advent of MXene-Based Synthetics and Modification Approaches for Advanced Applications in Wastewater Treatment," Membranes. 15, 2025. https://doi.org/10.3390/membranes15120364
[33] A. Bathla, "Implementation of MXenes for Water Treatment, in: O.P. Pandey, P. Sharma (Eds.), MXenes: Emerging 2D Materials, Springer Nature Singapore," Singapore, 2024, pp. 109–119. https://doi.org/10.1007/978-981-97-4064-2_6
[34] N.-S. Mussa, K. Askaruly, K. Bexeitova, S. Azat, K. Toshtay, "Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production," Carbon Trends. 20, 2025, 100551. https://doi.org/10.1016/j.cartre.2025.100551
[35] Y. Sun, J. Lu, S. Li, C. Dai, D. Zou, W. Jing, "MXene-based membranes in water treatment: Current status and future prospects," Separation and Purification Technology. 331, 2024, 125640. https://doi.org/10.1016/j.seppur.2023.125640
[36] P.O.Å. Persson, J. Rosen, "Current state of the art on tailoring the MXene composition, structure, and surface chemistry," Current Opinion in Solid State and Materials Science. 23, 2019, 100774. https://doi.org/10.1016/j.cossms.2019.100774
[37] X. Gao, Z. Li, J. Xue, Y. Qian, L. Zhang, J. Caro, H. Wang, "Titanium carbide Ti 3 C 2 T x ( MXene) enhanced PAN nanofiber membrane for air purification," Journal of Membrane Science. 586, 2019 162–169. https://doi.org/10.1016/j.memsci.2019.05.058
[38] N. Bisht, S. Jaiswal, J. Vishwakarma, S.K. Gupta, R.J. Yeo, S.K.R.S. Sankaranarayanan, C. Dhand, N. Dwivedi, "Mxene enhanced Shape Memory Polymer Composites: The rise of MXenes as fillers for stimuli-responsive materials," Chemical Engineering Journal. 498, 2024. https://doi.org/10.1016/j.cej.2024.155154
[39] Z. Lu, Y. Wei, J. Deng, L. Ding, Z.-K. Li, H. Wang, "Self-Crosslinked MXene (Ti3C2Tx) Membranes with Good Antiswelling Property for Monovalent Metal Ion Exclusion," ACS Nano. 13, 2019, 10535–10544. https://doi.org/10.1021/acsnano.9b04612
[40] Hou, H. Zhou, K. Zhu, C. Xie, S. Liu, Y. He, X. Zhu, M. Wu, T. Huang, "Superwetting Ti3C2TX MXene membranes intercalated with sodium alginate for oil/water separation," Carbohydrate Polymer Technologies and Applications. 5, 2023, 100278. https://doi.org/10.1016/J.CARPTA.2022.100278
[41] Qian, C. Yuan, X. Wang, H. Zhang, L. Du, G. Wei, S. Chen, "Conductive MXene ultrafiltration membrane for improved antifouling ability and water quality under electrochemical assistance," RSC Advances. 13, 2023, 15872–15880. https://doi.org/10.1039/d3ra01116j
[42] S. Jin, Y. Guo, F. Wang, A. Zhou,"The synthesis of MXenes," MRS Bulletin. 48, 2023, 245–252. https://doi.org/10.1557/s43577-023-00491-x
[43] J. Michael, Z. Qifeng, W. Danling, "Titanium carbide MXene: Synthesis, electrical and optical properties and their applications in sensors and energy storage devices," Nanomaterials and Nanotechnology. 9, 2019, 1–9. https://doi.org/10.1177/1847980418824470
[44] H. Kiran, A.B.M. Ali, R. Ashraf, M.B. Tahir, M. Nasir, N. Hasnain, M.F. Ullah, D. Abduvalieva, N. Batool, "Comparative Study of Ti3C2Tx MXene Synthesized via HF and LiF-HCl Etching: Structural, Optical, and Photocatalytic Insights," Journal of Inorganic and Organometallic Polymers and Materials. 35, 2025, 9565–9578. https://doi.org/10.1007/s10904-025-03832-2
[45] S. Nouseen, M. Pumera, "Electrochemical etching of MXenes: mechanism, challenges and future outlooks," Journal of Materials Chemistry A. 13, 2025, 34055–34084. https://doi.org/10.1039/d5ta04176g
[46] F. Wang, S. Wang, F. Tian, F. Wang, X. Xia, Q. Zhang, Z. Pang, X. Yu, G. Li, H.-Y. Hsu, S. Hu, L. Ji, Q. Xu, Y. Zhao, X. Zou, X. Lu, "Advances in molten-salt-assisted synthesis of 2D MXenes and their applications in electrochemical energy storage and conversion," Chemical Engineering Journal. 470, 2023, 144185. https://doi.org/10.1016/j.cej.2023.144185
[47] Mahabari, R.D. Mohili, M. Patel, A.H. Jadhav, K. Lee, N.K. Chaudhari, "HF-free microwave-assisted synthesis of MXene as an electrocatalyst for hydrogen evolution in alkaline media," Nanoscale Advances. 6, 2024, 5388–5397. https://doi.org/10.1039/D4NA00250D
[48] W. Huang, J. Wang, W. Lai, M. Guo, "MXene Surface Architectonics: Bridging Molecular Design to Multifunctional Applications," Molecules. 30, 2025. https://doi.org/10.3390/molecules30091929
[49] T. Amrillah, C.A.C. Abdullah, A. Hermawan, F.N.I. Sari, V.N. Alvani, "Towards Greener and More Sustainable Synthesis of MXenes: A Review," Nanomaterials. 12, 2022. https://doi.org/10.3390/nano12234280
[50] A. Keneshbekova, G. Smagulova, B. Kaidar, A. Imash, A. Ilyanov, R. Kazhdanbekov, E. Yensep, A. Lesbayev, "MXene/Carbon Nanocomposites for Water Treatment," Membranes. 14, 2024. https://doi.org/10.3390/membranes14090184
[51] H. Jain, L. Singh, A. Shrivastava, M. Paul, H. Horo, H.S. Samuel, "MXene-enhanced polymer nanocomposite membranes for next-generation wastewater treatment and desalination," Next Materials. 10, 2026, 101574. https://doi.org/10.1016/j.nxmate.2025.101574
[52] K. Maleski, M. Alhabeb, "Top-Down MXene Synthesis (Selective Etching), in: B. Anasori, Y. Gogotsi (Eds.), 2D Metal Carbides and Nitrides (MXenes): Structure, Properties and Applications," Springer International Publishing, Cham, 2019, pp. 69–87. https://doi.org/10.1007/978-3-030-19026-2
[53] Ahmadi Bonakdar, D. Rodrigue, M.A. Bonakdar, D. Rodrigue, "Electrospinning: Processes, Structures, and Materials," Macromol. 4, 2024, 58–103. https://doi.org/10.3390/macromol4010004
[54] Al-Furaiji, M. Kadhom, K. Kalash, B. Waisi, N. Albayati, "Preparation of thin-film composite membranes supported with electrospun nanofibers for desalination by forward osmosis," Drinking Water Engineering and Science. 13, 2020, 51–57. https://doi.org/10.5194/dwes-13-51-2020
[55] M. Mozafari, M. Soroush, "Surface functionalization of MXenes," Materials Advances. 2, 2021, 7277–7307. https://doi.org/10.1039/d1ma00625h
[56] I.A. Khan, L.T. Yogarathinam, H. Younas, A. Mushtaq, I.H. Aljundi, N. Baig, "The rise of MXenes: Synthesis, properties, and fabrication of advanced membranes," Desalination. 620, 2026, 119598. https://doi.org/10.1016/j.desal.2025.119598
[57] Y. Han, J. Hu, X. Liu, F. Liu, "Progress in Surface and Interface Modification Strategies of MXene Materials for Energy Storage Applications," Materials. 18, 2025, 1–33. https://doi.org/10.3390/ma18153576
[58] R. Patel, K. Mahabari, K. Patel, M. Patel, A.H. Jadhav, S. Dharaskar, R.R. Karri, N. Chaudhari, "MoS2/MXene composite material for high-performance removal of Rhodamine B dye: synthesis and application," Scientific Reports. 15, 2025, 42099. https://doi.org/10.1038/s41598-025-26240-5
[59] A. Sreekumar, A.R. Nair, A. Raman, A. Sivan, M. Pandey, K. Deshmukh, S. Appukuttan, "MXene-Reinforced Polymer Composite Membranes for Water Desalination and Wastewater Treatment," Wiley Semiconductors, 2024, 459-500. https://doi.org/10.1002/9781119901280.ch14
[60] Z. Huang, D. Ling Zhao, L. Shen, H. Lin, C. Chen, Y. Xu, B. Li, J. Teng, L. Han, T.-S. Chung, "Mxenes for membrane separation: from fabrication strategies to advanced applications," Science Bulletin. 69, 2024, 125–140. https://doi.org/10.1016/j.scib.2023.11.008
[61] R. Imsong, D. Dhar Purkayastha, "Dual-functional superhydrophilic/underwater superoleophobic 2D Ti3C2TX MXene-PAN membrane for efficient oil-water separation and adsorption of organic dyes in wastewater," Separation and Purification Technology. 306, 2023, 122636. https://doi.org/10.1016/j.seppur.2022.122636
[62] Riaz, Z. Hussain, H. Pan, Z. Lin, "Engineering MXenes for advanced organic coatings: Synthesis, surface functionalization, corrosion protection performance, and future perspectives," Progress in Organic Coatings. 217, 2026, 110219. https://doi.org/10.1016/j.porgcoat.2026.110219
[63] M. Danish, M. Tayyab Raza, M. Iftikhar, I. Hassan, S.A. Husnain, M. Muneeb ul Hassan, M. Mumtaz, A.M. Khan, H. Noor, F. Shahzad, "Spray deposited Graphene@MXene on a flexible polymer substrate for Terahertz Shielding," Materials Chemistry and Physics. 311, 2024, 128573. https://doi.org/10.1016/j.matchemphys.2023.128573
[64] S. Hu, P. Han, S. Zhang, J. Wang, C. Meng, G. Wei, Z. Gu, "Layer-by-layer assembling MXene /poly(3-glycidyloxypropyldimethoxymethylsilane) hierarchical structure onto carbon fibers for high-performance carbon fiber/epoxy composites," Composites Science and Technology. 241, 2023, 110149. https://doi.org/10.1016/j.compscitech.2023.110149
[65] S. Chen, Y. Du, X. Zhang, Y. Xie, Z. Shi, H. Ji, W. Zhao, C. Zhao, "One-step electrospinning of negatively-charged polyethersulfone nanofibrous membranes for selective removal of cationic dyes," Journal of the Taiwan Institute of Chemical Engineers. 82, 2018, 179–188. https://doi.org/10.1016/J.JTICE.2017.11.018
[66] X. Gao, Z.K. Li, J. Xue, Y. Qian, L.Z. Zhang, J. Caro, H. Wang, "Titanium carbide Ti3C2Tx (MXene) enhanced PAN nanofiber membrane for air purification," Journal of Membrane Science. 586, 2019, 162–169. https://doi.org/10.1016/j.memsci.2019.05.058
[67] L. Zhang, Y. Liu, G. Zeng, Z. Yang, Q. Lin, Y. Wang, X. Wang, S. Pu, "Two-dimensional Na-Bentonite@MXene composite membrane with switchable wettability for selective oil/water separation," Separation and Purification Technology. 306, 2023, 122677. https://doi.org/10.1016/J.SEPPUR.2022.122677
[68] Y. Du, J. Yu, B. Chen, X. Zhu, "Recent progresses in the modification strategies of MXene-based membranes for water and wastewater treatments," Environmental Science: Nano. 12, 2025, 150–188. https://doi.org/10.1039/D4EN00712c
[69] H. Zhang, M. Yong, T. Hu, Y. Kang, Z. Wang, Z. Xu, X. Li, X. Sun, L. Guo, F. Sheng, X. Zeng, Z. Li, X. Li, H. Wang, T. Xu, X. Zhang, "Multifunctional intercalants create stable subnanochannels in MoS2 membranes for wastewater treatment," Nature Communications. 16, 2025, 8353. https://doi.org/10.1038/s41467-025-58409-x
[70] M.H. Munshi, S.A. Hussain, M. Akter, M.A. Hakim, M.A. Hasan, M.J. Kabir, M. Kamruzzaman, T. Islam, "MXene-Based Polymer Composites for Advanced Filtration: Properties, Fabrication, and Future Directions," ChemistrySelect. 11, 2026. https://doi.org/10.1002/slct.202506512
[71] A.A. Bankole, R.S.B. Zakari, K. Ahmad, M. Abi Jaoude, "Challenges and Opportunities Associated with the Development of Functionalized Electrospun Fibers, in: S. Garg, A. Chandra, S. Sagadevan (Eds.), Emerging Sustainable Nanomaterials for Biomedical Applications," Springer Nature Switzerland, Cham, 2024, pp. 301–331. https://doi.org/10.1007/978-3-031-63961-6_12
[72] H.S. Al-Okaidy, B.I. Waisi, "The Effect of Electrospinning Parameters on Morphological and Mechanical Properties of PAN-based Nanofibers Membrane," Baghdad Science Journal. 20, 2023, 1433–1441. https://doi.org/10.21123/bsj.2023.7309
[73] P.O.Å. Persson, MXene Surface Chemistry, in: B. Anasori, Y. Gogotsi (Eds.), "2D Metal Carbides and Nitrides (MXenes): Structure, Properties and Applications," Springer International Publishing, Cham, 2019, pp. 125–136. https://doi.org/10.1007/978-3-030-19026-2_8
[74] Q. Zhao, S. Huang, X. Han, J. Chen, X. Ma, " Highly active and controllable MOF-derived carbon nanosheets supported iron catalysts for Fischer–Tropsch synthesis," Carbon. 173, 2021. https://doi.org/10.1016/j.carbon.2020.11.019
[75] Q. Feng, Y. Zhan, W. Yang, H. Dong, A. Sun, L. Li, X. Chen, Y. Chen, "Ultra-high flux and synergistically enhanced anti-fouling Ag@MXene lamellar membrane for the fast purification of oily wastewater through nano-intercalation, photocatalytic self-cleaning and antibacterial effect," Separation and Purification Technology. 298, 2022, 121635. https://doi.org/10.1016/j.seppur.2022.121635
[76] M. Wu, B. Wang, Q. Hu, L. Wang, A. Zhou, "The Synthesis Process and Thermal Stability of V2C MXene," Materials. 11, 2018. https://doi.org/10.3390/ma11112112
[77] O.J. Kewate, I. Hussain, N. Tyagi, S. Saxena, K. Zhang, E.G. Rajamansingh, N. Chinnappan, H. Joshi, S. Punniyakoti, "Nb-based MXenes: Structures, properties, synthesis, and application towards supercapacitors," Journal of Energy Storage. 94, 2024, 112445. https://doi.org/10.1016/j.est.2024.112445
[78] S. Kumar, M. Taunk, "2D MXenes for flexible device applications," Materials Today Physics. 46, 2024, 101483. https://doi.org/10.1016/J.MTPHYS.2024.101483
[79] M. Ilyas, M. Younas, M.U.H. Shah, W.U. Rehman, A.U. Rehman, Z.H. Yuan, Y.M. Zheng, M. Sheikh, M. Rezakazemi, "MXene-based 2D Ti3C2Tx nanosheets for highly efficient cadmium (Cd2+) adsorption," Journal of Water Process Engineering. 55, 2023, 104131. https://doi.org/10.1016/J.JWPE.2023.104131
[80] M. Kaur, U. Krishnan, P. Sharma, K. Kaur, R.K. Sharma, A. Kumar, "MXenes in action: Adsorption strategies for environmental contaminants," Journal of Alloys and Compounds. 1034, 2025, 181350. https://doi.org/10.1016/j.jallcom.2025.181350
[81] Z. Othman, H.R. Mackey, K.A. Mahmoud, "A critical overview of MXenes adsorption behavior toward heavy metals," Chemosphere. 295, 2022, 133849. https://doi.org/10.1016/j.chemosphere.2022.133849
[82] Karthikeyan, S.S. Elanchezhiyan, J. Preethi, K. Talukdar, S. Meenakshi, C.M. Park, "Two-dimensional (2D) Ti3C2Tx MXene nanosheets with superior adsorption behavior for phosphate and nitrate ions from the aqueous environment," Ceramics International. 47, 2021, 732–739. https://doi.org/10.1016/J.CERAMINT.2020.08.183
[83] S. Sharma, M. Mishra, H. Sharma, A.S. Chauhan, B. Das, D. Rajput, V. Pandey, R.B. Tripathi, R. Sharma, "Polymeric nanocomposites: Recent advances, challenges, techniques, and biomedical applications," Annales Pharmaceutiques Françaises. 83, 2025, 1019–1039. https://doi.org/10.1016/j.pharma.2025.06.003
[84] B.M. Jun, M. Jang, C.M. Park, J. Han, Y. Yoon, "Selective adsorption of Cs+ by MXene (Ti3C2Tx) from model low-level radioactive wastewater," Nuclear Engineering and Technology. 52, 2020, 1201–1207. https://doi.org/10.1016/J.NET.2019.11.020
[85] Z.H. Zhang, J.Y. Xu, X.L. Yang, "MXene/sodium alginate gel beads for adsorption of methylene blue," Materials Chemistry and Physics. 260, 2021, 124123. https://doi.org/10.1016/J.MATCHEMPHYS.2020.124123
[86] Z. Wei, Z. Peigen, T. Wubian, Q. Xia, Z. Yamei, S. ZhengMing, "Alkali treated Ti3C2Tx MXenes and their dye adsorption performance," Materials Chemistry and Physics. 206, 2018, 270–276. https://doi.org/10.1016/j.matchemphys.2017.12.034
[87] Sun, F. Zheng, M. Zhu, Z. Song, K. Wang, M. Zhong, D. Wu, R.B. Little, Z. Xu, H. Zhu, "Selective Trans-Membrane Transport of Alkali and Alkaline Earth Cations through Graphene Oxide Membranes Based on Cation−π Interactions," ACS Nano. 8, 2014, 850–859. https://doi.org/10.1021/nn4055682
[88] S. Wang, F. Wang, Y. Jin, X. Meng, B. Meng, N. Yang, J. Sunarso, S. Liu, "Removal of heavy metal cations and co-existing anions in simulated wastewater by two separated hydroxylated MXene membranes under an external voltage," Journal of Membrane Science. 638, 2021, 119697. https://doi.org/10.1016/j.memsci.2021.119697
[89] Y. Sun, Z. Xu, Y. Zhuang, G. Liu, W. Jin, G. Liu, W. Jing, "Tunable dextran retention of MXene-TiO2 mesoporous membranes by adjusting the 2D MXene content," 2D Materials. 5, 2018, 45003. https://doi.org/10.1088/2053-1583/aad01e
[90] Y. Yan, H. Han, Y. Dai, H. Zhu, W. Liu, X. Tang, W. Gan, H. Li, "Nb2CTx MXene Nanosheets for Dye Adsorption," ACS Applied Nano Materials. 4, 2021, 11763–11769. https://doi.org/10.1021/acsanm.1c02339
[91] Y. Abraham Swu, D. Dhar Purkayastha, "V2CTx MXene for sustainable wastewater treatment: Inspired by the exoskeletons of nature’s microscopic architects," Applied Surface Science. 680, 2025, 161365. https://doi.org/10.1016/j.apsusc.2024.161365
[92] Z. Yin, Z. Lu, Y. Xu, Y. Zhang, L. He, P. Li, L. Xiong, L. Ding, Y. Wei, H. Wang, "Supported MXene/GO Composite Membranes with Suppressed Swelling for Metal Ion Sieving," Membranes. 11, 2021. https://doi.org/10.3390/membranes11080621
[93] G. Liu, J. Shen, Q. Liu, G. Liu, J. Xiong, J. Yang, W. Jin, "Ultrathin two-dimensional MXene membrane for pervaporation desalination," Journal of Membrane Science. 548, 2018, 548–558. https://doi.org/10.1016/J.MEMSCI.2017.11.065
[94] C.E. Ren, M. Alhabeb, B.W. Byles, M.-Q. Zhao, B. Anasori, E. Pomerantseva, K.A. Mahmoud, Y. Gogotsi, "Voltage-Gated Ions Sieving through 2D MXene Ti3C2Tx Membranes," ACS Applied Nano Materials. 1, 2018, 3644–3652. https://doi.org/10.1021/acsanm.8b00762
[95] Rasool, K.A. Mahmoud, D.J. Johnson, M. Helal, G.R. Berdiyorov, Y. Gogotsi, "Efficient Antibacterial Membrane based on Two-Dimensional Ti3C2Tx (MXene) Nanosheets," Scientific Reports. 7, 2017, 1598. https://doi.org/10.1038/s41598-017-01714-3
[96] N.M. Jabbar, S.D. Salman, I.M. Rashid, Y.S. Mahdi, "Removal of an anionic Eosin dye from aqueous solution using modified activated carbon prepared from date palm fronds," Chemical Data Collections. 42, 2022, 100965. https://doi.org/10.1016/j.cdc.2022.100965
[97] B.-M. Jun, J. Heo, N. Taheri-Qazvini, C.M. Park, Y. Yoon, "Adsorption of selected dyes on Ti3C2Tx MXene and Al-based metal-organic framework," Ceramics International. 46, 2020, 2960–2968. https://doi.org/10.1016/j.ceramint.2019.09.293
[98] K.E. Talib, S.D. Salman, "Removal of Malachite Green from Aqueous Solution using Ficus Benjamina Activated Carbon-Nonmetal Oxide synthesized by pyro Carbonic Acid Microwave," Al-Khwarizmi Engineering Journal. 19, 2023, 26–38. https://doi.org/10.22153/kej.2023.03.002
[99] Lin, W. Ye, M. Xie, D.H. Seo, J. Luo, Y. Wan, B. Van der Bruggen, "Environmental impacts and remediation of dye-containing wastewater," Nature Reviews Earth & Environment. 4, 2023, 785–803. https://doi.org/10.1038/s43017-023-00489-8
[100] C. Peng, P. Wei, X. Chen, Y. Zhang, F. Zhu, Y. Cao, H. Wang, H. Yu, F. Peng, "A hydrothermal etching route to synthesis of 2D MXene (Ti3C2, Nb2C): Enhanced exfoliation and improved adsorption performance," Ceramics International. 44, 2018, 18886–18893. https://doi.org/10.1016/J.CERAMINT.2018.07.124
[101] V.N. Sahith, A. Kumar J, V.S. Sruthi, T. Krithiga, S. Sundararaman, P. Deivasigamani, D. Venkatesan, M. Anish, A. Hosseini-Bandegharaei, "Mxenes-based sorbents: Pioneering nanomaterials and its mechanism for advanced dye remediation in aqueous environments," Next Materials. 9, 2025, 101029. https://doi.org/10.1016/j.nxmate.2025.101029
[102] Q.A. Hind S. AbdulhayHameed;, "Bioremoval of Chromium by Local Isolates of Pseudomonas aeruginosa in Respect to its Genotype," Iraqi Journal of Sciences. 57, 2016.
[103] T. Liu, J.H. Hou, J.B. Wang, W. Wang, X.Y. Wang, J.L. Wu, "Biosorption of heavy metals from aqueous solution by the novel biosorbent Pectobacterium sp. ND2," Environmental Progress and Sustainable Energy. 37, 2018, 968–974. https://doi.org/10.1002/ep.12757
[104] W. Khalid, S.D. Salman, "Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon," Al-Khwarizmi Engineering Journal. 15, 2019, 60–69. https://doi.org/10.22153/kej.2019.04.001
[105] P.G. shekhi Abadi, M. Irani, L.R. Rad, "Mechanisms of the removal of the metal ions, dyes, and drugs from wastewaters by the electrospun nanofiber membranes," Journal of the Taiwan Institute of Chemical Engineers. 143, 2023, 104625. https://doi.org/10.1016/J.JTICE.2022.104625
[106] C. Zhang, Y. Ma, X. Zhang, S. Abdolhosseinzadeh, H. Sheng, W. Lan, A. Pakdel, J. Heier, F. Nüesch, "Two-Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications," Energy and Environmental Materials. 3, 2020, 29–55. https://doi.org/10.1002/eem2.12058
[107] Y. Gong, X. Xing, Y. Wang, Z. Lv, Y. Zhou, S.-T. Han, "Emerging MXenes for Functional Memories," Small Science. 1, 2021, 2100006. https://doi.org/10.1002/smsc.202100006
[108] Z. Ajmal, A. Qadeer, K. Singh, A. Al Mahmud, M.N. Lakhan, H. Pradeep, B. Hussain, A. Ullah, H.R. Khan, E.H. Ibrahim, O.J. Kewate, J. Cui, P. Rosaiah, B. Akkinepally, I. Hussain, W. Shuhang, "A comprehensive review on MXenes for various applications," Applied Energy. 397, 2025, 126136. https://doi.org/10.1016/j.apenergy.2025.126136
[109] Ahmaruzzaman, "MXenes and MXene-supported nanocomposites: a novel materials for aqueous environmental remediation.," RSC Advances. 12 2022 34766–34789. https://doi.org/ 10.1039/d2ra05530a
[110] N.N. Safi, B.I. Waisi, "Mathematical and experimental study of the direct contact membrane distillation method for desalination using a hydrophobic electrospun nanofibers membrane," Iraqi Journal of Chemical and Petroleum Engineering. 25, 2024, 123–137. https://doi.org/10.31699/IJCPE.2024.4.12
[111] X. Feng, Z. Yu, R. Long, Y. Sun, M. Wang, X. Li, G. Zeng, "Polydopamine intimate contacted two-dimensional/two-dimensional ultrathin nylon basement membrane supported RGO/PDA/MXene composite material for oil-water separation and dye removal," Separation and Purification Technology. 247, 2020, 116945. https://doi.org/10.1016/j.seppur.2020.116945
[112] B. Sun, P. Qiu, Z. Liang, Y. Xue, X. Zhang, L. Yang, H. Cui, J. Tian, "The fabrication of 1D/2D CdS nanorod@Ti3C2 MXene composites for good photocatalytic activity of hydrogen generation and ammonia synthesis," Chemical Engineering Journal. 406, 2021, 127177. https://doi.org/10.1016/J.CEJ.2020.127177
[113] M.U. Hameed, Z. Amjad, B. Al Alwan, A. El Jery, H.M.A. Hassan, L. Ali, A. Ahmad, S. Khan, S. Raza, "Recent progress in 2D-MXene-based membranes for water treatments; fabrication, properties, and advanced desalination application," Desalination. 599, 2025, 118462. https://doi.org/10.1016/j.desal.2024.118462
[114] Soni, M. Ahuja, P.K. Jagtap, V. Chauhan, S.K. Raj, P.P. Sharma, "The Advent of MXene-Based Synthetics and Modification Approaches for Advanced Applications in Wastewater Treatment," Membranes. 15, 2025, 1–21. https://doi.org/10.3390/membranes15120364
[115] Z. Zeng, L. Song, L. Ding, H. Wang, "MXene-Based Membranes for Selective Ion Separation," Membranes. 16, 2026. https://doi.org/10.3390/membranes16040146
[116] W.K. Al-Musawy, B.I. Waisi, M.H. Al-Furaiji, A. Shehan, M. Jahangiri, "Preparation, Characterization, and Evaluation of Electrospun Copolymer Nanofiber Membranes for Kerosene Removal from Aqueous Solution," Al-Khwarizmi Engineering Journal. 22, 2026, 1–13. https://doi.org/10.22153/kej.2026.12.010
[117] K. Abuhasel, M. Kchaou, M. Alquraish, Y. Munusamy, Y.T. Jeng, "Oily Wastewater Treatment: Overview of Conventional and Modern Methods, Challenges, and Future Opportunities," Water. 13, 2021. https://doi.org/10.3390/w13070980
[118] Y. Xin, B. Qi, X. Wu, C. Yang, B. Li, "Different types of membrane materials for oil-water separation: Status and challenges," Colloid and Interface Science Communications. 59, 2024,100772. https://doi.org/10.1016/J.COLCOM.2024.100772
[119] Sun, W. Ye, J. Zhang, K. Zheng, Structure, "Properties, and Preparation of MXene and the Application of Its Composites in Supercapacitors," Inorganics. 12, 2024. https://doi.org/10.3390/inorganics12040112
[120] A.R. Jabur, L.K. Abbas, S.A. Moosa, "Antibacterial Activity of Electrospun Silver Nitrate /Nylon 6 Polymeric Nanofiber Water Filtration Mats," Al-Khwarizmi Engineering Journal. 13, 2017, 84–93. https://doi.org/10.22153/kej.2017.10.001
[121] B. Sarac, S. Yücer, F. Ciftci, "MXenes in microbiology and virology: from pathogen detection to antimicrobial applications," Nanoscale. 17, 2025, 9619–9651. https://doi.org/10.1039/d5nr00477b
[122] Y. Liu, X. Chen, J. Sun, N. Xu, Q. Tang, J. Ren, C. Chen, W. Lei, C. Zhang, D. Liu, "Large-scale production of MXenes as nanoknives for antibacterial application," Nanoscale Advances. 5, 2023, 6572–6581. https://doi.org/10.1039/D3NA00744H
[123] Basma I. Waisi, "Carbonized Copolymers Nonwoven Nanofibers Composite: Surface Morphology and Fibers Orientation," Iraqi Journal of Chemical and Petroleum Engineering. 2, 2019. https://doi.org/10.31699/IJCPE.2019.2.2
[124] S. Raut, J.K. Sahoo, S.K. Sahoo, "Electrospun MXene based functionalized nanofibers for water pollutants adsorption: Potentials, challenges and future perspective," Journal of Molecular Liquids. 433, 2025, 127871. https://doi.org/10.1016/J.MOLLIQ.2025.127871
[125] W. Bao, H. Shen, G. Zeng, Y. Zhang, Y. Wang, D. Cui, J. Xia, K. Jing, H. Liu, C. Guo, F. Yu, K. Sun, J. Li, "Engineering the next generation of MXenes: challenges and strategies for scalable production and enhanced performance," Nanoscale. 17, 2025, 6204–6265. https://doi.org/10.1039/D4NR04560B
[126] Z.E. AlHadithy, A.A. AbdulRazak, A.M.H.A. Al-Ghaban, Q.F. Alsalhy, H. Meskher, R.A. Al-Juboori, K.K. Katibi, D.U. Lawal, "Advancements in Water Treatment with MXene-Enhanced Membranes: A Review of Current Progress and Future Directions," Water, Air, & Soil Pollution. 235, 2024, 809. https://doi.org/10.1007/s11270-024-07628-x
Downloads
Published
Issue
Section
License
Copyright (c) 2026 The Author(s). Published by College of Engineering, University of Baghdad.

This work is licensed under a Creative Commons Attribution 4.0 International License.







