Adsorption of Flagyl on Prepared Ash from Rice Husk
DOI:
https://doi.org/10.31699/IJCPE.2021.4.2Keywords:
Amber rice, Flagyl, rice husk, adsorptionAbstract
In recent years, it has been evident that searching for alternative methods with low-price and eco-friendly features that produce high-quality adsorbents is in high demand. In the present work, Rice husk from Iraqi rice named (Amber) had been used as the primary source to produce rice husk ash (RHA) for the removal of the antibiotic metronidazole (Flagyl) from water. After optimum drying of rice husk, rice husk ash (RHA) was obtained at 600 °C using an electric oven. RHA has been investigated for properties using X-ray diffraction (XRD), porosity, and surface area (SA). The experimental work adsorption data were optimized to evaluate Langmuir and Freundlich constants. The thermodynamic parameters likely a change in Gipp's energy (ΔG), enthalpy (ΔH), and entropy (ΔS). The impacts of increasing temperature on adsorption capacity were investigated, and the results indicate that the pseudo-second-order kinetics model could be presented the dynamic adsorption data that it has. The resultant values for the heat of adsorption and the free energy indicated that adsorption of Flagyl is preferred at low temperatures.
Received on 08/12/2021
Accepted on 29/12/2021
Published on 30/12/2021
References
Escher BI, Baumgartner R, Koller M, Treyer K, Lienert J, McArdell CS. Environmental toxicology and risk assessment of pharmaceuticals from hospital wastewater. Water research. 2011 Jan 1;45(1):75-92.
Larsson DJ. Pollution from drug manufacturing: review and perspectives. Phil. Trans. R. Soc. B. 2014 Nov 19;369(1656):20130571.
Boxall A. B. New and emerging water pollutants arising from agriculture: 2012.
Sorell TL. Approaches to the development of human health toxicity values for active pharmaceutical ingredients in the environment. The AAPS journal. 2016 Jan 1;18(1):92-101.
Lien LT, Hoa NQ, Chuc NT, et al. Antibiotics in Wastewater of a Rural and an Urban Hospital before and after Wastewater Treatment, and the Relationship with Antibiotic Use-A One Year Study from Vietnam. Int J Environ Res Public Health. 2016;13(6):588. Published 2016 Jun 14. doi:10.3390/ijerph13060588.
Shakti Rath, bydute kumar Dispersal of Antibiotic Resistant Bacteria into Aquatic Environment - An Overview. iMedPub Journals. 2018. Published:February 07, 2018. Vol.1 No.1:2.
Rodriguez-Mozaz S, Chamorro S, Marti E, Huerta B, Gros M, Sànchez-Melsió A, Borrego CM, Barceló D, Balcázar JL. Occurrence of antibiotics and antibiotic resistance genes in hospital and urban wastewaters and their impact on the receiving river. Water research. 2015 Feb 1;69:234-42.
Metronidazole: MedlinePlus Drug Information. Available at https://medlineplus.gov › Drugs, Herbs and Supplements
Pharmaceutical Wastewater Effluent-Source of Contaminants of Emerging Concern: Phytotoxicity of Metronidazole to Soybean (Glycine max). Toxics. 2017;5(2):10. Published 2017 Apr 2. doi:10.3390/toxics5020010.
metronidazole:Topics by Science.gov Retrieved from https://www.science.gov/topicpages/m/metronidazole
Shraim A, Diab A, Alsuhaimi A, Niazy E, Metwally M, Amad M, Sioud S, Dawoud A. Analysis of some pharmaceuticals in municipal wastewater of Almadinah Almunawarah. Arabian Journal of Chemistry. 2017 Feb 1;10:S719-29.
Nasseh I, Khodadadi M, Khosravi R, Beirami A, Nasseh N. Metronidazole Removal Methods from Aquatic Media: A Systematic Review. Annals of Military and Health Sciences Research. 2016;14(4).
Ahmaruzzaman M, Gupta VK. Rice husk and its ash as low-cost adsorbents in water and wastewater treatment. Industrial & Engineering Chemistry Research. 2011 Nov 23;50(24):13589-613.
Foo KY, Hameed BH. Utilization of rice husk ash as novel adsorbent: a judicious recycling of the colloidal agricultural waste. Advances in colloid and interface science. 2009 Nov 30;152(1-2):39-47.
Production of high quality rice husk ash- Greenwich Academic literature archive (GALA). Retrieved from http://gala.gre.ac.uk/12130
Mulugeta M, Lelisa B. Removal of methylene blue (Mb) dye from aqueous solution by bioadsorption onto untreated Parthenium hystrophorous weed. Modern Chemistry & Applications. 2014 Dec 30.
S. Mondal, “Methods of dye removal from dye house effluent—an overview,” Environmental Engineering Science, vol. 25, no. 3, pp. 383–396, 2008.
Mohammed MA, Shitu A, Ibrahim A. Removal of methylene blue using low cost adsorbent: a review. Research Journal of Chemical Sciences ISSN. 2014;2231:606X.
Ghorai S, Sarkar A, Raoufi M, Panda AB, Schönherr H, Pal S. Enhanced removal of methylene blue and methyl violet dyes from aqueous solution using a nanocomposite of hydrolyzed polyacrylamide grafted xanthan gum and incorporated nanosilica. ACS applied materials & interfaces. 2014 Mar 21;6(7):4766-77.
G. Crini, “Non-conventional low-cost adsorbents for dye removal: a review,” Bioresource Technology, vol. 97, no. 9, pp. 1061–1085, 2006.
Khamparia S, Jaspal D, Malviya A. Optimization of adsorption process for removal of sulphonated di azo textile dye. Green Chemistry & Technology Letters. 2015 Nov 19;1(01):61-6.
Barno, Suondos KA, and Ammar S. Abbas. "Reduction of Organics in Dairy Wastewater by Adsorption on a Prepared Charcoal from Iraqi Sugarcane." In IOP Conference Series: Materials Science and Engineering, vol. 736, no. 2, p. 022096. IOP Publishing, 2020.
A. R. Tehrani-Bagha, H. Nikkar, N. M. Mahmoodi, M. Markazi, and F. M. Menger, “The sorption of cationic dyes onto kaolin: kinetic, isotherm and thermodynamic studies,” Desalination, vol. 266, no. 1–3, pp. 274–280, 2011.
Barno, Suondos KA, Haider J. Mohamed, Siham M. Saeed, Mohammed J. Al-Ani, and Ammar S. Abbas. "Prepared 13X Zeolite as a Promising Adsorbent for the Removal of Brilliant Blue Dye from Wastewater." Iraqi Journal of Chemical and Petroleum Engineering 22, no. 2 (2021): 1-6.
A. S. Abbas and S. A. Hussien, “Equilibrium, Kinetic and Thermodynamic Study of Aniline Adsorption over Prepared ZSM-5 Zeolite,” Iraqi J. Chem. Pet. Eng., vol. 18, no. 1, pp. 47–56, 2017.
R. K. Abid and A. S. Abbas, “Adsorption of organic pollutants from real refinery wastewater on prepared cross-linked starch by epichlorohydrin,” Data Br., vol. 19, pp. 1318–1326, 2018, doi: 10.1016/j.dib.2018.05.060.
F. K. Al-Jubory, I. M. Mujtaba, and A. S. Abbas, “Preparation and Characterization of Biodegradable Crosslinked Starch Ester as Adsorbent,” in 2nd International Conference on Materials Engineering & Science (IConMEAS 2019), 2020, pp. 20165–20169, doi: https://doi.org/10.1063/5.0000170.
Al-Jubory, F. K., I. M. Mujtaba, and A. S. Abbas. "Removal of Ciprofloxacin from Aqueous Solution Using Prepared Biodegradable Potato Cross-linked Starch Ester." In IOP Conference Series: Materials Science and Engineering, vol. 1076, no. 1, p. 012031. IOP Publishing, 2021.
I. Langmuir, “THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. PART I. SOLIDS.,” J. Am. Chem. Soc., vol. 38, no. 11, pp. 2221–2295, Nov. 1916.
H. M. F. Freundlich, “Uber Die Adsorption in Losungen,” Zeitschrift fur Phys. Chemie-Leipzig, vol. 57A, pp. 385–470, 1906.
K. L. Tan and B. H. Hameed, “Insight into the adsorption kinetics models for the removal of contaminants from aqueous solutions,” J. Taiwan Inst. Chem. Eng., vol. 74, pp. 25–48, 2017.
D. C. Montgomery, E. A. Peck, and G. G. Vining, Introduction to linear regression analysis. Wiley, 2012.
B. Samiey and S. Farhadi, “Kinetics and thermodynamics of adsorption of Fuchsin acid on nickel oxide nanoparticles.,” Acta Chim. Slov., vol. 60, no. 4, pp. 763–73, 2013.
L. Khenniche and F. Benissad-Aissani, “Adsorptive Removal of phenol by Coffee Residue Activated Carbon and Commercial Activated Carbon: Equilibrium, Kinetics, and Thermodynamics,” J. Chem. Eng. Data, vol. 55, no. 11, pp. 4677–4686, Nov. 2010.
Downloads
Published
Issue
Section
License
Copyright (c) 2021 Iraqi Journal of Chemical and Petroleum Engineering
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
