Thermal and Catalytic Degradation Kinetics of High-Density Polyethylene Over NaX Nano-Zeolite
Keywords:Thermal degradation, HDPE, NaX Zeolite, TGA, Coats and Redfern, kinetic analysis.
Thermal and catalytic pyrolysis of waste plastics in an inert atmosphere has been regarded as a creative method, since pyrolysis can convert plastics waste into hydrocarbons that can be used either as fuels or as a source of chemicals.
Natural Iraqi kaolin clay was used to synthesis the NaX nano- zeolite by hydrothermal conditions with average particle size equal to 77.63nm.Thermal decomposition kinetics of high-density polyethylene (HDPE) in the absence and presence of catalysts nano NaX Zeolite was investigated. Thermal and catalytic degradation of HDPE was performed using a thermogravimetric analyzer in nitrogen atmosphere under non-isothermal conditions 4, 7 and 10 °C/min heating rates were employed in thermogravimetric analysis (TGA) experiments.
First-order decomposition reaction was assumed, and for the kinetic analysis Coats and Redfern (CR) method was used. The apparent activation energy (Ea) was evaluated. Results showed that the NaX nano-zeolite decreases the activation energy (Ea) of HDPE pyrolysis further than the thermal pyrolysis.
How to Cite
Copyright (c) 2023 Iraqi Journal of Chemical and Petroleum Engineering
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
For papers published in IJCPE, authors and their institutions all have the same rights to reuse articles published in the journal in accordance with the journal by IJCPE is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. This permits users to copy, redistribute, remix, transmit and adapt the work provided the original work and source is appropriately cited. Please check the license for full license terms and attribution requirements.